LIBS depth profiling of Be-containing samples with different gaseous impurity concentrations

P. G. Bhat; P. Veis; A. Marín Roldán; J. Karhunen; P. Paris; I. Jõgi; A. Hakola; J. Likonen; S. Almaviva; W. Gromelski; M. Ladygina; P. Gasior; J. Ristkok; I. Bogdanović Radović; Z. Siketić; O. Romanenko; C. Porosnicu; C. Lungu

doi:10.1016/j.nme.2023.101549

LIBS depth profiling of Be-containing samples with different gaseous impurity concentrations

P. G. Bhat, P. Veis (Corresponding Author), A. Marín Roldán, J. Karhunen, P. Paris, I. Jõgi, A. Hakola, J. Likonen, S. Almaviva, W. Gromelski, M. Ladygina, P. Gasior, J. Ristkok, I. Bogdanović Radović, Z. Siketić, O. Romanenko, C. Porosnicu, C. Lungu

Research output: Contribution to journal › Article › Scientific › peer-review

3 Citations (Scopus)

Abstract

Understanding the interaction between the fusion plasma and the plasma-facing materials (PFMs) is crucial for achieving the optimal performance, safety, and lifetime of the fusion devices. Relevant materials have been intensely studied to determine fuel retention and the composition of the co-deposited layers on the PFMs by depth profile analysis using Laser-Induced Breakdown Spectroscopy (LIBS) and Calibration-Free (CF)-LIBS. However, the comparison between the layers containing a mixture of different (seeding) gases using LIBS, has not been studied systematically. Consequently, the aim of this work is the LIBS depth profile analysis of Be-based samples containing the fuel (D) and one of the seeding gases (N, Ne, He) with variable concentrations to study the potential impact on fuel retention in the PFMs. The LIBS measurements were performed using Nd:YAG laser (1064 nm) under Ar atmosphere (at 2 and 100 mbar). In LIBS the ablation rate was evaluated, spectral lines of all relevant elements except N and Ne were detected and compared with the SIMS depth profiles. The reasons for the non-detectability of Ne are discussed in detail.

Original language	English
Article number	101549
Number of pages	6
Journal	Nuclear Materials and Energy
Volume	37
DOIs	https://doi.org/10.1016/j.nme.2023.101549
Publication status	Published - Dec 2023
MoE publication type	A1 Journal article-refereed

Funding

This work has been carried out within the framework of the EUROfusion Consortium, funded by the European Union via the Euratom Research and Training Programme (Grant Agreement No 101052200 - EUROfusion). Views and opinions expressed here are however those of the author(s) only and do not necessarily reflect those of the European Union or European Commission. Neither the European Union nor the European Commission can be held responsible for them. The authors PGB, PV, and AMR acknowledge the Scientific Grant Agency of the Slovak Republic (contract number 1/0803/21, VEGA-2/0144/21) and the Slovak Research and Development Agency (APVV-16-0612 and APVV-22-0548) for financial support. This scientific paper has been published as part of the international project co-financed by the Polish Ministry of Science and Higher Education within the programme called ‘PMW’ for 2023.

Keywords

Ablation rates
Be-containing samples
Deuterium
LIBS depth profiles
Neon detectability
Seeding gases

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.nme.2023.101549Licence: CC BY

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Bhat, P. G., Veis, P., Marín Roldán, A., Karhunen, J., Paris, P., Jõgi, I., Hakola, A., Likonen, J., Almaviva, S., Gromelski, W., Ladygina, M., Gasior, P., Ristkok, J., Bogdanović Radović, I., Siketić, Z., Romanenko, O., Porosnicu, C., & Lungu, C. (2023). LIBS depth profiling of Be-containing samples with different gaseous impurity concentrations. Nuclear Materials and Energy, 37, Article 101549. https://doi.org/10.1016/j.nme.2023.101549

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title = "LIBS depth profiling of Be-containing samples with different gaseous impurity concentrations",

abstract = "Understanding the interaction between the fusion plasma and the plasma-facing materials (PFMs) is crucial for achieving the optimal performance, safety, and lifetime of the fusion devices. Relevant materials have been intensely studied to determine fuel retention and the composition of the co-deposited layers on the PFMs by depth profile analysis using Laser-Induced Breakdown Spectroscopy (LIBS) and Calibration-Free (CF)-LIBS. However, the comparison between the layers containing a mixture of different (seeding) gases using LIBS, has not been studied systematically. Consequently, the aim of this work is the LIBS depth profile analysis of Be-based samples containing the fuel (D) and one of the seeding gases (N, Ne, He) with variable concentrations to study the potential impact on fuel retention in the PFMs. The LIBS measurements were performed using Nd:YAG laser (1064 nm) under Ar atmosphere (at 2 and 100 mbar). In LIBS the ablation rate was evaluated, spectral lines of all relevant elements except N and Ne were detected and compared with the SIMS depth profiles. The reasons for the non-detectability of Ne are discussed in detail.",

keywords = "Ablation rates, Be-containing samples, Deuterium, LIBS depth profiles, Neon detectability, Seeding gases",

author = "Bhat, {P. G.} and P. Veis and {Mar{\'i}n Rold{\'a}n}, A. and J. Karhunen and P. Paris and I. J{\~o}gi and A. Hakola and J. Likonen and S. Almaviva and W. Gromelski and M. Ladygina and P. Gasior and J. Ristkok and {Bogdanovi{\'c} Radovi{\'c}}, I. and Z. Siketi{\'c} and O. Romanenko and C. Porosnicu and C. Lungu",

