Microstructural and physicochemical properties of oxidized potato starch for paper coating

Karin Autio, Tapani Suortti, Kaisa Poutanen, Antti Hamunen

    Research output: Contribution to journalArticleScientificpeer-review

    30 Citations (Scopus)


    Heat‐induced structural changes were examined for a series of potato starches differing in degree of oxidation and prepared as 25 and 35% dispersions. The molecular weight of amylopectin decreased markedly with the degree of oxidation. Microstructural studies revealed that all oxidized potato starch dispersions heated to 90deg;C contained whole granules. The least oxidized potato starch (Raisamyl 316) paste contained large numbers of swollen granules filled with dissolved amylose. In the more oxidized potato starch dispersions, both amylopectin and amylose were solubilized within the granule. Mixing of the amylose and amylopectin occurred and amylose‐ and amylopectin‐rich domains could be seen inside the granule. At 35% concentration all starches studied formed a gel during cooling (from 90 to 30deg;C). The lower the degree of oxidation, the higher the gelling temperature. Raisamyl 310 formed the firmest gel. The gel formation of most oxidized potato starches was weak. Raising the heating temperature from 90 to 120deg;C, in combination with shearing, delayed the gelation.
    Original languageEnglish
    Pages (from-to)393-398
    Number of pages6
    Issue number10
    Publication statusPublished - 1992
    MoE publication typeA1 Journal article-refereed


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