Ion-induced nucleation of dibutyl phthalate vapors on spherical and nonspherical singly and multiply charged polyethylene glycol ions

Albert G. Nasibulin (Corresponding Author), J. Fernandez de la Mora, Esko I. Kauppinen

Research output: Contribution to journalArticleScientificpeer-review

13 Citations (Scopus)

Abstract

Dibutyl phthalate vapor nucleation induced by positive polyethylene glycol (PEG) ions with controlled sizes and charges was experimentally studied. The ions were produced by electrospray ionization, classified in a high-resolution differential mobility analyzer, and studied in a nano condensation nucleus counter of the mixing type. Ionic radii of PEG varied from 0.52 to 1.56 nm, including from singly to quadruply charged ions. Some of these ions are fully stretched chains, other are spherical, and others have intermediate forms, all of them having been previously characterized by mobility and mass spectrometry studies. Activation of PEG1080+2 requires a supersaturation almost as high as that required for small singly charged ions and higher than for PEG1080+. This anomaly is explained by the Coulombic stretching of the ion into a long chain, where the two charged centers appear to be relatively decoupled from each other. The critical supersaturation for singly charged spherical ions falls below Thomson's (capillary) theory and even below the already low values seen previously for tetraheptyl ammonium bromide clusters. Spherical PEG4120+2 falls close to the Thomson curve. The trends observed for slightly nonspherical PEG4120+3 and highly nonspherical (but not quite linear) PEG4120+4 are intermediate between those of multiply charged spheres and small singly charged ions.
Original languageEnglish
Pages (from-to)1133 - 1138
Number of pages6
JournalJournal of Physical Chemistry A
Volume112
Issue number6
DOIs
Publication statusPublished - 2008
MoE publication typeA1 Journal article-refereed

Fingerprint

Dibutyl Phthalate
phthalates
glycols
polyethylenes
Nucleation
Vapors
nucleation
Ions
vapors
ions
Supersaturation
supersaturation
condensation nuclei
Electrospray ionization
ammonium bromides
Stretching
Mass spectrometry
Condensation
analyzers
counters

Keywords

  • ion-induced nucleation
  • nucleation
  • polyethylene glycol
  • PEG
  • electrospray
  • electrospray ionization

Cite this

Nasibulin, Albert G. ; Fernandez de la Mora, J. ; Kauppinen, Esko I. / Ion-induced nucleation of dibutyl phthalate vapors on spherical and nonspherical singly and multiply charged polyethylene glycol ions. In: Journal of Physical Chemistry A. 2008 ; Vol. 112, No. 6. pp. 1133 - 1138.
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abstract = "Dibutyl phthalate vapor nucleation induced by positive polyethylene glycol (PEG) ions with controlled sizes and charges was experimentally studied. The ions were produced by electrospray ionization, classified in a high-resolution differential mobility analyzer, and studied in a nano condensation nucleus counter of the mixing type. Ionic radii of PEG varied from 0.52 to 1.56 nm, including from singly to quadruply charged ions. Some of these ions are fully stretched chains, other are spherical, and others have intermediate forms, all of them having been previously characterized by mobility and mass spectrometry studies. Activation of PEG1080+2 requires a supersaturation almost as high as that required for small singly charged ions and higher than for PEG1080+. This anomaly is explained by the Coulombic stretching of the ion into a long chain, where the two charged centers appear to be relatively decoupled from each other. The critical supersaturation for singly charged spherical ions falls below Thomson's (capillary) theory and even below the already low values seen previously for tetraheptyl ammonium bromide clusters. Spherical PEG4120+2 falls close to the Thomson curve. The trends observed for slightly nonspherical PEG4120+3 and highly nonspherical (but not quite linear) PEG4120+4 are intermediate between those of multiply charged spheres and small singly charged ions.",
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Ion-induced nucleation of dibutyl phthalate vapors on spherical and nonspherical singly and multiply charged polyethylene glycol ions. / Nasibulin, Albert G. (Corresponding Author); Fernandez de la Mora, J.; Kauppinen, Esko I.

In: Journal of Physical Chemistry A, Vol. 112, No. 6, 2008, p. 1133 - 1138.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Ion-induced nucleation of dibutyl phthalate vapors on spherical and nonspherical singly and multiply charged polyethylene glycol ions

AU - Nasibulin, Albert G.

AU - Fernandez de la Mora, J.

AU - Kauppinen, Esko I.

PY - 2008

Y1 - 2008

N2 - Dibutyl phthalate vapor nucleation induced by positive polyethylene glycol (PEG) ions with controlled sizes and charges was experimentally studied. The ions were produced by electrospray ionization, classified in a high-resolution differential mobility analyzer, and studied in a nano condensation nucleus counter of the mixing type. Ionic radii of PEG varied from 0.52 to 1.56 nm, including from singly to quadruply charged ions. Some of these ions are fully stretched chains, other are spherical, and others have intermediate forms, all of them having been previously characterized by mobility and mass spectrometry studies. Activation of PEG1080+2 requires a supersaturation almost as high as that required for small singly charged ions and higher than for PEG1080+. This anomaly is explained by the Coulombic stretching of the ion into a long chain, where the two charged centers appear to be relatively decoupled from each other. The critical supersaturation for singly charged spherical ions falls below Thomson's (capillary) theory and even below the already low values seen previously for tetraheptyl ammonium bromide clusters. Spherical PEG4120+2 falls close to the Thomson curve. The trends observed for slightly nonspherical PEG4120+3 and highly nonspherical (but not quite linear) PEG4120+4 are intermediate between those of multiply charged spheres and small singly charged ions.

AB - Dibutyl phthalate vapor nucleation induced by positive polyethylene glycol (PEG) ions with controlled sizes and charges was experimentally studied. The ions were produced by electrospray ionization, classified in a high-resolution differential mobility analyzer, and studied in a nano condensation nucleus counter of the mixing type. Ionic radii of PEG varied from 0.52 to 1.56 nm, including from singly to quadruply charged ions. Some of these ions are fully stretched chains, other are spherical, and others have intermediate forms, all of them having been previously characterized by mobility and mass spectrometry studies. Activation of PEG1080+2 requires a supersaturation almost as high as that required for small singly charged ions and higher than for PEG1080+. This anomaly is explained by the Coulombic stretching of the ion into a long chain, where the two charged centers appear to be relatively decoupled from each other. The critical supersaturation for singly charged spherical ions falls below Thomson's (capillary) theory and even below the already low values seen previously for tetraheptyl ammonium bromide clusters. Spherical PEG4120+2 falls close to the Thomson curve. The trends observed for slightly nonspherical PEG4120+3 and highly nonspherical (but not quite linear) PEG4120+4 are intermediate between those of multiply charged spheres and small singly charged ions.

KW - ion-induced nucleation

KW - nucleation

KW - polyethylene glycol

KW - PEG

KW - electrospray

KW - electrospray ionization

U2 - 10.1021/jp0755995

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JO - Journal of Physical Chemistry A

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