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year = "2023",

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doi = "10.1016/j.nme.2023.101549",

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Bhat, PG, Veis, P, Marín Roldán, A, Karhunen, J, Paris, P, Jõgi, I, Hakola, A , Likonen, J, Almaviva, S, Gromelski, W, Ladygina, M, Gasior, P, Ristkok, J, Bogdanović Radović, I, Siketić, Z, Romanenko, O, Porosnicu, C & Lungu, C 2023, 'LIBS depth profiling of Be-containing samples with different gaseous impurity concentrations', Nuclear Materials and Energy, vol. 37, 101549. https://doi.org/10.1016/j.nme.2023.101549

TY - JOUR

T1 - LIBS depth profiling of Be-containing samples with different gaseous impurity concentrations

AU - Bhat, P. G.

AU - Veis, P.

AU - Marín Roldán, A.

AU - Karhunen, J.

AU - Paris, P.

AU - Jõgi, I.

AU - Hakola, A.

AU - Likonen, J.

AU - Almaviva, S.

AU - Gromelski, W.

AU - Ladygina, M.

AU - Gasior, P.

AU - Ristkok, J.

AU - Bogdanović Radović, I.

AU - Siketić, Z.

AU - Romanenko, O.

AU - Porosnicu, C.

AU - Lungu, C.

PY - 2023/12

Y1 - 2023/12

N2 - Understanding the interaction between the fusion plasma and the plasma-facing materials (PFMs) is crucial for achieving the optimal performance, safety, and lifetime of the fusion devices. Relevant materials have been intensely studied to determine fuel retention and the composition of the co-deposited layers on the PFMs by depth profile analysis using Laser-Induced Breakdown Spectroscopy (LIBS) and Calibration-Free (CF)-LIBS. However, the comparison between the layers containing a mixture of different (seeding) gases using LIBS, has not been studied systematically. Consequently, the aim of this work is the LIBS depth profile analysis of Be-based samples containing the fuel (D) and one of the seeding gases (N, Ne, He) with variable concentrations to study the potential impact on fuel retention in the PFMs. The LIBS measurements were performed using Nd:YAG laser (1064 nm) under Ar atmosphere (at 2 and 100 mbar). In LIBS the ablation rate was evaluated, spectral lines of all relevant elements except N and Ne were detected and compared with the SIMS depth profiles. The reasons for the non-detectability of Ne are discussed in detail.

AB - Understanding the interaction between the fusion plasma and the plasma-facing materials (PFMs) is crucial for achieving the optimal performance, safety, and lifetime of the fusion devices. Relevant materials have been intensely studied to determine fuel retention and the composition of the co-deposited layers on the PFMs by depth profile analysis using Laser-Induced Breakdown Spectroscopy (LIBS) and Calibration-Free (CF)-LIBS. However, the comparison between the layers containing a mixture of different (seeding) gases using LIBS, has not been studied systematically. Consequently, the aim of this work is the LIBS depth profile analysis of Be-based samples containing the fuel (D) and one of the seeding gases (N, Ne, He) with variable concentrations to study the potential impact on fuel retention in the PFMs. The LIBS measurements were performed using Nd:YAG laser (1064 nm) under Ar atmosphere (at 2 and 100 mbar). In LIBS the ablation rate was evaluated, spectral lines of all relevant elements except N and Ne were detected and compared with the SIMS depth profiles. The reasons for the non-detectability of Ne are discussed in detail.

KW - Ablation rates

KW - Be-containing samples

KW - Deuterium

KW - LIBS depth profiles

KW - Neon detectability

KW - Seeding gases

UR - http://www.scopus.com/inward/record.url?scp=85176257197&partnerID=8YFLogxK

U2 - 10.1016/j.nme.2023.101549

DO - 10.1016/j.nme.2023.101549

M3 - Article

AN - SCOPUS:85176257197

SN - 2352-1791

VL - 37

JO - Nuclear Materials and Energy

JF - Nuclear Materials and Energy

M1 - 101549

ER -

LIBS depth profiling of Be-containing samples with different gaseous impurity concentrations

Abstract

Funding

Keywords

UN SDGs

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