Mechanism of transpassive dissolution of nickel-based alloys studies by impedance spectroscopy and rotating ring-disc voltammetry

Iva Betova, Martin Bojinov (Corresponding Author), Petri Kinnunen, Timo Laitinen, Pekka Pohjanne, Timo Saario

    Research output: Contribution to journalArticleScientificpeer-review

    13 Citations (Scopus)

    Abstract

    A generalised kinetic model of transpassive dissolution of industrial nickel-based alloys is presented in this paper.
    It is based on electrochemical impedance spectroscopic (EIS) and rotating ring-disk (RRDE) measurements on several nickel-based alloys in 0.5 M sulphate and chloride solutions with pH ranging from 2 to 7.
    The model assumes that the dissolution of Cr from the transpassive film occurs via a Cr(VI) surface intermediate species. The dissolution of Ni as Ni(II) is proposed to occur via two parallel paths featuring two reaction intermediates.
    The role of Fe as a secondary passivating agent and Mo as an accelerator of transpassive dissolution is also taken into account.
    The kinetic model has been found to reproduce quantitatively the current vs. potential curves and the impedance spectra for the studied nickel-based alloys in the transpassive region.
    The proposed mechanism is sensitive to the impact of alloy and electrolyte composition on the dissolution process. Thus it can serve as a starting point to describe the transpassive behaviour of engineering alloys.
    Original languageEnglish
    Pages (from-to)2093-2107
    JournalElectrochimica Acta
    Volume47
    Issue number13-14
    DOIs
    Publication statusPublished - 2002
    MoE publication typeA1 Journal article-refereed

    Fingerprint

    Voltammetry
    Nickel
    Dissolution
    Spectroscopy
    Reaction intermediates
    Kinetics
    Electrolytes
    Sulfates
    Particle accelerators
    Chlorides
    Chemical analysis

    Keywords

    • nickel-based alloys
    • transpassive dissolution
    • electrochemical impedance spectroscopy (eis)
    • rotating ring-disc electrode (rrde)
    • kinetic model

    Cite this

    @article{499325e1008e4b48982e6c14e52774e8,
    title = "Mechanism of transpassive dissolution of nickel-based alloys studies by impedance spectroscopy and rotating ring-disc voltammetry",
    abstract = "A generalised kinetic model of transpassive dissolution of industrial nickel-based alloys is presented in this paper. It is based on electrochemical impedance spectroscopic (EIS) and rotating ring-disk (RRDE) measurements on several nickel-based alloys in 0.5 M sulphate and chloride solutions with pH ranging from 2 to 7. The model assumes that the dissolution of Cr from the transpassive film occurs via a Cr(VI) surface intermediate species. The dissolution of Ni as Ni(II) is proposed to occur via two parallel paths featuring two reaction intermediates. The role of Fe as a secondary passivating agent and Mo as an accelerator of transpassive dissolution is also taken into account. The kinetic model has been found to reproduce quantitatively the current vs. potential curves and the impedance spectra for the studied nickel-based alloys in the transpassive region. The proposed mechanism is sensitive to the impact of alloy and electrolyte composition on the dissolution process. Thus it can serve as a starting point to describe the transpassive behaviour of engineering alloys.",
    keywords = "nickel-based alloys, transpassive dissolution, electrochemical impedance spectroscopy (eis), rotating ring-disc electrode (rrde), kinetic model",
    author = "Iva Betova and Martin Bojinov and Petri Kinnunen and Timo Laitinen and Pekka Pohjanne and Timo Saario",
    year = "2002",
    doi = "10.1016/S0013-4686(02)00080-4",
    language = "English",
    volume = "47",
    pages = "2093--2107",
    journal = "Electrochimica Acta",
    issn = "0013-4686",
    publisher = "Elsevier",
    number = "13-14",

    }

    Mechanism of transpassive dissolution of nickel-based alloys studies by impedance spectroscopy and rotating ring-disc voltammetry. / Betova, Iva; Bojinov, Martin (Corresponding Author); Kinnunen, Petri; Laitinen, Timo; Pohjanne, Pekka; Saario, Timo.

    In: Electrochimica Acta, Vol. 47, No. 13-14, 2002, p. 2093-2107.

    Research output: Contribution to journalArticleScientificpeer-review

    TY - JOUR

    T1 - Mechanism of transpassive dissolution of nickel-based alloys studies by impedance spectroscopy and rotating ring-disc voltammetry

    AU - Betova, Iva

    AU - Bojinov, Martin

    AU - Kinnunen, Petri

    AU - Laitinen, Timo

    AU - Pohjanne, Pekka

    AU - Saario, Timo

    PY - 2002

    Y1 - 2002

    N2 - A generalised kinetic model of transpassive dissolution of industrial nickel-based alloys is presented in this paper. It is based on electrochemical impedance spectroscopic (EIS) and rotating ring-disk (RRDE) measurements on several nickel-based alloys in 0.5 M sulphate and chloride solutions with pH ranging from 2 to 7. The model assumes that the dissolution of Cr from the transpassive film occurs via a Cr(VI) surface intermediate species. The dissolution of Ni as Ni(II) is proposed to occur via two parallel paths featuring two reaction intermediates. The role of Fe as a secondary passivating agent and Mo as an accelerator of transpassive dissolution is also taken into account. The kinetic model has been found to reproduce quantitatively the current vs. potential curves and the impedance spectra for the studied nickel-based alloys in the transpassive region. The proposed mechanism is sensitive to the impact of alloy and electrolyte composition on the dissolution process. Thus it can serve as a starting point to describe the transpassive behaviour of engineering alloys.

    AB - A generalised kinetic model of transpassive dissolution of industrial nickel-based alloys is presented in this paper. It is based on electrochemical impedance spectroscopic (EIS) and rotating ring-disk (RRDE) measurements on several nickel-based alloys in 0.5 M sulphate and chloride solutions with pH ranging from 2 to 7. The model assumes that the dissolution of Cr from the transpassive film occurs via a Cr(VI) surface intermediate species. The dissolution of Ni as Ni(II) is proposed to occur via two parallel paths featuring two reaction intermediates. The role of Fe as a secondary passivating agent and Mo as an accelerator of transpassive dissolution is also taken into account. The kinetic model has been found to reproduce quantitatively the current vs. potential curves and the impedance spectra for the studied nickel-based alloys in the transpassive region. The proposed mechanism is sensitive to the impact of alloy and electrolyte composition on the dissolution process. Thus it can serve as a starting point to describe the transpassive behaviour of engineering alloys.

    KW - nickel-based alloys

    KW - transpassive dissolution

    KW - electrochemical impedance spectroscopy (eis)

    KW - rotating ring-disc electrode (rrde)

    KW - kinetic model

    U2 - 10.1016/S0013-4686(02)00080-4

    DO - 10.1016/S0013-4686(02)00080-4

    M3 - Article

    VL - 47

    SP - 2093

    EP - 2107

    JO - Electrochimica Acta

    JF - Electrochimica Acta

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