Intercomparison of trace element determination in samples from a coal-fired power plant

Ermo Ikävalko, Timo Laitinen, Mika Pärkkä, Inkeri Yliruokanen

Research output: Contribution to journalArticleScientificpeer-review

5 Citations (Scopus)

Abstract

The combustion of fossil fuels, e.g. coal, is one of the anthropogenic sources of hazardous trace element emissions.
This interlaboratory study was arranged to test and improve the quality of trace element analysis of different types of samples from a coal-fired power plant. Samples of coal, fly ash, by-product from flue gas desulphurisation (=FGD product, consisting mainly of CaSO3 and CaSO4), and two different absorption media used for the sampling of vaporous metals and metalloids in flue gases were sent to be analyzed for Al. As, Be, Cd. Co, Cr, Cu, Hg, Mn, Ni. Pb. Se, Tl, V and Zn by different Finnish laboratories using mainly atomic spectroscopic methods.
In addition, neutron activation analysis and X-ray fluorescence spectroscopy were employed. 12 laboratories took part in the analysis of a HNO3 sample, 5 in the analysis of a K2Cr2O7/HNO3 sample, 15 in the analysis of a fly ash sample, 9 in the analysis of a coal sample, and 7 in the analysis of a sample of the by-product from flue gas desulphurisation.
The results were evaluated both in terms of interlaboratory agreement and in comparison with different digestion and analytical methods used in the intercomparison. The magnitude of the deviations of the results clearly indicated a need to develop the quality of power plant sample analysis.
Considering the methods used, it was concluded that the composition of the acid mixture used for the digestion of solid samples is more decisive than the method of heating during the digestion.
Original languageEnglish
Pages (from-to)207-224
JournalInternational Journal of Environmental Analytical Chemistry
Volume61
Issue number3
DOIs
Publication statusPublished - 1995
MoE publication typeA1 Journal article-refereed

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Power Plants
Coal
coal-fired power plant
power plants
Trace Elements
Coal Ash
Trace elements
coal
trace elements
Power plants
Flue gases
trace element
Digestion
Gases
Fly ash
Byproducts
digestion
Metalloids
Potassium Dichromate
X-Ray Emission Spectrometry

Cite this

Ikävalko, Ermo ; Laitinen, Timo ; Pärkkä, Mika ; Yliruokanen, Inkeri. / Intercomparison of trace element determination in samples from a coal-fired power plant. In: International Journal of Environmental Analytical Chemistry. 1995 ; Vol. 61, No. 3. pp. 207-224.
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Intercomparison of trace element determination in samples from a coal-fired power plant. / Ikävalko, Ermo; Laitinen, Timo; Pärkkä, Mika; Yliruokanen, Inkeri.

In: International Journal of Environmental Analytical Chemistry, Vol. 61, No. 3, 1995, p. 207-224.

Research output: Contribution to journalArticleScientificpeer-review

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AB - The combustion of fossil fuels, e.g. coal, is one of the anthropogenic sources of hazardous trace element emissions. This interlaboratory study was arranged to test and improve the quality of trace element analysis of different types of samples from a coal-fired power plant. Samples of coal, fly ash, by-product from flue gas desulphurisation (=FGD product, consisting mainly of CaSO3 and CaSO4), and two different absorption media used for the sampling of vaporous metals and metalloids in flue gases were sent to be analyzed for Al. As, Be, Cd. Co, Cr, Cu, Hg, Mn, Ni. Pb. Se, Tl, V and Zn by different Finnish laboratories using mainly atomic spectroscopic methods. In addition, neutron activation analysis and X-ray fluorescence spectroscopy were employed. 12 laboratories took part in the analysis of a HNO3 sample, 5 in the analysis of a K2Cr2O7/HNO3 sample, 15 in the analysis of a fly ash sample, 9 in the analysis of a coal sample, and 7 in the analysis of a sample of the by-product from flue gas desulphurisation. The results were evaluated both in terms of interlaboratory agreement and in comparison with different digestion and analytical methods used in the intercomparison. The magnitude of the deviations of the results clearly indicated a need to develop the quality of power plant sample analysis. Considering the methods used, it was concluded that the composition of the acid mixture used for the digestion of solid samples is more decisive than the method of heating during the digestion.

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