Microdomains occurrence in the LixFePS3 intercalates: A Mössbauer and ESR spectroscopy study

P. Colombet; G. Ouvrard; Olli Antson; R. Brec

doi:10.1016/0304-8853(87)90338-6

Microdomains occurrence in the LixFePS3 intercalates: A Mössbauer and ESR spectroscopy study

P. Colombet, G. Ouvrard, Olli Antson (Corresponding Author), R. Brec

University of Nantes

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Abstract

The LixMPS3 (M = first row transition-metal) lamellar intercalation compounds, together with the corresponding host structures, have been studied using ESR and, as far as the iron-containing materials are concerned, Mössbauer spectroscopy. The results can be interpreted assuming that the reduced metallic sites in the intercalates are markedly segregated so that two kinds of microdomains are formed. One of them exhibits unchanged MPS3-type properties.

Original language	English
Pages (from-to)	100-110
Journal	Journal of Magnetism and Magnetic Materials
Volume	71
Issue number	1
DOIs	https://doi.org/10.1016/0304-8853(87)90338-6
Publication status	Published - 1987
MoE publication type	A1 Journal article-refereed

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title = "Microdomains occurrence in the LixFePS3 intercalates: A M{\"o}ssbauer and ESR spectroscopy study",

abstract = "The LixMPS3 (M = first row transition-metal) lamellar intercalation compounds, together with the corresponding host structures, have been studied using ESR and, as far as the iron-containing materials are concerned, M{\"o}ssbauer spectroscopy. The results can be interpreted assuming that the reduced metallic sites in the intercalates are markedly segregated so that two kinds of microdomains are formed. One of them exhibits unchanged MPS3-type properties.",

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T2 - A Mössbauer and ESR spectroscopy study

AU - Colombet, P.

AU - Ouvrard, G.

AU - Antson, Olli

AU - Brec, R.

PY - 1987

Y1 - 1987

N2 - The LixMPS3 (M = first row transition-metal) lamellar intercalation compounds, together with the corresponding host structures, have been studied using ESR and, as far as the iron-containing materials are concerned, Mössbauer spectroscopy. The results can be interpreted assuming that the reduced metallic sites in the intercalates are markedly segregated so that two kinds of microdomains are formed. One of them exhibits unchanged MPS3-type properties.

AB - The LixMPS3 (M = first row transition-metal) lamellar intercalation compounds, together with the corresponding host structures, have been studied using ESR and, as far as the iron-containing materials are concerned, Mössbauer spectroscopy. The results can be interpreted assuming that the reduced metallic sites in the intercalates are markedly segregated so that two kinds of microdomains are formed. One of them exhibits unchanged MPS3-type properties.

U2 - 10.1016/0304-8853(87)90338-6

DO - 10.1016/0304-8853(87)90338-6

M3 - Article

SN - 0304-8853

VL - 71

SP - 100

EP - 110

JO - Journal of Magnetism and Magnetic Materials

JF - Journal of Magnetism and Magnetic Materials

IS - 1

ER -

Microdomains occurrence in the LixFePS3 intercalates: A Mössbauer and ESR spectroscopy study

Abstract

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