How Cellulose Nanofibrils Affect Bulk, Surface, and Foam Properties of Anionic Surfactant Solutions

Wenchao Xiang, Natalie Preisig, Annika Ketola, Blaise L. Tardy, Long Bai, Jukka A. Ketoja, Cosima Stubenrauch (Corresponding Author), Orlando J. Rojas (Corresponding Author)

Research output: Contribution to journalArticleScientificpeer-review

1 Citation (Scopus)

Abstract

We study the generation and decay of aqueous foams stabilized by sodium dodecyl sulfate (SDS) in the presence of unmodified cellulose nanofibrils (CNF). Together with the rheology of aqueous suspensions containing CNF and SDS, the interfacial/colloidal interactions are determined by quartz crystal microgravimetry with dissipation monitoring, surface plasmon resonance, and isothermal titration calorimetry. The results are used to explain the properties of the air/water interface (interfacial activity and dilatational moduli determined from oscillating air bubbles) and of the bulk (steady-state flow, oscillatory shear, and capillary thinning). These properties are finally correlated to the foamability and to the foam stability. The latter was studied as a function of time by monitoring the foam volume, the liquid fraction, and the bubble size distribution. The shear-thinning effect of CNF is found to facilitate foam formation at SDS concentrations above the critical micelle concentration (cSDS ≥ cmc). Compared with foams stabilized by pure SDS, the presence of CNF enhances the viscosity and elasticity of the continuous phase as well as of the air/water interface. The CNF-containing foams have higher liquid fractions, larger initial bubble sizes, and better stability. Due to charge screening effects caused by sodium counter ions and depletion attraction caused by SDS micelles, especially at high SDS concentrations, CNF forms aggregates in the Plateau borders and nodes of the foam, thus slowing down liquid drainage and bubble growth and improving foam stability. Overall, our findings advance the understanding of the role of CNF in foam generation and stabilization.

Original languageEnglish
Pages (from-to)4361-4369
Number of pages9
JournalBiomacromolecules
Volume20
Issue number12
DOIs
Publication statusPublished - 9 Dec 2019
MoE publication typeA1 Journal article-refereed

Fingerprint

Anionic surfactants
Cellulose
Foams
Sodium dodecyl sulfate
Sodium Dodecyl Sulfate
Bubbles (in fluids)
Liquids
Air
Capillary flow
Quartz
Radiation counters
Shear thinning
Water
Monitoring
Critical micelle concentration
Surface plasmon resonance
Micelles
Calorimetry
Shear flow
Titration

Cite this

Xiang, Wenchao ; Preisig, Natalie ; Ketola, Annika ; Tardy, Blaise L. ; Bai, Long ; Ketoja, Jukka A. ; Stubenrauch, Cosima ; Rojas, Orlando J. / How Cellulose Nanofibrils Affect Bulk, Surface, and Foam Properties of Anionic Surfactant Solutions. In: Biomacromolecules. 2019 ; Vol. 20, No. 12. pp. 4361-4369.
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abstract = "We study the generation and decay of aqueous foams stabilized by sodium dodecyl sulfate (SDS) in the presence of unmodified cellulose nanofibrils (CNF). Together with the rheology of aqueous suspensions containing CNF and SDS, the interfacial/colloidal interactions are determined by quartz crystal microgravimetry with dissipation monitoring, surface plasmon resonance, and isothermal titration calorimetry. The results are used to explain the properties of the air/water interface (interfacial activity and dilatational moduli determined from oscillating air bubbles) and of the bulk (steady-state flow, oscillatory shear, and capillary thinning). These properties are finally correlated to the foamability and to the foam stability. The latter was studied as a function of time by monitoring the foam volume, the liquid fraction, and the bubble size distribution. The shear-thinning effect of CNF is found to facilitate foam formation at SDS concentrations above the critical micelle concentration (cSDS ≥ cmc). Compared with foams stabilized by pure SDS, the presence of CNF enhances the viscosity and elasticity of the continuous phase as well as of the air/water interface. The CNF-containing foams have higher liquid fractions, larger initial bubble sizes, and better stability. Due to charge screening effects caused by sodium counter ions and depletion attraction caused by SDS micelles, especially at high SDS concentrations, CNF forms aggregates in the Plateau borders and nodes of the foam, thus slowing down liquid drainage and bubble growth and improving foam stability. Overall, our findings advance the understanding of the role of CNF in foam generation and stabilization.",
author = "Wenchao Xiang and Natalie Preisig and Annika Ketola and Tardy, {Blaise L.} and Long Bai and Ketoja, {Jukka A.} and Cosima Stubenrauch and Rojas, {Orlando J.}",
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How Cellulose Nanofibrils Affect Bulk, Surface, and Foam Properties of Anionic Surfactant Solutions. / Xiang, Wenchao; Preisig, Natalie; Ketola, Annika; Tardy, Blaise L.; Bai, Long; Ketoja, Jukka A.; Stubenrauch, Cosima (Corresponding Author); Rojas, Orlando J. (Corresponding Author).

In: Biomacromolecules, Vol. 20, No. 12, 09.12.2019, p. 4361-4369.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - How Cellulose Nanofibrils Affect Bulk, Surface, and Foam Properties of Anionic Surfactant Solutions

AU - Xiang, Wenchao

AU - Preisig, Natalie

AU - Ketola, Annika

AU - Tardy, Blaise L.

AU - Bai, Long

AU - Ketoja, Jukka A.

AU - Stubenrauch, Cosima

AU - Rojas, Orlando J.

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AB - We study the generation and decay of aqueous foams stabilized by sodium dodecyl sulfate (SDS) in the presence of unmodified cellulose nanofibrils (CNF). Together with the rheology of aqueous suspensions containing CNF and SDS, the interfacial/colloidal interactions are determined by quartz crystal microgravimetry with dissipation monitoring, surface plasmon resonance, and isothermal titration calorimetry. The results are used to explain the properties of the air/water interface (interfacial activity and dilatational moduli determined from oscillating air bubbles) and of the bulk (steady-state flow, oscillatory shear, and capillary thinning). These properties are finally correlated to the foamability and to the foam stability. The latter was studied as a function of time by monitoring the foam volume, the liquid fraction, and the bubble size distribution. The shear-thinning effect of CNF is found to facilitate foam formation at SDS concentrations above the critical micelle concentration (cSDS ≥ cmc). Compared with foams stabilized by pure SDS, the presence of CNF enhances the viscosity and elasticity of the continuous phase as well as of the air/water interface. The CNF-containing foams have higher liquid fractions, larger initial bubble sizes, and better stability. Due to charge screening effects caused by sodium counter ions and depletion attraction caused by SDS micelles, especially at high SDS concentrations, CNF forms aggregates in the Plateau borders and nodes of the foam, thus slowing down liquid drainage and bubble growth and improving foam stability. Overall, our findings advance the understanding of the role of CNF in foam generation and stabilization.

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