Integration of 2D and 3D nanostructure fabrication with wafer-scale microelectronics: Photonic crystals and graphene: Dissertation

    Research output: ThesisDissertationCollection of Articles

    Abstract

    This Thesis considers different aspects of heterogeneous integration of 2- and 3- dimensional nanostructures with today's microelectronics process flow. The applications in the main focus are integrated 3D photonic crystals on a photonic chip and graphene biosensors, both exploiting directed self-assembly but at different length scales. View point is from the fabrication and integration challenges, but the future prospects of the selected fields of applications are also reviewed. Utilization of new materials and structures in microelectronics and photonics applications typically requires integration with the existing platforms. The fabrication processes are optimized for the established materials and generally require both high thermal budget and elemental purity to avoid contamination, thus the novel elements need to be integrated at the back-end phase and aligned with the pre-existing structures on the substrate. For that, there are basically three alternatives; (i) directed self-assembly, (ii) high precision placement and (iii) methods exploiting thin film growth and lithographic definition of the nanostructures. Whereas the 2D photonic crystals can be conveniently fabricated with advanced nanolithographic methods such as deep-UV lithography and etching, for the 3D photonic crystals the lithographic approach may not be the most efficient method. This Thesis presents a scalable directed self-assembly method for the fabrication of artificial opal photonic crystals on a photonic chip and defines the processing steps required for the inversion of the opal with silicon to obtain full photonic band gap without damaging the underlying chip. The existence of the full photonic band gap in the inverted silicon photonic crystal is demonstrated by measurements via the integrated waveguides. The integration of graphene with microelectronics processes is, in principle, simple due to the sheet-like structure of the material. The atomically thin 2D crystal can be processed in a manner similar to traditional thin films, as soon as graphene is on the substrate. This Thesis presents different methods aiming for scalable production of high quality graphene on different substrates, ranging from mechanical exfoliation based on step-and-stamp printing to rapid chemical vapour deposition with subsequent thin film transfer, which is the most promising method for large area graphene production. From the physical and chemical point of view, however, graphene is not a traditional thin film. Due to the single atom thickness, environment has a significant influence on the electronic properties of graphene. This has to be taken into account in the processing and design of graphene devices, but it also provides means to highly efficient sensing applications. The key issue in graphene based sensors is in the specific recognition, which has to be introduced by functionalization. This Thesis addresses the functionalization of graphene field-effect-transistors with selfassembled bio-receptors, utilizing non-covalent hydrophobic interactions between graphene and hydrophobin proteins.
    Original languageEnglish
    QualificationDoctor Degree
    Awarding Institution
    • Aalto University
    Supervisors/Advisors
    • Liljeroth, Peter, Supervisor, External person
    • Imhof, Arnout, Advisor, External person
    • Sun, Jie, Advisor, External person
    Award date24 Jul 2015
    Place of PublicationEspoo
    Publisher
    Print ISBNs978-951-38-8324-9
    Electronic ISBNs978-951-38-8325-6
    Publication statusPublished - 2015
    MoE publication typeG5 Doctoral dissertation (article)

    Fingerprint

    Graphite
    Photonic crystals
    Microelectronics
    Nanostructures
    Fabrication
    Photonics
    Self assembly
    Photonic band gap
    Thin films
    Silicon
    Substrates
    Film growth
    Processing
    Field effect transistors
    Biosensors
    Electronic properties
    Lithography
    Printing
    Chemical vapor deposition
    Etching

    Keywords

    • integration
    • graphene
    • photonic crystals
    • opals
    • biosensing

