Long-term alteration of bentonite in the presence of metallic iron

Sirpa Kumpulainen, Leena Kiviranta, Torbjörn Carlsson, Arto Muurinen, Daniel Svensson, Hiroshi Sasamoto, Mikatzu Yui, Paul Wersin, Dominic Rosch

Research output: Book/ReportReport

Abstract

According to the KBS-3H concept, each copper canister containing spent nuclear fuel will be surrounded by a bentonite buffer and a perforated steel cylinder. Since steel is unstable in wet bentonite, it will corrode and the corrosion products will interact with the surrounding bentonite in ways that are not fully understood. Such interaction may seriously impair the bentonite’s functioning as a buffer material, e.g. by lowering its CEC or decreasing its swelling capacity. This report presents results from two ironbentonite experiments carried out under quite different conditions at VTT (Finland) and JAEA (Japan). Both studies focused on long-term iron-bentonite interactions under
anaerobic conditions.

The study at VTT comprised eight years long experiments focused on diffusive based interactions between solid cast-iron and compacted MX-80 bentonite (dry density 1.5-1.6 g/cm3) in contact with an aqueous 0.5 M NaCl solution. The study at JAEA comprised ten years long batch experiments, each involving a mixture of metallic iron powder (25 g), an industrially refined Na bentonite, Kunipia F, which contains more than 99% montmorillonite (25 g), and an aqueous solution (250 mL). Samples were sent to B+Tech in airtight steel vessels filled with N2 and subsequently analyzed at various laboratories in Finland and Sweden. The JAEA samples differed with regard to the initial solution chemistry, which was either distilled water, 0.3 M NaCl, 0.6 M NaCl, 0.1 M NaHCO3, or 0.05 M Na2SO4.

The analyses of the MX-80 bentonite samples were carried out on samples containing a cast iron cylinder and also on corresponding background samples with no cast iron. In addition, the external solution and gas phase in contact with the bentonite were analyzed. Briefly, the gas contained H2, most possibly caused by corrosion of the cast iron, and CO2, mainly as a result of carbonate dissolution. The eight years old external solution exhibited, inter alia, reducing conditions, a pH of around eight, and measurable amounts of Mg2+, Ca2+, and SO4 2-. The bentonite was carefully divided into subsamples, which were studied with XRD, FTIR, SEM, ICP-AES, TEM-EDS, XANES, Mössbauer spectroscopy, and wet-chemical methods. Briefly, bentonite samples containing cast iron cylinders contained higher amounts of iron than the reference samples. The corroded iron was predominantly in the divalent form, and its concentration was highest close to the cylinder and decreased strongly with increasing distance from its surface. The average corrosion rate estimated from Fe profiles in the Fe-reacted samples is about 1.7 µm/a. The results from the Mössbauer spectroscopy analyses suggest that no reduction of the octahedral Fe3+ in the montmorillonite layers had occurred. The swelling pressure and the hydraulic conductivity were measured in undisturbed subsamples of the MX-80. The iron-bentonite interaction seemed to slightly decrease the swelling pressure, while the hydraulic conductivity was unchanged.

The corrosion rate of the Cu vessel surface was estimated from the Cu analysis in the clay to be about 0.035 µm/a.

The JAEA samples were analyzed with regard to the conditions in the water and in the bentonite. The water exhibited pH values in the approximate range of 11 to 13, and clearly reducing conditions with Eh values between -260 and -580 mV. XRD and FTIR analyses of the bentonite material, showed that montmorillonite was completely transformed to a non-swelling 7 Å clay mineral, most likely to the serpentine mineral berthierine, in samples containing 0.3-0.6 M NaCl solutions, with the highest pH values. The transformation was incomplete in samples containing 0.1 M NaHCO3 solution, and did not occur at all when the solution was either 0.05 M Na2SO4 or distilled water.

This report is a result of a joint project between Posiva and SKB. The report will also be printed as SKB Report R-10-52.
Original languageEnglish
PublisherPosiva
Number of pages92
Publication statusPublished - 2010
MoE publication typeD4 Published development or research report or study

Publication series

SeriesWorking Report
Number2010-71
SeriesSKB rapport
NumberR-10-52
ISSN1402-3091

Fingerprint

Bentonite
Iron
Cast iron
Steel
Swelling
Water
Hydraulic conductivity
Corrosion rate
Contacts (fluid mechanics)
Buffers
Gases
Serpentine Asbestos
Corrosion
X ray absorption near edge structure spectroscopy
Iron powder
Experiments
Spent fuels
Carbonates
Nuclear fuels

