Lignin cationization with glycidyltrimethylammonium chloride aiming at water purification applications

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Abstract

Hardwood organosolv lignin (OSL) and enzymatic hydrolysis lignin (EHL) from softwood were cationized by glycidyltrimethylammonium chloride (GTAC) as new lignin starting materials for the reaction. The products were in detail characterized by 31P-NMR to elucidate the reactivity of different lignin functionalities in cationization with GTAC. For OSL, a high cationization level (degree of substitution 0.74) was reached leading to a water-soluble product. For EHL, low solubility and lower reactivity were observed, likely due to the high saccharide content. Further, lower reactivity of the guaiacyl type lignin present in softwood, compared to syringyl type lignin in hardwoods, which was shown to react efficiently during the derivatization of OSL, probably played a role. In parallel to cationization, an increase of carboxylic acids (from 0.03 up to 0.55 mmol/g) in the lignin was observed as an unexpected side reaction, possibly as a result of alkaline oxygen oxidation. The applicability of the cationized lignins was tested for water purification applications in three model systems which have only sparingly been studied with cationized lignins. GTAC-OSL and GTAC-EHL were found promising for sulfate removal, with sulfate sorption capacities of up to 54 mg/g. GTAC-OSL was also found suitable for promoting kaolin settling and to some extent for humic acid coagulation.

Original languageEnglish
Pages (from-to)188-194
Number of pages7
JournalIndustrial Crops and Products
Volume104
DOIs
Publication statusPublished - 1 Oct 2017
MoE publication typeA1 Journal article-refereed

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water purification
lignin
chlorides
enzymatic hydrolysis
softwood
hardwood
sulfates
kaolin
derivatization
humic acids
carboxylic acids
coagulation

Keywords

  • lignin
  • glycidyltrimethylammonium chloride
  • cationization
  • water purification
  • sulfate adsorption
  • Cationization

Cite this

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title = "Lignin cationization with glycidyltrimethylammonium chloride aiming at water purification applications",
abstract = "Hardwood organosolv lignin (OSL) and enzymatic hydrolysis lignin (EHL) from softwood were cationized by glycidyltrimethylammonium chloride (GTAC) as new lignin starting materials for the reaction. The products were in detail characterized by 31P-NMR to elucidate the reactivity of different lignin functionalities in cationization with GTAC. For OSL, a high cationization level (degree of substitution 0.74) was reached leading to a water-soluble product. For EHL, low solubility and lower reactivity were observed, likely due to the high saccharide content. Further, lower reactivity of the guaiacyl type lignin present in softwood, compared to syringyl type lignin in hardwoods, which was shown to react efficiently during the derivatization of OSL, probably played a role. In parallel to cationization, an increase of carboxylic acids (from 0.03 up to 0.55 mmol/g) in the lignin was observed as an unexpected side reaction, possibly as a result of alkaline oxygen oxidation. The applicability of the cationized lignins was tested for water purification applications in three model systems which have only sparingly been studied with cationized lignins. GTAC-OSL and GTAC-EHL were found promising for sulfate removal, with sulfate sorption capacities of up to 54 mg/g. GTAC-OSL was also found suitable for promoting kaolin settling and to some extent for humic acid coagulation.",
keywords = "lignin, glycidyltrimethylammonium chloride, cationization, water purification, sulfate adsorption, Cationization",
author = "Ronny Wahlstr{\"o}m and Anna Kalliola and Juha Heikkinen and Hanna Kyll{\"o}nen and Tarja Tamminen",
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Lignin cationization with glycidyltrimethylammonium chloride aiming at water purification applications. / Wahlström, Ronny; Kalliola, Anna; Heikkinen, Juha; Kyllönen, Hanna; Tamminen, Tarja.

In: Industrial Crops and Products, Vol. 104, 01.10.2017, p. 188-194.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Lignin cationization with glycidyltrimethylammonium chloride aiming at water purification applications

AU - Wahlström, Ronny

AU - Kalliola, Anna

AU - Heikkinen, Juha

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AU - Tamminen, Tarja

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