Investigations of NanoBud formation

Albert G. Nasibulin; Anton S. Anisimov; Peter V. Pikhitsa; Hua Jiang; David P. Brown; Mansoo Choi; Esko I. Kauppinen

doi:10.1016/j.cplett.2007.08.050

Investigations of NanoBud formation

Albert G. Nasibulin
, Anton S. Anisimov
, Peter V. Pikhitsa
, Hua Jiang
, David P. Brown
, Mansoo Choi
, Esko I. Kauppinen

VTT Technical Research Centre of Finland

Helsinki University of Technology
Seoul National University

Research output: Contribution to journal › Article › Scientific › peer-review

103 Citations (Scopus)

Abstract

The formation of a novel hybrid material, NanoBuds, single-walled carbon nanotubes (CNTs) with covalently attached fullerenes was investigated in a ferrocene–carbon monoxide system.
Fullerenes and CNTs were simultaneously formed by carbon monoxide disproportionation on the surface of iron particles in the presence of etching agents such as H2O and CO2.
On the basis of parametric investigations and in situ sampling of the product from different locations in the reactor the mechanisms for NanoBud formation are discussed.

Original language	English
Pages (from-to)	109-114
Journal	Chemical Physics Letters
Volume	446
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2007.08.050
Publication status	Published - 2007
MoE publication type	A1 Journal article-refereed

Keywords

nanostructures
nanobuds

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10.1016/j.cplett.2007.08.050

Cite this

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title = "Investigations of NanoBud formation",

abstract = "The formation of a novel hybrid material, NanoBuds, single-walled carbon nanotubes (CNTs) with covalently attached fullerenes was investigated in a ferrocene–carbon monoxide system. Fullerenes and CNTs were simultaneously formed by carbon monoxide disproportionation on the surface of iron particles in the presence of etching agents such as H2O and CO2. On the basis of parametric investigations and in situ sampling of the product from different locations in the reactor the mechanisms for NanoBud formation are discussed.",

keywords = "nanostructures, nanobuds",

author = "Nasibulin, \{Albert G.\} and Anisimov, \{Anton S.\} and Pikhitsa, \{Peter V.\} and Hua Jiang and Brown, \{David P.\} and Mansoo Choi and Kauppinen, \{Esko I.\}",

year = "2007",

doi = "10.1016/j.cplett.2007.08.050",

language = "English",

volume = "446",

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journal = "Chemical Physics Letters",

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TY - JOUR

T1 - Investigations of NanoBud formation

AU - Nasibulin, Albert G.

AU - Anisimov, Anton S.

AU - Pikhitsa, Peter V.

AU - Jiang, Hua

AU - Brown, David P.

AU - Choi, Mansoo

AU - Kauppinen, Esko I.

PY - 2007

Y1 - 2007

N2 - The formation of a novel hybrid material, NanoBuds, single-walled carbon nanotubes (CNTs) with covalently attached fullerenes was investigated in a ferrocene–carbon monoxide system. Fullerenes and CNTs were simultaneously formed by carbon monoxide disproportionation on the surface of iron particles in the presence of etching agents such as H2O and CO2. On the basis of parametric investigations and in situ sampling of the product from different locations in the reactor the mechanisms for NanoBud formation are discussed.

AB - The formation of a novel hybrid material, NanoBuds, single-walled carbon nanotubes (CNTs) with covalently attached fullerenes was investigated in a ferrocene–carbon monoxide system. Fullerenes and CNTs were simultaneously formed by carbon monoxide disproportionation on the surface of iron particles in the presence of etching agents such as H2O and CO2. On the basis of parametric investigations and in situ sampling of the product from different locations in the reactor the mechanisms for NanoBud formation are discussed.

KW - nanostructures

KW - nanobuds

U2 - 10.1016/j.cplett.2007.08.050

DO - 10.1016/j.cplett.2007.08.050

M3 - Article

SN - 0009-2614

VL - 446

SP - 109

EP - 114

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

Investigations of NanoBud formation

Abstract

Keywords

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