Keywords

  • Rauta-bentoniittivuorovaikutus
  • raudan korroosio
  • kuparin korroosio

Cite this

Kumpulainen, S., Kiviranta, L., Carlsson, T., Muurinen, A., Svensson, D., Sasamoto, H., ... Rosch, D. (2010). Long-term alteration of bentonite in the presence of metallic iron. Posiva . Working Report, No. 2010-71, SKB rapport, No. R-10-52
Kumpulainen, Sirpa ; Kiviranta, Leena ; Carlsson, Torbjörn ; Muurinen, Arto ; Svensson, Daniel ; Sasamoto, Hiroshi ; Yui, Mikatzu ; Wersin, Paul ; Rosch, Dominic. / Long-term alteration of bentonite in the presence of metallic iron. Posiva , 2010. 92 p. (Working Report; No. 2010-71). (SKB rapport; No. R-10-52).
@book{d07cea6ee1144b158ceb3d21c11840d8,
title = "Long-term alteration of bentonite in the presence of metallic iron",
abstract = "According to the KBS-3H concept, each copper canister containing spent nuclear fuel will be surrounded by a bentonite buffer and a perforated steel cylinder. Since steel is unstable in wet bentonite, it will corrode and the corrosion products will interact with the surrounding bentonite in ways that are not fully understood. Such interaction may seriously impair the bentonite’s functioning as a buffer material, e.g. by lowering its CEC or decreasing its swelling capacity. This report presents results from two ironbentonite experiments carried out under quite different conditions at VTT (Finland) and JAEA (Japan). Both studies focused on long-term iron-bentonite interactions underanaerobic conditions.The study at VTT comprised eight years long experiments focused on diffusive based interactions between solid cast-iron and compacted MX-80 bentonite (dry density 1.5-1.6 g/cm3) in contact with an aqueous 0.5 M NaCl solution. The study at JAEA comprised ten years long batch experiments, each involving a mixture of metallic iron powder (25 g), an industrially refined Na bentonite, Kunipia F, which contains more than 99{\%} montmorillonite (25 g), and an aqueous solution (250 mL). Samples were sent to B+Tech in airtight steel vessels filled with N2 and subsequently analyzed at various laboratories in Finland and Sweden. The JAEA samples differed with regard to the initial solution chemistry, which was either distilled water, 0.3 M NaCl, 0.6 M NaCl, 0.1 M NaHCO3, or 0.05 M Na2SO4.The analyses of the MX-80 bentonite samples were carried out on samples containing a cast iron cylinder and also on corresponding background samples with no cast iron. In addition, the external solution and gas phase in contact with the bentonite were analyzed. Briefly, the gas contained H2, most possibly caused by corrosion of the cast iron, and CO2, mainly as a result of carbonate dissolution. The eight years old external solution exhibited, inter alia, reducing conditions, a pH of around eight, and measurable amounts of Mg2+, Ca2+, and SO4 2-. The bentonite was carefully divided into subsamples, which were studied with XRD, FTIR, SEM, ICP-AES, TEM-EDS, XANES, M{\"o}ssbauer spectroscopy, and wet-chemical methods. Briefly, bentonite samples containing cast iron cylinders contained higher amounts of iron than the reference samples. The corroded iron was predominantly in the divalent form, and its concentration was highest close to the cylinder and decreased strongly with increasing distance from its surface. The average corrosion rate estimated from Fe profiles in the Fe-reacted samples is about 1.7 µm/a. The results from the M{\"o}ssbauer spectroscopy analyses suggest that no reduction of the octahedral Fe3+ in the montmorillonite layers had occurred. The swelling pressure and the hydraulic conductivity were measured in undisturbed subsamples of the MX-80. The iron-bentonite interaction seemed to slightly decrease the swelling pressure, while the hydraulic conductivity was unchanged.The corrosion rate of the Cu vessel surface was estimated from the Cu analysis in the clay to be about 0.035 µm/a. The JAEA samples were analyzed with regard to the conditions in the water and in the bentonite. The water exhibited pH values in the approximate range of 11 to 13, and clearly reducing conditions with Eh values between -260 and -580 mV. XRD and FTIR analyses of the bentonite material, showed that montmorillonite was completely transformed to a non-swelling 7 {\AA} clay mineral, most likely to the serpentine mineral berthierine, in samples containing 0.3-0.6 M NaCl solutions, with the highest pH values. The transformation was incomplete in samples containing 0.1 M NaHCO3 solution, and did not occur at all when the solution was either 0.05 M Na2SO4 or distilled water. This report is a result of a joint project between Posiva and SKB. The report will also be printed as SKB Report R-10-52.",
keywords = "Rauta-bentoniittivuorovaikutus, raudan korroosio, kuparin korroosio",
author = "Sirpa Kumpulainen and Leena Kiviranta and Torbj{\"o}rn Carlsson and Arto Muurinen and Daniel Svensson and Hiroshi Sasamoto and Mikatzu Yui and Paul Wersin and Dominic Rosch",
year = "2010",
language = "English",
series = "Working Report",
publisher = "Posiva",
number = "2010-71",
address = "Finland",

