Abstract
The charge transfer properties of alkylTCNQ derivatives in the LB films of molecular conductors were examined. TMTTF, OMTTF and BEDOTTF were adopted as donors to form charge transfer complexes with C10 TCNQ or C14TCNQ. The degree of charge transfer of the alkylTCNQ in the LB films could be controlled from nearly neutral to fully ionic state by adopting appropriate donors for the counterpart. OMTTF-C10TCNQ formed a neutral complex which is located near the neutral-ionic boundary and is expected to be a candidate to realise neutral-ionic phase transition in the LB films.
| Original language | English |
|---|---|
| Pages (from-to) | 1843-1844 |
| Journal | Synthetic Metals |
| Volume | 86 |
| Issue number | 1-3 |
| DOIs | |
| Publication status | Published - 1997 |
| MoE publication type | A1 Journal article-refereed |
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Langmuir-Blodgett films of molecular conductors based on alkylTCNQ derivatives. / Nakamura, Takayoshi; Konuma, T.; Akutagawa, T.; Tachibana, Hiroaki; Azumi, Reiko; Matsumoto, Mitsuyoshi; Isotalo, Heikki; Horiuchi, Sachio; Yamochi, Hideki; Saito, Gunzi.
In: Synthetic Metals, Vol. 86, No. 1-3, 1997, p. 1843-1844.Research output: Contribution to journal › Article › Scientific › peer-review
TY - JOUR
T1 - Langmuir-Blodgett films of molecular conductors based on alkylTCNQ derivatives
AU - Nakamura, Takayoshi
AU - Konuma, T.
AU - Akutagawa, T.
AU - Tachibana, Hiroaki
AU - Azumi, Reiko
AU - Matsumoto, Mitsuyoshi
AU - Isotalo, Heikki
AU - Horiuchi, Sachio
AU - Yamochi, Hideki
AU - Saito, Gunzi
PY - 1997
Y1 - 1997
N2 - The charge transfer properties of alkylTCNQ derivatives in the LB films of molecular conductors were examined. TMTTF, OMTTF and BEDOTTF were adopted as donors to form charge transfer complexes with C10 TCNQ or C14TCNQ. The degree of charge transfer of the alkylTCNQ in the LB films could be controlled from nearly neutral to fully ionic state by adopting appropriate donors for the counterpart. OMTTF-C10TCNQ formed a neutral complex which is located near the neutral-ionic boundary and is expected to be a candidate to realise neutral-ionic phase transition in the LB films.
AB - The charge transfer properties of alkylTCNQ derivatives in the LB films of molecular conductors were examined. TMTTF, OMTTF and BEDOTTF were adopted as donors to form charge transfer complexes with C10 TCNQ or C14TCNQ. The degree of charge transfer of the alkylTCNQ in the LB films could be controlled from nearly neutral to fully ionic state by adopting appropriate donors for the counterpart. OMTTF-C10TCNQ formed a neutral complex which is located near the neutral-ionic boundary and is expected to be a candidate to realise neutral-ionic phase transition in the LB films.
U2 - 10.1016/S0379-6779(97)80931-9
DO - 10.1016/S0379-6779(97)80931-9
M3 - Article
VL - 86
SP - 1843
EP - 1844
JO - Synthetic Metals
JF - Synthetic Metals
SN - 0379-6779
IS - 1-3
ER -