    Cite this

    @phdthesis{672f45f4aea94d99ba0b8b3bca32abba,
    title = "Integration of 2D and 3D nanostructure fabrication with wafer-scale microelectronics: Photonic crystals and graphene: Dissertation",
    abstract = "This Thesis considers different aspects of heterogeneous integration of 2- and 3- dimensional nanostructures with today's microelectronics process flow. The applications in the main focus are integrated 3D photonic crystals on a photonic chip and graphene biosensors, both exploiting directed self-assembly but at different length scales. View point is from the fabrication and integration challenges, but the future prospects of the selected fields of applications are also reviewed. Utilization of new materials and structures in microelectronics and photonics applications typically requires integration with the existing platforms. The fabrication processes are optimized for the established materials and generally require both high thermal budget and elemental purity to avoid contamination, thus the novel elements need to be integrated at the back-end phase and aligned with the pre-existing structures on the substrate. For that, there are basically three alternatives; (i) directed self-assembly, (ii) high precision placement and (iii) methods exploiting thin film growth and lithographic definition of the nanostructures. Whereas the 2D photonic crystals can be conveniently fabricated with advanced nanolithographic methods such as deep-UV lithography and etching, for the 3D photonic crystals the lithographic approach may not be the most efficient method. This Thesis presents a scalable directed self-assembly method for the fabrication of artificial opal photonic crystals on a photonic chip and defines the processing steps required for the inversion of the opal with silicon to obtain full photonic band gap without damaging the underlying chip. The existence of the full photonic band gap in the inverted silicon photonic crystal is demonstrated by measurements via the integrated waveguides. The integration of graphene with microelectronics processes is, in principle, simple due to the sheet-like structure of the material. The atomically thin 2D crystal can be processed in a manner similar to traditional thin films, as soon as graphene is on the substrate. This Thesis presents different methods aiming for scalable production of high quality graphene on different substrates, ranging from mechanical exfoliation based on step-and-stamp printing to rapid chemical vapour deposition with subsequent thin film transfer, which is the most promising method for large area graphene production. From the physical and chemical point of view, however, graphene is not a traditional thin film. Due to the single atom thickness, environment has a significant influence on the electronic properties of graphene. This has to be taken into account in the processing and design of graphene devices, but it also provides means to highly efficient sensing applications. The key issue in graphene based sensors is in the specific recognition, which has to be introduced by functionalization. This Thesis addresses the functionalization of graphene field-effect-transistors with selfassembled bio-receptors, utilizing non-covalent hydrophobic interactions between graphene and hydrophobin proteins.",
    keywords = "integration, graphene, photonic crystals, opals, biosensing",
    author = "Sanna Arpiainen",
    year = "2015",
    language = "English",
    isbn = "978-951-38-8324-9",
    series = "VTT Science",
    publisher = "VTT Technical Research Centre of Finland",
    number = "100",
    address = "Finland",
    school = "Aalto University",

    }

    Integration of 2D and 3D nanostructure fabrication with wafer-scale microelectronics : Photonic crystals and graphene: Dissertation. / Arpiainen, Sanna.

    Espoo : VTT Technical Research Centre of Finland, 2015. 78 p.

    Research output: ThesisDissertationCollection of Articles

    TY - THES

    T1 - Integration of 2D and 3D nanostructure fabrication with wafer-scale microelectronics

