Modeling of nickel-based hydrotalcite catalyst coated on heat exchanger reactors for CO2 methanation

Francisco Vidal Vázquez, Johanna Kihlman, Ajenthan Mylvaganam, Pekka Simell, Mari Leena Koskinen-Soivi, Ville Alopaeus

    Research output: Contribution to journalArticleScientificpeer-review

    3 Citations (Scopus)

    Abstract

    This study presents the kinetic modeling of CO2 methanation reaction using 15 wt% Ni/Mg/Al hydrotalcite coated catalyst. Power law and Langmuir-Hinshelwood-Hougens-Watson (LHHW) models were used to represent the kinetics of CO2 methanation. LHHW model displayed better representation of the kinetics and was chosen for modeling the CO2 methanation reaction in a plate type heat exchanger reactor. Comparison between experiments, 1D model, and 2D model proved the reliability of using internally coated tubular reactor for kinetic modeling of coated catalyst. This work also performed modeling of a plate type heat exchanger reactor with catalytically coated corrugated plates for CO2 methanation. Heat exchanger reactors with coated catalyst allow controlling the reaction temperature and thus, avoiding temperature runaway owing to the highly exothermic CO2 methanation reaction. The corrugated pattern created by the opposing corrugated plates of the plate heat exchanger reactor proved to be excellent for distributing the flow homogeneously inside each reaction channel and the entire reactor. In this reactor, 92% CO2 conversion was achieved at GHSV = 4400 h−1, 573 K and 5 bar. The good performance of this reactor was due to the high activity displayed by Ni-hydrotalcite coated catalyst, homogeneous flow distribution and high surface area of the reactor. Thus, plate type heat exchanger reactor with catalytically coated corrugated plates proved to be suitable alternative to plate heat exchanger reactors with microchannel plates.

    Original languageEnglish
    Pages (from-to)694-707
    Number of pages14
    JournalChemical Engineering Journal
    Volume349
    DOIs
    Publication statusPublished - 1 Oct 2018
    MoE publication typeA1 Journal article-refereed

    Fingerprint

    hydrotalcite
    Methanation
    Nickel
    Heat exchangers
    nickel
    catalyst
    Catalysts
    modeling
    Kinetics
    kinetics
    Microchannels
    reactor

    Keywords

    • Carbon capture and utilization
    • CO methanation
    • Coated catalyst
    • Heat exchanger reactor
    • Hydrotalcite
    • Reactor modeling

    Cite this

    Vidal Vázquez, Francisco ; Kihlman, Johanna ; Mylvaganam, Ajenthan ; Simell, Pekka ; Koskinen-Soivi, Mari Leena ; Alopaeus, Ville. / Modeling of nickel-based hydrotalcite catalyst coated on heat exchanger reactors for CO2 methanation. In: Chemical Engineering Journal. 2018 ; Vol. 349. pp. 694-707.
    @article{47f7f47c89754ec8893cf6e52fb3db6b,
    title = "Modeling of nickel-based hydrotalcite catalyst coated on heat exchanger reactors for CO2 methanation",
    abstract = "This study presents the kinetic modeling of CO2 methanation reaction using 15 wt{\%} Ni/Mg/Al hydrotalcite coated catalyst. Power law and Langmuir-Hinshelwood-Hougens-Watson (LHHW) models were used to represent the kinetics of CO2 methanation. LHHW model displayed better representation of the kinetics and was chosen for modeling the CO2 methanation reaction in a plate type heat exchanger reactor. Comparison between experiments, 1D model, and 2D model proved the reliability of using internally coated tubular reactor for kinetic modeling of coated catalyst. This work also performed modeling of a plate type heat exchanger reactor with catalytically coated corrugated plates for CO2 methanation. Heat exchanger reactors with coated catalyst allow controlling the reaction temperature and thus, avoiding temperature runaway owing to the highly exothermic CO2 methanation reaction. The corrugated pattern created by the opposing corrugated plates of the plate heat exchanger reactor proved to be excellent for distributing the flow homogeneously inside each reaction channel and the entire reactor. In this reactor, 92{\%} CO2 conversion was achieved at GHSV = 4400 h−1, 573 K and 5 bar. The good performance of this reactor was due to the high activity displayed by Ni-hydrotalcite coated catalyst, homogeneous flow distribution and high surface area of the reactor. Thus, plate type heat exchanger reactor with catalytically coated corrugated plates proved to be suitable alternative to plate heat exchanger reactors with microchannel plates.",
    keywords = "Carbon capture and utilization, CO methanation, Coated catalyst, Heat exchanger reactor, Hydrotalcite, Reactor modeling",
    author = "{Vidal V{\'a}zquez}, Francisco and Johanna Kihlman and Ajenthan Mylvaganam and Pekka Simell and Koskinen-Soivi, {Mari Leena} and Ville Alopaeus",
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    Modeling of nickel-based hydrotalcite catalyst coated on heat exchanger reactors for CO2 methanation. / Vidal Vázquez, Francisco; Kihlman, Johanna; Mylvaganam, Ajenthan; Simell, Pekka; Koskinen-Soivi, Mari Leena; Alopaeus, Ville.

