Impact of hydrothermal and alkaline treatments of birch kraft pulp on the levelling-off degree of polymerization (LODP) of cellulose microfibrils

Marc Borrega (Corresponding Author), Patrik Ahvenainen, Eero Kontturi (Corresponding Author)

Research output: Contribution to journalArticleScientificpeer-review

Abstract

Abstract: The levelling-off degree of polymerization (LODP) is typically considered an apodictic number of each cellulosic source that relates to the length of its cellulose crystallites. In this study, we have performed hydrothermal and alkaline treatments on bleached birch kraft pulp to adjust the xylan content, and the resulting pulps have been subjected to acid hydrolysis to determine their LODP. The results show that hydrothermal treatments promote longitudinal alterations in the supramolecular structure of cellulose, represented by a linear decrease in the LODP with lowering the xylan content in the pulp. Moreover, a decrease in LODP is also observed after alkaline extraction of the birch kraft pulp, but the decrease as a function of xylan content differs from that observed after hydrothermal treatments. The results appear to indicate that the LODP is rather an artifact introduced during processing of the material than a true measure of the length of the crystallites in the native cellulose source. Graphical abstract: [Figure not available: see fulltext.].

Original languageEnglish
Pages (from-to)6811-6818
Number of pages8
JournalCellulose
Volume25
Issue number11
DOIs
Publication statusPublished - 1 Nov 2018
MoE publication typeNot Eligible

Fingerprint

Kraft pulp
Cellulose
Xylans
Polymerization
Crystallites
Pulp
Bleached pulp
Hydrolysis
Acids
Processing

Keywords

  • Acid hydrolysis
  • Alkaline extraction
  • Cellulose
  • Hydrothermal treatment
  • LODP
  • Xylan

Cite this

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title = "Impact of hydrothermal and alkaline treatments of birch kraft pulp on the levelling-off degree of polymerization (LODP) of cellulose microfibrils",
abstract = "Abstract: The levelling-off degree of polymerization (LODP) is typically considered an apodictic number of each cellulosic source that relates to the length of its cellulose crystallites. In this study, we have performed hydrothermal and alkaline treatments on bleached birch kraft pulp to adjust the xylan content, and the resulting pulps have been subjected to acid hydrolysis to determine their LODP. The results show that hydrothermal treatments promote longitudinal alterations in the supramolecular structure of cellulose, represented by a linear decrease in the LODP with lowering the xylan content in the pulp. Moreover, a decrease in LODP is also observed after alkaline extraction of the birch kraft pulp, but the decrease as a function of xylan content differs from that observed after hydrothermal treatments. The results appear to indicate that the LODP is rather an artifact introduced during processing of the material than a true measure of the length of the crystallites in the native cellulose source. Graphical abstract: [Figure not available: see fulltext.].",
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Impact of hydrothermal and alkaline treatments of birch kraft pulp on the levelling-off degree of polymerization (LODP) of cellulose microfibrils. / Borrega, Marc (Corresponding Author); Ahvenainen, Patrik; Kontturi, Eero (Corresponding Author).

In: Cellulose, Vol. 25, No. 11, 01.11.2018, p. 6811-6818.

Research output: Contribution to journalArticleScientificpeer-review

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AU - Borrega, Marc

AU - Ahvenainen, Patrik

AU - Kontturi, Eero

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N2 - Abstract: The levelling-off degree of polymerization (LODP) is typically considered an apodictic number of each cellulosic source that relates to the length of its cellulose crystallites. In this study, we have performed hydrothermal and alkaline treatments on bleached birch kraft pulp to adjust the xylan content, and the resulting pulps have been subjected to acid hydrolysis to determine their LODP. The results show that hydrothermal treatments promote longitudinal alterations in the supramolecular structure of cellulose, represented by a linear decrease in the LODP with lowering the xylan content in the pulp. Moreover, a decrease in LODP is also observed after alkaline extraction of the birch kraft pulp, but the decrease as a function of xylan content differs from that observed after hydrothermal treatments. The results appear to indicate that the LODP is rather an artifact introduced during processing of the material than a true measure of the length of the crystallites in the native cellulose source. Graphical abstract: [Figure not available: see fulltext.].

AB - Abstract: The levelling-off degree of polymerization (LODP) is typically considered an apodictic number of each cellulosic source that relates to the length of its cellulose crystallites. In this study, we have performed hydrothermal and alkaline treatments on bleached birch kraft pulp to adjust the xylan content, and the resulting pulps have been subjected to acid hydrolysis to determine their LODP. The results show that hydrothermal treatments promote longitudinal alterations in the supramolecular structure of cellulose, represented by a linear decrease in the LODP with lowering the xylan content in the pulp. Moreover, a decrease in LODP is also observed after alkaline extraction of the birch kraft pulp, but the decrease as a function of xylan content differs from that observed after hydrothermal treatments. The results appear to indicate that the LODP is rather an artifact introduced during processing of the material than a true measure of the length of the crystallites in the native cellulose source. Graphical abstract: [Figure not available: see fulltext.].

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