Investigations of NanoBud formation

Albert G. Nasibulin, Anton S. Anisimov, Peter V. Pikhitsa, Hua Jiang, David P. Brown, Mansoo Choi, Esko I. Kauppinen

Research output: Contribution to journalArticleScientificpeer-review

79 Citations (Scopus)

Abstract

The formation of a novel hybrid material, NanoBuds, single-walled carbon nanotubes (CNTs) with covalently attached fullerenes was investigated in a ferrocene–carbon monoxide system.
Fullerenes and CNTs were simultaneously formed by carbon monoxide disproportionation on the surface of iron particles in the presence of etching agents such as H2O and CO2.
On the basis of parametric investigations and in situ sampling of the product from different locations in the reactor the mechanisms for NanoBud formation are discussed.
Original languageEnglish
Pages (from-to)109-114
JournalChemical Physics Letters
Volume446
Issue number1-3
DOIs
Publication statusPublished - 2007
MoE publication typeA1 Journal article-refereed

Fingerprint

Fullerenes
fullerenes
carbon nanotubes
Carbon Nanotubes
Hybrid materials
Single-walled carbon nanotubes (SWCN)
Carbon Monoxide
carbon monoxide
Etching
Iron
sampling
reactors
etching
Sampling
iron
products

Keywords

  • nanostructures
  • nanobuds

Cite this

Nasibulin, A. G., Anisimov, A. S., Pikhitsa, P. V., Jiang, H., Brown, D. P., Choi, M., & Kauppinen, E. I. (2007). Investigations of NanoBud formation. Chemical Physics Letters, 446(1-3), 109-114. https://doi.org/10.1016/j.cplett.2007.08.050
Nasibulin, Albert G. ; Anisimov, Anton S. ; Pikhitsa, Peter V. ; Jiang, Hua ; Brown, David P. ; Choi, Mansoo ; Kauppinen, Esko I. / Investigations of NanoBud formation. In: Chemical Physics Letters. 2007 ; Vol. 446, No. 1-3. pp. 109-114.
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Nasibulin, AG, Anisimov, AS, Pikhitsa, PV, Jiang, H, Brown, DP, Choi, M & Kauppinen, EI 2007, 'Investigations of NanoBud formation', Chemical Physics Letters, vol. 446, no. 1-3, pp. 109-114. https://doi.org/10.1016/j.cplett.2007.08.050

Investigations of NanoBud formation. / Nasibulin, Albert G.; Anisimov, Anton S.; Pikhitsa, Peter V.; Jiang, Hua; Brown, David P.; Choi, Mansoo; Kauppinen, Esko I.

In: Chemical Physics Letters, Vol. 446, No. 1-3, 2007, p. 109-114.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Investigations of NanoBud formation

AU - Nasibulin, Albert G.

AU - Anisimov, Anton S.

AU - Pikhitsa, Peter V.

AU - Jiang, Hua

AU - Brown, David P.

AU - Choi, Mansoo

AU - Kauppinen, Esko I.

PY - 2007

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N2 - The formation of a novel hybrid material, NanoBuds, single-walled carbon nanotubes (CNTs) with covalently attached fullerenes was investigated in a ferrocene–carbon monoxide system. Fullerenes and CNTs were simultaneously formed by carbon monoxide disproportionation on the surface of iron particles in the presence of etching agents such as H2O and CO2. On the basis of parametric investigations and in situ sampling of the product from different locations in the reactor the mechanisms for NanoBud formation are discussed.

AB - The formation of a novel hybrid material, NanoBuds, single-walled carbon nanotubes (CNTs) with covalently attached fullerenes was investigated in a ferrocene–carbon monoxide system. Fullerenes and CNTs were simultaneously formed by carbon monoxide disproportionation on the surface of iron particles in the presence of etching agents such as H2O and CO2. On the basis of parametric investigations and in situ sampling of the product from different locations in the reactor the mechanisms for NanoBud formation are discussed.

KW - nanostructures

KW - nanobuds

U2 - 10.1016/j.cplett.2007.08.050

DO - 10.1016/j.cplett.2007.08.050

M3 - Article

VL - 446

SP - 109

EP - 114

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1-3

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Nasibulin AG, Anisimov AS, Pikhitsa PV, Jiang H, Brown DP, Choi M et al. Investigations of NanoBud formation. Chemical Physics Letters. 2007;446(1-3):109-114. https://doi.org/10.1016/j.cplett.2007.08.050