}

Kumpulainen, S, Kiviranta, L, Carlsson, T, Muurinen, A, Svensson, D, Sasamoto, H, Yui, M, Wersin, P & Rosch, D 2010, Long-term alteration of bentonite in the presence of metallic iron. Working Report, no. 2010-71, SKB rapport, no. R-10-52, Posiva .

Long-term alteration of bentonite in the presence of metallic iron. / Kumpulainen, Sirpa; Kiviranta, Leena; Carlsson, Torbjörn; Muurinen, Arto; Svensson, Daniel; Sasamoto, Hiroshi; Yui, Mikatzu; Wersin, Paul; Rosch, Dominic.

Posiva , 2010. 92 p. (Working Report; No. 2010-71). (SKB rapport; No. R-10-52).

Research output: Book/ReportReport

TY - BOOK

T1 - Long-term alteration of bentonite in the presence of metallic iron

AU - Kumpulainen, Sirpa

AU - Kiviranta, Leena

AU - Carlsson, Torbjörn

AU - Muurinen, Arto

AU - Svensson, Daniel

AU - Sasamoto, Hiroshi

AU - Yui, Mikatzu

AU - Wersin, Paul

AU - Rosch, Dominic

PY - 2010

Y1 - 2010

N2 - According to the KBS-3H concept, each copper canister containing spent nuclear fuel will be surrounded by a bentonite buffer and a perforated steel cylinder. Since steel is unstable in wet bentonite, it will corrode and the corrosion products will interact with the surrounding bentonite in ways that are not fully understood. Such interaction may seriously impair the bentonite’s functioning as a buffer material, e.g. by lowering its CEC or decreasing its swelling capacity. This report presents results from two ironbentonite experiments carried out under quite different conditions at VTT (Finland) and JAEA (Japan). Both studies focused on long-term iron-bentonite interactions underanaerobic conditions.The study at VTT comprised eight years long experiments focused on diffusive based interactions between solid cast-iron and compacted MX-80 bentonite (dry density 1.5-1.6 g/cm3) in contact with an aqueous 0.5 M NaCl solution. The study at JAEA comprised ten years long batch experiments, each involving a mixture of metallic iron powder (25 g), an industrially refined Na bentonite, Kunipia F, which contains more than 99% montmorillonite (25 g), and an aqueous solution (250 mL). Samples were sent to B+Tech in airtight steel vessels filled with N2 and subsequently analyzed at various laboratories in Finland and Sweden. The JAEA samples differed with regard to the initial solution chemistry, which was either distilled water, 0.3 M NaCl, 0.6 M NaCl, 0.1 M NaHCO3, or 0.05 M Na2SO4.The analyses of the MX-80 bentonite samples were carried out on samples containing a cast iron cylinder and also on corresponding background samples with no cast iron. In addition, the external solution and gas phase in contact with the bentonite were analyzed. Briefly, the gas contained H2, most possibly caused by corrosion of the cast iron, and CO2, mainly as a result of carbonate dissolution. The eight years old external solution exhibited, inter alia, reducing conditions, a pH of around eight, and measurable amounts of Mg2+, Ca2+, and SO4 2-. The bentonite was carefully divided into subsamples, which were studied with XRD, FTIR, SEM, ICP-AES, TEM-EDS, XANES, Mössbauer spectroscopy, and wet-chemical methods. Briefly, bentonite samples containing cast iron cylinders contained higher amounts of iron than the reference samples. The corroded iron was predominantly in the divalent form, and its concentration was highest close to the cylinder and decreased strongly with increasing distance from its surface. The average corrosion rate estimated from Fe profiles in the Fe-reacted samples is about 1.7 µm/a. The results from the Mössbauer spectroscopy analyses suggest that no reduction of the octahedral Fe3+ in the montmorillonite layers had occurred. The swelling pressure and the hydraulic conductivity were measured in undisturbed subsamples of the MX-80. The iron-bentonite interaction seemed to slightly decrease the swelling pressure, while the hydraulic conductivity was unchanged.The corrosion rate of the Cu vessel surface was estimated from the Cu analysis in the clay to be about 0.035 µm/a. The JAEA samples were analyzed with regard to the conditions in the water and in the bentonite. The water exhibited pH values in the approximate range of 11 to 13, and clearly reducing conditions with Eh values between -260 and -580 mV. XRD and FTIR analyses of the bentonite material, showed that montmorillonite was completely transformed to a non-swelling 7 Å clay mineral, most likely to the serpentine mineral berthierine, in samples containing 0.3-0.6 M NaCl solutions, with the highest pH values. The transformation was incomplete in samples containing 0.1 M NaHCO3 solution, and did not occur at all when the solution was either 0.05 M Na2SO4 or distilled water. This report is a result of a joint project between Posiva and SKB. The report will also be printed as SKB Report R-10-52.

