Keratin-reinforced cellulose filaments from ionic liquid solutions

Kari Kammiovirta, Anna-Stiina Jääskeläinen, Lauri Kuutti, Ulla Holopainen-Mantila, Arja Paananen, Anna Suurnäkki, Hannes Orelma (Corresponding Author)

Research output: Contribution to journalArticleScientificpeer-review

4 Citations (Scopus)

Abstract

Cellulose-based filaments produced with ionic liquid-based processes have high application potential in textiles and composites to replace cotton fibres. Those filaments have unique properties already that could be further improved with additions of proteins. Keratin from poultry feathers is currently a low-value material that has potential as a renewable feedstock in material applications. In this study, cellulose filaments with chicken feather keratin were prepared by wet-spinning from ionic liquid solution. Both keratin and cellulose were dissolved in [EMIM]Ac and spun into ethanol to regenerate cellulose and keratin and wash out the ionic liquid. The effect of keratin addition on filament properties was investigated by microscopic, spectroscopic and strength analyses. It was observed that a small keratin addition into cellulosic filaments improved the mechanical properties remarkably, whereas high keratin additions resulted in reduced mechanical performance. Keratin accumulation on the surface of the prepared filaments was observed. In addition, based on FTIR spectroscopy, it is likely that the morphology of cellulose changed from cellulose I to II and the ?-sheets in feather keratin unfolded to unordered keratin upon dissolution and regeneration. The cellulose-protein filaments may find applications from areas where good biocompatibility and easy modifiability are required characteristics.
Original languageEnglish
Pages (from-to)88797-88806
JournalRSC Advances
Volume6
Issue number91
DOIs
Publication statusPublished - 2016
MoE publication typeA1 Journal article-refereed

Fingerprint

Keratin
Ionic Liquids
Keratins
Ionic liquids
Cellulose
Proteins
Poultry
Cotton fibers
Biocompatibility
Feedstocks
Textiles
Dissolution
Ethanol
Spectroscopy

Keywords

  • cellulose
  • keratin
  • filament
  • blend
  • FTIR
  • CLSM

Cite this

Kammiovirta, Kari ; Jääskeläinen, Anna-Stiina ; Kuutti, Lauri ; Holopainen-Mantila, Ulla ; Paananen, Arja ; Suurnäkki, Anna ; Orelma, Hannes. / Keratin-reinforced cellulose filaments from ionic liquid solutions. In: RSC Advances. 2016 ; Vol. 6, No. 91. pp. 88797-88806.
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abstract = "Cellulose-based filaments produced with ionic liquid-based processes have high application potential in textiles and composites to replace cotton fibres. Those filaments have unique properties already that could be further improved with additions of proteins. Keratin from poultry feathers is currently a low-value material that has potential as a renewable feedstock in material applications. In this study, cellulose filaments with chicken feather keratin were prepared by wet-spinning from ionic liquid solution. Both keratin and cellulose were dissolved in [EMIM]Ac and spun into ethanol to regenerate cellulose and keratin and wash out the ionic liquid. The effect of keratin addition on filament properties was investigated by microscopic, spectroscopic and strength analyses. It was observed that a small keratin addition into cellulosic filaments improved the mechanical properties remarkably, whereas high keratin additions resulted in reduced mechanical performance. Keratin accumulation on the surface of the prepared filaments was observed. In addition, based on FTIR spectroscopy, it is likely that the morphology of cellulose changed from cellulose I to II and the ?-sheets in feather keratin unfolded to unordered keratin upon dissolution and regeneration. The cellulose-protein filaments may find applications from areas where good biocompatibility and easy modifiability are required characteristics.",
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Keratin-reinforced cellulose filaments from ionic liquid solutions. / Kammiovirta, Kari; Jääskeläinen, Anna-Stiina; Kuutti, Lauri; Holopainen-Mantila, Ulla; Paananen, Arja; Suurnäkki, Anna; Orelma, Hannes (Corresponding Author).

In: RSC Advances, Vol. 6, No. 91, 2016, p. 88797-88806.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Keratin-reinforced cellulose filaments from ionic liquid solutions

AU - Kammiovirta, Kari

AU - Jääskeläinen, Anna-Stiina

AU - Kuutti, Lauri

AU - Holopainen-Mantila, Ulla

AU - Paananen, Arja

AU - Suurnäkki, Anna

AU - Orelma, Hannes

PY - 2016

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N2 - Cellulose-based filaments produced with ionic liquid-based processes have high application potential in textiles and composites to replace cotton fibres. Those filaments have unique properties already that could be further improved with additions of proteins. Keratin from poultry feathers is currently a low-value material that has potential as a renewable feedstock in material applications. In this study, cellulose filaments with chicken feather keratin were prepared by wet-spinning from ionic liquid solution. Both keratin and cellulose were dissolved in [EMIM]Ac and spun into ethanol to regenerate cellulose and keratin and wash out the ionic liquid. The effect of keratin addition on filament properties was investigated by microscopic, spectroscopic and strength analyses. It was observed that a small keratin addition into cellulosic filaments improved the mechanical properties remarkably, whereas high keratin additions resulted in reduced mechanical performance. Keratin accumulation on the surface of the prepared filaments was observed. In addition, based on FTIR spectroscopy, it is likely that the morphology of cellulose changed from cellulose I to II and the ?-sheets in feather keratin unfolded to unordered keratin upon dissolution and regeneration. The cellulose-protein filaments may find applications from areas where good biocompatibility and easy modifiability are required characteristics.

AB - Cellulose-based filaments produced with ionic liquid-based processes have high application potential in textiles and composites to replace cotton fibres. Those filaments have unique properties already that could be further improved with additions of proteins. Keratin from poultry feathers is currently a low-value material that has potential as a renewable feedstock in material applications. In this study, cellulose filaments with chicken feather keratin were prepared by wet-spinning from ionic liquid solution. Both keratin and cellulose were dissolved in [EMIM]Ac and spun into ethanol to regenerate cellulose and keratin and wash out the ionic liquid. The effect of keratin addition on filament properties was investigated by microscopic, spectroscopic and strength analyses. It was observed that a small keratin addition into cellulosic filaments improved the mechanical properties remarkably, whereas high keratin additions resulted in reduced mechanical performance. Keratin accumulation on the surface of the prepared filaments was observed. In addition, based on FTIR spectroscopy, it is likely that the morphology of cellulose changed from cellulose I to II and the ?-sheets in feather keratin unfolded to unordered keratin upon dissolution and regeneration. The cellulose-protein filaments may find applications from areas where good biocompatibility and easy modifiability are required characteristics.

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