Modeling the Interaction Between Compacted Bentonite Clay and Hyperalkaline Solution

    Research output: Chapter in Book/Report/Conference proceedingConference article in proceedingsScientificpeer-review

    Abstract

    Spent nuclear fuel is planned to be disposed of in deep underground repositories in many countries, including Finland. An essential part of the Finnish final repository concept is a compacted bentonite buffer. Unfortunately, experimental work is only of limited use when predicting the long-term stability of bentonite in repository conditions, and therefore complementary modeling tools and method development are needed to gain confidence in the safety of the disposal. This work involves the modeling of the chemical interaction between inflowing hyperalkaline solution—envisaged to constitute a risk to the long-term chemical stability of the buffer—and bentonite clay in a column filled with crushed rock and compacted bentonite. The main interest was in the cation-exchange equilibria and mineral alterations in bentonite. TOUGHREACT was found to be a useful modeling tool in stability studies of the bentonite. Especially good results were gained for the cation-exchanger composition.
    Original languageEnglish
    Title of host publicationProceedings of the TOUGH Symposium 2009
    Subtitle of host publicationSeptember 14—16, 2009
    Place of PublicationBerkeley
    Pages277-282
    Publication statusPublished - 2009
    MoE publication typeA4 Article in a conference publication
    EventTOUGH Symposium 2009 - Berkeley, United States
    Duration: 14 Sep 200916 Sep 2009

    Conference

    ConferenceTOUGH Symposium 2009
    CountryUnited States
    CityBerkeley
    Period14/09/0916/09/09

    Fingerprint

    bentonite
    clay
    repository
    modeling
    mineral alteration
    ion exchange
    cation
    safety
    rock

    Keywords

    • THC
    • bentonite
    • modelling
    • cement

    Cite this

    Tanhua-Tyrkkö, M., Olin, M., & Lehikoinen, J. (2009). Modeling the Interaction Between Compacted Bentonite Clay and Hyperalkaline Solution. In Proceedings of the TOUGH Symposium 2009: September 14—16, 2009 (pp. 277-282). Berkeley.
    Tanhua-Tyrkkö, Merja ; Olin, Markus ; Lehikoinen, Jarmo. / Modeling the Interaction Between Compacted Bentonite Clay and Hyperalkaline Solution. Proceedings of the TOUGH Symposium 2009: September 14—16, 2009. Berkeley, 2009. pp. 277-282
    @inproceedings{010f18924d784f3bb80a33980d0c7ced,
    title = "Modeling the Interaction Between Compacted Bentonite Clay and Hyperalkaline Solution",
    abstract = "Spent nuclear fuel is planned to be disposed of in deep underground repositories in many countries, including Finland. An essential part of the Finnish final repository concept is a compacted bentonite buffer. Unfortunately, experimental work is only of limited use when predicting the long-term stability of bentonite in repository conditions, and therefore complementary modeling tools and method development are needed to gain confidence in the safety of the disposal. This work involves the modeling of the chemical interaction between inflowing hyperalkaline solution—envisaged to constitute a risk to the long-term chemical stability of the buffer—and bentonite clay in a column filled with crushed rock and compacted bentonite. The main interest was in the cation-exchange equilibria and mineral alterations in bentonite. TOUGHREACT was found to be a useful modeling tool in stability studies of the bentonite. Especially good results were gained for the cation-exchanger composition.",
    keywords = "THC, bentonite, modelling, cement",
    author = "Merja Tanhua-Tyrkk{\"o} and Markus Olin and Jarmo Lehikoinen",
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    language = "English",
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    booktitle = "Proceedings of the TOUGH Symposium 2009",

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    Tanhua-Tyrkkö, M, Olin, M & Lehikoinen, J 2009, Modeling the Interaction Between Compacted Bentonite Clay and Hyperalkaline Solution. in Proceedings of the TOUGH Symposium 2009: September 14—16, 2009. Berkeley, pp. 277-282, TOUGH Symposium 2009, Berkeley, United States, 14/09/09.

    Modeling the Interaction Between Compacted Bentonite Clay and Hyperalkaline Solution. / Tanhua-Tyrkkö, Merja; Olin, Markus; Lehikoinen, Jarmo.

    Proceedings of the TOUGH Symposium 2009: September 14—16, 2009. Berkeley, 2009. p. 277-282.

    Research output: Chapter in Book/Report/Conference proceedingConference article in proceedingsScientificpeer-review

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    AB - Spent nuclear fuel is planned to be disposed of in deep underground repositories in many countries, including Finland. An essential part of the Finnish final repository concept is a compacted bentonite buffer. Unfortunately, experimental work is only of limited use when predicting the long-term stability of bentonite in repository conditions, and therefore complementary modeling tools and method development are needed to gain confidence in the safety of the disposal. This work involves the modeling of the chemical interaction between inflowing hyperalkaline solution—envisaged to constitute a risk to the long-term chemical stability of the buffer—and bentonite clay in a column filled with crushed rock and compacted bentonite. The main interest was in the cation-exchange equilibria and mineral alterations in bentonite. TOUGHREACT was found to be a useful modeling tool in stability studies of the bentonite. Especially good results were gained for the cation-exchanger composition.

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    Tanhua-Tyrkkö M, Olin M, Lehikoinen J. Modeling the Interaction Between Compacted Bentonite Clay and Hyperalkaline Solution. In Proceedings of the TOUGH Symposium 2009: September 14—16, 2009. Berkeley. 2009. p. 277-282