Kinetic resolution of aminoalkenes by asymmetric hydroamination: A mechanistic study

Keyphrases

• Aminoalkenes 100%
• Asymmetric Hydroamination 100%
• Kinetic Resolution 100%
• Mechanistic Studies 100%
• Cyclization 66%
• Pre-equilibrium 66%
• Curtin-Hammett 66%
• Kinetic Study 33%
• Amines 33%
• Attractive Interaction 33%
• Relative Rate 33%
• Chelates 33%
• Metal Center 33%
• Amino Group 33%
• Diastereoselectivity 33%
• Hydroamination 33%
• Rare-earth Metal Complex 33%
• Aryl Substituents 33%
• Stereocenters 33%
• Aliphatic Substituents 33%
• Aromatic Systems 33%
• Resolution Process 33%
• Cyclization Rate 33%
• Complex Preferences 33%
• High Efficiency 33%
• Phenyl Substituent 33%
• Enantiopure 33%

INIS

• substrates 100%
• kinetics 100%
• asymmetry 100%
• resolution 100%
• catalysts 80%
• efficiency 50%
• cyclization 30%
• metals 20%
• interactions 10%
• demand 10%
• increasing 10%
• equilibrium 10%
• range 10%
• ligands 10%
• amines 10%
• aromatics 10%
• chirality 10%
• rare earths 10%
• chelating agents 10%

Chemistry

• Mechanistic Study 100%
• Hydroamination 100%
• Kinetic Study 50%
• Lanthanoid Atom 50%
• Diastereoselectivity 50%
• Enantiopurity 50%
• Amino Group 50%
• Enantiomer 50%