@article{f562c17f6be94163813f84bc33532177,
title = "Imidazolium-Based Poly(ionic liquid)s as New Alternatives for CO2 Capture.",
abstract = "Solid imidazolium-based poly(ionic liq.)s with variable mol. wts. that contain the poly[2-(1-butylimidazolium-3-yl)ethyl methacrylate] (BIEMA) cation and different counter-anions were evaluated in terms of CO2 capture and compared with classical ionic liqs. with similar counter-anions. In addn. to poly(ionic liq.)s with often-applied ions such as BF4-, PF6-, NTf2-, trifluoromethanesulfonate (OTf-) and Br-, for the 1st time [BIEMA][acetate] was synthesized, which revealed a remarkably high CO2 sorption performance that exceeded the poly(ionic liq.)s studied previously on av. by a factor of four (12.46 mg/gPIL). This study provides an understanding of the factors that affect CO2 sorption and a comparison of the CO2 capture efficiency with the frequently used sorbents. Also, all the studied sorbents were reusable if regenerated under carefully selected conditions and can be considered as suitable candidates for CO2 sorption. [on SciFinder(R)]",
keywords = "Polymerization (RAFT, imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture), Ionomers Role: NUU (Other use, unclassified), PEP (Physical, engineering or chemical process), PRP (Properties), PUR (Purification or recovery), SPN (Synthetic preparation), PREP (Preparation), PROC (Process), USES (Uses) (acrylic, Onium compounds Role: NUU (Other use, USES (Uses) (imidazolium compounds, Absorbents, Ion exchange, Molecular structure-property relationship (imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture), Polyoxyalkylenes Role: MOA (Modifier or additive use), NUU (Other use, USES (Uses) (imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture), Ionic liquids (polymeric, Molecular structure-property relationship (sorption, imidazolium, polyionic, liq, Carbon, dioxide, absorbent, ionomer, counterion, effect",
author = "Privalova, {Elena I.} and Erno Karjalainen and Mari Nurmi and P{\"a}ivi M{\"a}ki-Arvela and Kari Er{\"a}nen and Heikki Tenhu and Murzin, {Dmitry Yu} and Jyri-Pekka Mikkola",
note = "Copyright (C) 2013 American Chemical Society (ACS). All Rights Reserved.; Section Code: 48-1; CA Section Cross-references: 59; CODEN: CHEMIZ; CAS Registry Numbers: 2638-94-0P Role: CAT (Catalyst use), PEP (Physical, engineering or chemical process), PUR (Purification or recovery), PREP (Preparation), PROC (Process), USES (Uses) (ACPA; imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 957132-87-5P Role: NUU (Other use, unclassified), PRP (Properties), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), USES (Uses), RACT (Reactant or reagent) (P5 [BIEMA][Br]; imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 796738-93-7P (1-[2-(Methacryloyloxy)ethyl]-3-butylimidazolium tetrafluoroborate) Role: PEP (Physical, engineering or chemical process), PRP (Properties), PUR (Purification or recovery), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), PROC (Process), RACT (Reactant or reagent) ([BIEMA][BF4] monomer; imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 957132-79-5P Role: PEP (Physical, engineering or chemical process), PRP (Properties), PUR (Purification or recovery), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), PROC (Process), RACT (Reactant or reagent) ([BIEMA][Br]; imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 201611-92-9P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (chain transfer agent; imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 25322-68-3 (PEG 400) Role: MOA (Modifier or additive use), NUU (Other use, unclassified), USES (Uses) (imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 957132-87-5DP Role: NUU (Other use, unclassified), PEP (Physical, engineering or chemical process), PRP (Properties), PUR (Purification or recovery), SPN (Synthetic preparation), PREP (Preparation), PROC (Process), USES (Uses) (imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 174501-64-5P (1-Butyl-3-methylimidazolium hexafluorophosphate); 174501-65-6P (1-Butyl-3-methylimidazolium tetrafluoroborate); 796738-91-5P Role: NUU (Other use, unclassified), PRP (Properties), SPN (Synthetic preparation), PREP (Preparation), USES (Uses) (imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 4316-42-1P (1-Butylimidazole) Role: PEP (Physical, engineering or chemical process), PUR (Purification or recovery), PREP (Preparation), PROC (Process) (imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 4513-56-8P (2-Bromoethyl methacrylate) Role: PEP (Physical, engineering or chemical process), PUR (Purification or recovery), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), PROC (Process), RACT (Reactant or reagent) (imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 124-38-9 (Carbon dioxide) Role: PEP (Physical, engineering or chemical process), REM (Removal or disposal), PROC (Process) (imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 540-51-2 (2-Bromoethanol); 920-46-7 (Methacrylic acid chloride); 85100-77-2 (1-Butyl-3-methylimidazolium bromide) Role: RCT (Reactant), RACT (Reactant or reagent) (imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture); 13755-29-8 (Sodium tetrafluoroborate); 16941-11-0 (Ammonium hexafluorophosphate); 33454-82-9 (Lithium trifluoromethanesulfonate); 90076-65-6 (Lithium bis(trifluoromethanesulfonyl)imide) Role: RGT (Reagent), RACT (Reactant or reagent) (imidazolium-based poly(ionic liq.)s as new alternatives for CO2 capture)",
year = "2013",
doi = "10.1002/cssc.201300120",
language = "English",
volume = "6",
pages = "1500--1509",
journal = "ChemSusChem",
issn = "1864-5631",
publisher = "Wiley-VCH Verlag",
number = "8",
}
