Metastable Nanobubbles

Tapio Vehmas; Lasse Makkonen

doi:10.1021/acsomega.0c05384

Metastable Nanobubbles

Tapio Vehmas (Corresponding Author), Lasse Makkonen

BA5505 Structural materials

Research output: Contribution to journal › Article › Scientific › peer-review

11 Citations (Scopus)

Abstract

Water containing suspended nanobubbles is utilized in various applications. The observed lifetime of suspended nanobubbles is several weeks, whereas, according to the classical theory of bubble stability, a nanosized bubble should dissolve within microseconds. Explanations for the longevity of nanosized bubbles have been proposed but none of them has gained general acceptance. In this study, we derive an explanation for the existence of metastable nanobubbles solely from the thermodynamic principles. According to our analysis, the dissolution of nanosized aqueous bulk bubbles is nonspontaneous below 180 nm diameter due to the energy requirement of gas dissolution. Hydrophobic surfaces have a further stabilizing effect, and the dissolution becomes nonspontaneous in surface nanobubbles having a diameter below 600 nm.

Original language	English
Pages (from-to)	8021-8027
Number of pages	7
Journal	ACS Omega
Volume	6
Issue number	12
DOIs	https://doi.org/10.1021/acsomega.0c05384
Publication status	Published - 30 Mar 2021
MoE publication type	A1 Journal article-refereed

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title = "Metastable Nanobubbles",

abstract = "Water containing suspended nanobubbles is utilized in various applications. The observed lifetime of suspended nanobubbles is several weeks, whereas, according to the classical theory of bubble stability, a nanosized bubble should dissolve within microseconds. Explanations for the longevity of nanosized bubbles have been proposed but none of them has gained general acceptance. In this study, we derive an explanation for the existence of metastable nanobubbles solely from the thermodynamic principles. According to our analysis, the dissolution of nanosized aqueous bulk bubbles is nonspontaneous below 180 nm diameter due to the energy requirement of gas dissolution. Hydrophobic surfaces have a further stabilizing effect, and the dissolution becomes nonspontaneous in surface nanobubbles having a diameter below 600 nm.",

author = "Tapio Vehmas and Lasse Makkonen",

note = "Funding Information: This work was supported by the Academy of Finland, grant 297278. Publisher Copyright: {\textcopyright} 2021 The Authors. Published by American Chemical Society.",

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doi = "10.1021/acsomega.0c05384",

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AU - Makkonen, Lasse

PY - 2021/3/30

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N2 - Water containing suspended nanobubbles is utilized in various applications. The observed lifetime of suspended nanobubbles is several weeks, whereas, according to the classical theory of bubble stability, a nanosized bubble should dissolve within microseconds. Explanations for the longevity of nanosized bubbles have been proposed but none of them has gained general acceptance. In this study, we derive an explanation for the existence of metastable nanobubbles solely from the thermodynamic principles. According to our analysis, the dissolution of nanosized aqueous bulk bubbles is nonspontaneous below 180 nm diameter due to the energy requirement of gas dissolution. Hydrophobic surfaces have a further stabilizing effect, and the dissolution becomes nonspontaneous in surface nanobubbles having a diameter below 600 nm.

AB - Water containing suspended nanobubbles is utilized in various applications. The observed lifetime of suspended nanobubbles is several weeks, whereas, according to the classical theory of bubble stability, a nanosized bubble should dissolve within microseconds. Explanations for the longevity of nanosized bubbles have been proposed but none of them has gained general acceptance. In this study, we derive an explanation for the existence of metastable nanobubbles solely from the thermodynamic principles. According to our analysis, the dissolution of nanosized aqueous bulk bubbles is nonspontaneous below 180 nm diameter due to the energy requirement of gas dissolution. Hydrophobic surfaces have a further stabilizing effect, and the dissolution becomes nonspontaneous in surface nanobubbles having a diameter below 600 nm.

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JO - ACS Omega

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Metastable Nanobubbles

Abstract

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