Molecular speciation of sulfur in solid oxide fuel cell anodes with X-ray absorption spectroscopy

A. Braun (Corresponding Author), M. Janousch, J. Sfeir, Jari Kiviaho, Matti Noponen, F. E. Huggins, M. J. Smith, R. Steinberger-Wilckens, P. Holtappels, T. Graule

Research output: Contribution to journalArticleScientificpeer-review

20 Citations (Scopus)

Abstract

Two sets of solid oxide fuel cell (SOFC) electrode assemblies from different manufacturers were run under different operating conditions with different sulfur exposure, and then subjected to X-ray absorption spectroscopy (XAS) at the sulfur K (1s) edge. Within the detection limits of the spectrometer, pristine fuel electrodes (anodes) show no traces of sulfur. The anodes operated with sulfur-containing natural gas and H2S doped natural gas show spectra rich in sulfur structures. Two other electrodes run with sulfur-containing natural gas, one with a sulfur filter and the other without, show an XAS spectrum with a very broad peak, covering the entire sulfur absorption range, and thus not allowing for identification of specific sulfur signatures. These appear to be the first ever reported sulfur XAS data on SOFC anodes, and the XAS technique shows promise to resolve some hitherto unsolved issues on sulfur poisoning of SOFC, particularly regarding the molecular speciation of the sulfur components.
Original languageEnglish
Pages (from-to)564 - 570
Number of pages7
JournalJournal of Power Sources
Volume183
Issue number2
DOIs
Publication statusPublished - 2008
MoE publication typeA1 Journal article-refereed

Fingerprint

cell anodes
X ray absorption spectroscopy
solid oxide fuel cells
Solid oxide fuel cells (SOFC)
Sulfur
Anodes
absorption spectroscopy
sulfur
x rays
natural gas
Natural gas
Electrodes
electrodes
anodes
poisoning
assemblies
Spectrometers

Keywords

  • SOFC
  • sulfur
  • sulphur
  • anode
  • poisoning
  • molecular speciation
  • thiophene
  • X-ray absorption
  • spectroscopy
  • XANES

Cite this

Braun, A. ; Janousch, M. ; Sfeir, J. ; Kiviaho, Jari ; Noponen, Matti ; Huggins, F. E. ; Smith, M. J. ; Steinberger-Wilckens, R. ; Holtappels, P. ; Graule, T. / Molecular speciation of sulfur in solid oxide fuel cell anodes with X-ray absorption spectroscopy. In: Journal of Power Sources. 2008 ; Vol. 183, No. 2. pp. 564 - 570.
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title = "Molecular speciation of sulfur in solid oxide fuel cell anodes with X-ray absorption spectroscopy",
abstract = "Two sets of solid oxide fuel cell (SOFC) electrode assemblies from different manufacturers were run under different operating conditions with different sulfur exposure, and then subjected to X-ray absorption spectroscopy (XAS) at the sulfur K (1s) edge. Within the detection limits of the spectrometer, pristine fuel electrodes (anodes) show no traces of sulfur. The anodes operated with sulfur-containing natural gas and H2S doped natural gas show spectra rich in sulfur structures. Two other electrodes run with sulfur-containing natural gas, one with a sulfur filter and the other without, show an XAS spectrum with a very broad peak, covering the entire sulfur absorption range, and thus not allowing for identification of specific sulfur signatures. These appear to be the first ever reported sulfur XAS data on SOFC anodes, and the XAS technique shows promise to resolve some hitherto unsolved issues on sulfur poisoning of SOFC, particularly regarding the molecular speciation of the sulfur components.",
keywords = "SOFC, sulfur, sulphur, anode, poisoning, molecular speciation, thiophene, X-ray absorption, spectroscopy, XANES",
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year = "2008",
doi = "10.1016/j.jpowsour.2008.05.048",
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Braun, A, Janousch, M, Sfeir, J, Kiviaho, J, Noponen, M, Huggins, FE, Smith, MJ, Steinberger-Wilckens, R, Holtappels, P & Graule, T 2008, 'Molecular speciation of sulfur in solid oxide fuel cell anodes with X-ray absorption spectroscopy', Journal of Power Sources, vol. 183, no. 2, pp. 564 - 570. https://doi.org/10.1016/j.jpowsour.2008.05.048

Molecular speciation of sulfur in solid oxide fuel cell anodes with X-ray absorption spectroscopy. / Braun, A. (Corresponding Author); Janousch, M.; Sfeir, J.; Kiviaho, Jari; Noponen, Matti; Huggins, F. E.; Smith, M. J.; Steinberger-Wilckens, R.; Holtappels, P.; Graule, T.

In: Journal of Power Sources, Vol. 183, No. 2, 2008, p. 564 - 570.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Molecular speciation of sulfur in solid oxide fuel cell anodes with X-ray absorption spectroscopy

AU - Braun, A.

AU - Janousch, M.

AU - Sfeir, J.

AU - Kiviaho, Jari

AU - Noponen, Matti

AU - Huggins, F. E.

AU - Smith, M. J.

AU - Steinberger-Wilckens, R.

AU - Holtappels, P.

AU - Graule, T.

PY - 2008

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AB - Two sets of solid oxide fuel cell (SOFC) electrode assemblies from different manufacturers were run under different operating conditions with different sulfur exposure, and then subjected to X-ray absorption spectroscopy (XAS) at the sulfur K (1s) edge. Within the detection limits of the spectrometer, pristine fuel electrodes (anodes) show no traces of sulfur. The anodes operated with sulfur-containing natural gas and H2S doped natural gas show spectra rich in sulfur structures. Two other electrodes run with sulfur-containing natural gas, one with a sulfur filter and the other without, show an XAS spectrum with a very broad peak, covering the entire sulfur absorption range, and thus not allowing for identification of specific sulfur signatures. These appear to be the first ever reported sulfur XAS data on SOFC anodes, and the XAS technique shows promise to resolve some hitherto unsolved issues on sulfur poisoning of SOFC, particularly regarding the molecular speciation of the sulfur components.

KW - SOFC

KW - sulfur

KW - sulphur

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KW - molecular speciation

KW - thiophene

KW - X-ray absorption

KW - spectroscopy

KW - XANES

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SP - 564

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JF - Journal of Power Sources

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