Microdomains occurrence in the LixFePS3 intercalates: A Mössbauer and ESR spectroscopy study

P. Colombet, G. Ouvrard, Olli Antson (Corresponding Author), R. Brec

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The LixMPS3 (M = first row transition-metal) lamellar intercalation compounds, together with the corresponding host structures, have been studied using ESR and, as far as the iron-containing materials are concerned, Mössbauer spectroscopy. The results can be interpreted assuming that the reduced metallic sites in the intercalates are markedly segregated so that two kinds of microdomains are formed. One of them exhibits unchanged MPS3-type properties.
Original languageEnglish
Pages (from-to)100-110
JournalJournal of Magnetism and Magnetic Materials
Issue number1
Publication statusPublished - 1987
MoE publication typeA1 Journal article-refereed


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