Microdomains occurrence in the LixFePS3 intercalates

A Mössbauer and ESR spectroscopy study

P. Colombet, G. Ouvrard, Olli Antson (Corresponding Author), R. Brec

Research output: Contribution to journalArticleScientificpeer-review

11 Citations (Scopus)

Abstract

The LixMPS3 (M = first row transition-metal) lamellar intercalation compounds, together with the corresponding host structures, have been studied using ESR and, as far as the iron-containing materials are concerned, Mössbauer spectroscopy. The results can be interpreted assuming that the reduced metallic sites in the intercalates are markedly segregated so that two kinds of microdomains are formed. One of them exhibits unchanged MPS3-type properties.
Original languageEnglish
Pages (from-to)100-110
JournalJournal of Magnetism and Magnetic Materials
Volume71
Issue number1
DOIs
Publication statusPublished - 1987
MoE publication typeA1 Journal article-refereed

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Intercalation compounds
intercalation
Transition metals
Paramagnetic resonance
Iron
transition metals
Spectroscopy
occurrences
iron
spectroscopy

Cite this

Colombet, P. ; Ouvrard, G. ; Antson, Olli ; Brec, R. / Microdomains occurrence in the LixFePS3 intercalates : A Mössbauer and ESR spectroscopy study. In: Journal of Magnetism and Magnetic Materials. 1987 ; Vol. 71, No. 1. pp. 100-110.
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Microdomains occurrence in the LixFePS3 intercalates : A Mössbauer and ESR spectroscopy study. / Colombet, P.; Ouvrard, G.; Antson, Olli (Corresponding Author); Brec, R.

In: Journal of Magnetism and Magnetic Materials, Vol. 71, No. 1, 1987, p. 100-110.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Microdomains occurrence in the LixFePS3 intercalates

T2 - A Mössbauer and ESR spectroscopy study

AU - Colombet, P.

AU - Ouvrard, G.

AU - Antson, Olli

AU - Brec, R.

PY - 1987

Y1 - 1987

N2 - The LixMPS3 (M = first row transition-metal) lamellar intercalation compounds, together with the corresponding host structures, have been studied using ESR and, as far as the iron-containing materials are concerned, Mössbauer spectroscopy. The results can be interpreted assuming that the reduced metallic sites in the intercalates are markedly segregated so that two kinds of microdomains are formed. One of them exhibits unchanged MPS3-type properties.

AB - The LixMPS3 (M = first row transition-metal) lamellar intercalation compounds, together with the corresponding host structures, have been studied using ESR and, as far as the iron-containing materials are concerned, Mössbauer spectroscopy. The results can be interpreted assuming that the reduced metallic sites in the intercalates are markedly segregated so that two kinds of microdomains are formed. One of them exhibits unchanged MPS3-type properties.

U2 - 10.1016/0304-8853(87)90338-6

DO - 10.1016/0304-8853(87)90338-6

M3 - Article

VL - 71

SP - 100

EP - 110

JO - Journal of Magnetism and Magnetic Materials

JF - Journal of Magnetism and Magnetic Materials

SN - 0304-8853

IS - 1

ER -