AB - According to the KBS-3H concept, each copper canister containing spent nuclear fuel will be surrounded by a bentonite buffer and a perforated steel cylinder. Since steel is unstable in wet bentonite, it will corrode and the corrosion products will interact with the surrounding bentonite in ways that are not fully understood. Such interaction may seriously impair the bentonite’s functioning as a buffer material, e.g. by lowering its CEC or decreasing its swelling capacity. This report presents results from two ironbentonite experiments carried out under quite different conditions at VTT (Finland) and JAEA (Japan). Both studies focused on long-term iron-bentonite interactions underanaerobic conditions.The study at VTT comprised eight years long experiments focused on diffusive based interactions between solid cast-iron and compacted MX-80 bentonite (dry density 1.5-1.6 g/cm3) in contact with an aqueous 0.5 M NaCl solution. The study at JAEA comprised ten years long batch experiments, each involving a mixture of metallic iron powder (25 g), an industrially refined Na bentonite, Kunipia F, which contains more than 99% montmorillonite (25 g), and an aqueous solution (250 mL). Samples were sent to B+Tech in airtight steel vessels filled with N2 and subsequently analyzed at various laboratories in Finland and Sweden. The JAEA samples differed with regard to the initial solution chemistry, which was either distilled water, 0.3 M NaCl, 0.6 M NaCl, 0.1 M NaHCO3, or 0.05 M Na2SO4.The analyses of the MX-80 bentonite samples were carried out on samples containing a cast iron cylinder and also on corresponding background samples with no cast iron. In addition, the external solution and gas phase in contact with the bentonite were analyzed. Briefly, the gas contained H2, most possibly caused by corrosion of the cast iron, and CO2, mainly as a result of carbonate dissolution. The eight years old external solution exhibited, inter alia, reducing conditions, a pH of around eight, and measurable amounts of Mg2+, Ca2+, and SO4 2-. The bentonite was carefully divided into subsamples, which were studied with XRD, FTIR, SEM, ICP-AES, TEM-EDS, XANES, Mössbauer spectroscopy, and wet-chemical methods. Briefly, bentonite samples containing cast iron cylinders contained higher amounts of iron than the reference samples. The corroded iron was predominantly in the divalent form, and its concentration was highest close to the cylinder and decreased strongly with increasing distance from its surface. The average corrosion rate estimated from Fe profiles in the Fe-reacted samples is about 1.7 µm/a. The results from the Mössbauer spectroscopy analyses suggest that no reduction of the octahedral Fe3+ in the montmorillonite layers had occurred. The swelling pressure and the hydraulic conductivity were measured in undisturbed subsamples of the MX-80. The iron-bentonite interaction seemed to slightly decrease the swelling pressure, while the hydraulic conductivity was unchanged.The corrosion rate of the Cu vessel surface was estimated from the Cu analysis in the clay to be about 0.035 µm/a. The JAEA samples were analyzed with regard to the conditions in the water and in the bentonite. The water exhibited pH values in the approximate range of 11 to 13, and clearly reducing conditions with Eh values between -260 and -580 mV. XRD and FTIR analyses of the bentonite material, showed that montmorillonite was completely transformed to a non-swelling 7 Å clay mineral, most likely to the serpentine mineral berthierine, in samples containing 0.3-0.6 M NaCl solutions, with the highest pH values. The transformation was incomplete in samples containing 0.1 M NaHCO3 solution, and did not occur at all when the solution was either 0.05 M Na2SO4 or distilled water. This report is a result of a joint project between Posiva and SKB. The report will also be printed as SKB Report R-10-52.

KW - Rauta-bentoniittivuorovaikutus

KW - raudan korroosio

KW - kuparin korroosio

M3 - Report

T3 - Working Report

BT - Long-term alteration of bentonite in the presence of metallic iron

PB - Posiva

ER -

Kumpulainen S, Kiviranta L, Carlsson T, Muurinen A, Svensson D, Sasamoto H et al. Long-term alteration of bentonite in the presence of metallic iron. Posiva , 2010. 92 p. (Working Report; No. 2010-71). (SKB rapport; No. R-10-52).