    In: Chemical Engineering Journal, Vol. 349, 01.10.2018, p. 694-707.

    Research output: Contribution to journalArticleScientificpeer-review

    TY - JOUR

    T1 - Modeling of nickel-based hydrotalcite catalyst coated on heat exchanger reactors for CO2 methanation

    AU - Vidal Vázquez, Francisco

    AU - Kihlman, Johanna

    AU - Mylvaganam, Ajenthan

    AU - Simell, Pekka

    AU - Koskinen-Soivi, Mari Leena

    AU - Alopaeus, Ville

    PY - 2018/10/1

    Y1 - 2018/10/1

    N2 - This study presents the kinetic modeling of CO2 methanation reaction using 15 wt% Ni/Mg/Al hydrotalcite coated catalyst. Power law and Langmuir-Hinshelwood-Hougens-Watson (LHHW) models were used to represent the kinetics of CO2 methanation. LHHW model displayed better representation of the kinetics and was chosen for modeling the CO2 methanation reaction in a plate type heat exchanger reactor. Comparison between experiments, 1D model, and 2D model proved the reliability of using internally coated tubular reactor for kinetic modeling of coated catalyst. This work also performed modeling of a plate type heat exchanger reactor with catalytically coated corrugated plates for CO2 methanation. Heat exchanger reactors with coated catalyst allow controlling the reaction temperature and thus, avoiding temperature runaway owing to the highly exothermic CO2 methanation reaction. The corrugated pattern created by the opposing corrugated plates of the plate heat exchanger reactor proved to be excellent for distributing the flow homogeneously inside each reaction channel and the entire reactor. In this reactor, 92% CO2 conversion was achieved at GHSV = 4400 h−1, 573 K and 5 bar. The good performance of this reactor was due to the high activity displayed by Ni-hydrotalcite coated catalyst, homogeneous flow distribution and high surface area of the reactor. Thus, plate type heat exchanger reactor with catalytically coated corrugated plates proved to be suitable alternative to plate heat exchanger reactors with microchannel plates.

    AB - This study presents the kinetic modeling of CO2 methanation reaction using 15 wt% Ni/Mg/Al hydrotalcite coated catalyst. Power law and Langmuir-Hinshelwood-Hougens-Watson (LHHW) models were used to represent the kinetics of CO2 methanation. LHHW model displayed better representation of the kinetics and was chosen for modeling the CO2 methanation reaction in a plate type heat exchanger reactor. Comparison between experiments, 1D model, and 2D model proved the reliability of using internally coated tubular reactor for kinetic modeling of coated catalyst. This work also performed modeling of a plate type heat exchanger reactor with catalytically coated corrugated plates for CO2 methanation. Heat exchanger reactors with coated catalyst allow controlling the reaction temperature and thus, avoiding temperature runaway owing to the highly exothermic CO2 methanation reaction. The corrugated pattern created by the opposing corrugated plates of the plate heat exchanger reactor proved to be excellent for distributing the flow homogeneously inside each reaction channel and the entire reactor. In this reactor, 92% CO2 conversion was achieved at GHSV = 4400 h−1, 573 K and 5 bar. The good performance of this reactor was due to the high activity displayed by Ni-hydrotalcite coated catalyst, homogeneous flow distribution and high surface area of the reactor. Thus, plate type heat exchanger reactor with catalytically coated corrugated plates proved to be suitable alternative to plate heat exchanger reactors with microchannel plates.

    KW - Carbon capture and utilization

    KW - CO methanation

    KW - Coated catalyst

    KW - Heat exchanger reactor

    KW - Hydrotalcite

    KW - Reactor modeling

    UR - http://www.scopus.com/inward/record.url?scp=85047395369&partnerID=8YFLogxK

    U2 - 10.1016/j.cej.2018.05.119

    DO - 10.1016/j.cej.2018.05.119

    M3 - Article

    VL - 349

    SP - 694

    EP - 707

    JO - Chemical Engineering Journal

    JF - Chemical Engineering Journal

    SN - 1385-8947

    ER -