    T2 - Photonic crystals and graphene: Dissertation

    AU - Arpiainen, Sanna

    PY - 2015

    Y1 - 2015

    N2 - This Thesis considers different aspects of heterogeneous integration of 2- and 3- dimensional nanostructures with today's microelectronics process flow. The applications in the main focus are integrated 3D photonic crystals on a photonic chip and graphene biosensors, both exploiting directed self-assembly but at different length scales. View point is from the fabrication and integration challenges, but the future prospects of the selected fields of applications are also reviewed. Utilization of new materials and structures in microelectronics and photonics applications typically requires integration with the existing platforms. The fabrication processes are optimized for the established materials and generally require both high thermal budget and elemental purity to avoid contamination, thus the novel elements need to be integrated at the back-end phase and aligned with the pre-existing structures on the substrate. For that, there are basically three alternatives; (i) directed self-assembly, (ii) high precision placement and (iii) methods exploiting thin film growth and lithographic definition of the nanostructures. Whereas the 2D photonic crystals can be conveniently fabricated with advanced nanolithographic methods such as deep-UV lithography and etching, for the 3D photonic crystals the lithographic approach may not be the most efficient method. This Thesis presents a scalable directed self-assembly method for the fabrication of artificial opal photonic crystals on a photonic chip and defines the processing steps required for the inversion of the opal with silicon to obtain full photonic band gap without damaging the underlying chip. The existence of the full photonic band gap in the inverted silicon photonic crystal is demonstrated by measurements via the integrated waveguides. The integration of graphene with microelectronics processes is, in principle, simple due to the sheet-like structure of the material. The atomically thin 2D crystal can be processed in a manner similar to traditional thin films, as soon as graphene is on the substrate. This Thesis presents different methods aiming for scalable production of high quality graphene on different substrates, ranging from mechanical exfoliation based on step-and-stamp printing to rapid chemical vapour deposition with subsequent thin film transfer, which is the most promising method for large area graphene production. From the physical and chemical point of view, however, graphene is not a traditional thin film. Due to the single atom thickness, environment has a significant influence on the electronic properties of graphene. This has to be taken into account in the processing and design of graphene devices, but it also provides means to highly efficient sensing applications. The key issue in graphene based sensors is in the specific recognition, which has to be introduced by functionalization. This Thesis addresses the functionalization of graphene field-effect-transistors with selfassembled bio-receptors, utilizing non-covalent hydrophobic interactions between graphene and hydrophobin proteins.

    AB - This Thesis considers different aspects of heterogeneous integration of 2- and 3- dimensional nanostructures with today's microelectronics process flow. The applications in the main focus are integrated 3D photonic crystals on a photonic chip and graphene biosensors, both exploiting directed self-assembly but at different length scales. View point is from the fabrication and integration challenges, but the future prospects of the selected fields of applications are also reviewed. Utilization of new materials and structures in microelectronics and photonics applications typically requires integration with the existing platforms. The fabrication processes are optimized for the established materials and generally require both high thermal budget and elemental purity to avoid contamination, thus the novel elements need to be integrated at the back-end phase and aligned with the pre-existing structures on the substrate. For that, there are basically three alternatives; (i) directed self-assembly, (ii) high precision placement and (iii) methods exploiting thin film growth and lithographic definition of the nanostructures. Whereas the 2D photonic crystals can be conveniently fabricated with advanced nanolithographic methods such as deep-UV lithography and etching, for the 3D photonic crystals the lithographic approach may not be the most efficient method. This Thesis presents a scalable directed self-assembly method for the fabrication of artificial opal photonic crystals on a photonic chip and defines the processing steps required for the inversion of the opal with silicon to obtain full photonic band gap without damaging the underlying chip. The existence of the full photonic band gap in the inverted silicon photonic crystal is demonstrated by measurements via the integrated waveguides. The integration of graphene with microelectronics processes is, in principle, simple due to the sheet-like structure of the material. The atomically thin 2D crystal can be processed in a manner similar to traditional thin films, as soon as graphene is on the substrate. This Thesis presents different methods aiming for scalable production of high quality graphene on different substrates, ranging from mechanical exfoliation based on step-and-stamp printing to rapid chemical vapour deposition with subsequent thin film transfer, which is the most promising method for large area graphene production. From the physical and chemical point of view, however, graphene is not a traditional thin film. Due to the single atom thickness, environment has a significant influence on the electronic properties of graphene. This has to be taken into account in the processing and design of graphene devices, but it also provides means to highly efficient sensing applications. The key issue in graphene based sensors is in the specific recognition, which has to be introduced by functionalization. This Thesis addresses the functionalization of graphene field-effect-transistors with selfassembled bio-receptors, utilizing non-covalent hydrophobic interactions between graphene and hydrophobin proteins.

    KW - integration

    KW - graphene

    KW - photonic crystals

    KW - opals

    KW - biosensing

    M3 - Dissertation

    SN - 978-951-38-8324-9

    T3 - VTT Science

    PB - VTT Technical Research Centre of Finland

    CY - Espoo

    ER -