@inbook{beec87c68dc14096bb208833cd0033f4,
title = "Modelling partial equilibria during steel solidification",
abstract = "The back diffusion of a solidifying system under local equilibrium conditions can be simulated by using immaterial constraints as set to the (stoichiometric) conservation matrix of the alloy mixture. In a solidifying alloy, complete diffusion between the liquid and solid portions is often found for chemical components with small atoms which dissolve interstitially in the solid state. Carbon in steels is a classical example. The constrained Gibbs energy method appears to be a useful technique to incorporate the necessary restrictions for those components, which are not allowed to diffuse in the solidifying system, while the interstitial components can reach their partial equilibria.",
author = "Klaus Hack and Risto Pajarre and Pertti Koukkari",
note = "Project code: 26639",
year = "2009",
language = "English",
isbn = "978-951-38-7330-1",
series = "VTT Tiedotteita - Research Notes",
publisher = "VTT Technical Research Centre of Finland",
number = "2506",
pages = "59--64",
booktitle = "Advanced Gibbs Energy Methods for Functional Materials and Processes",
address = "Finland",
}