Measuring rate constants for active species in the polymerization of ethylene by MAO-activated metallocene catalysts by electrospray ionization mass spectrometry

Fabio Di Lena; Esther Quintanilla; Peter Chen

doi:10.1039/b511997a

Measuring rate constants for active species in the polymerization of ethylene by MAO-activated metallocene catalysts by electrospray ionization mass spectrometry

Fabio Di Lena, Esther Quintanilla, Peter Chen^*

^*Corresponding author for this work

Not published at VTT

Swiss Federal Institute of Technology in Zurich (ETH Zürich)

Research output: Contribution to journal › Article › Scientific › peer-review

34 Citations (Scopus)

Abstract

Electrospray ionization mass spectrometry (ESI-MS) of MAO-activated metallocene-catalyzed polymerizations quenched with carbodiimides provides a method for the determination of rate constants in Ziegler-Natta polymerizations.

Original language	English
Pages (from-to)	5757-5759
Number of pages	3
Journal	Chemical Communications
Issue number	46
DOIs	https://doi.org/10.1039/b511997a
Publication status	Published - 14 Dec 2005
MoE publication type	A1 Journal article-refereed

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10.1039/b511997a

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@article{1e54f3f1d12143dcb81018fc2495a00f,

title = "Measuring rate constants for active species in the polymerization of ethylene by MAO-activated metallocene catalysts by electrospray ionization mass spectrometry",

abstract = "Electrospray ionization mass spectrometry (ESI-MS) of MAO-activated metallocene-catalyzed polymerizations quenched with carbodiimides provides a method for the determination of rate constants in Ziegler-Natta polymerizations.",

author = "\{Di Lena\}, Fabio and Esther Quintanilla and Peter Chen",

year = "2005",

month = dec,

day = "14",

doi = "10.1039/b511997a",

language = "English",

pages = "5757--5759",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry RSC",

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T1 - Measuring rate constants for active species in the polymerization of ethylene by MAO-activated metallocene catalysts by electrospray ionization mass spectrometry

AU - Di Lena, Fabio

AU - Quintanilla, Esther

AU - Chen, Peter

PY - 2005/12/14

Y1 - 2005/12/14

N2 - Electrospray ionization mass spectrometry (ESI-MS) of MAO-activated metallocene-catalyzed polymerizations quenched with carbodiimides provides a method for the determination of rate constants in Ziegler-Natta polymerizations.

AB - Electrospray ionization mass spectrometry (ESI-MS) of MAO-activated metallocene-catalyzed polymerizations quenched with carbodiimides provides a method for the determination of rate constants in Ziegler-Natta polymerizations.

UR - https://www.scopus.com/pages/publications/29844445511

U2 - 10.1039/b511997a

DO - 10.1039/b511997a

M3 - Article

AN - SCOPUS:29844445511

SN - 1359-7345

SP - 5757

EP - 5759

JO - Chemical Communications

JF - Chemical Communications

IS - 46

ER -

Measuring rate constants for active species in the polymerization of ethylene by MAO-activated metallocene catalysts by electrospray ionization mass spectrometry

Abstract

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