Multicomb polymeric supramolecules and their self-organization: Combination of coordination and ionic interactions

Sami Valkama, Olli Lehtonen, Kristian Lappalainen, Harri Kosonen, Pascal Castro, Timo Repo, Mika Torkkeli, Ritva Serimaa, Gerrit ten Brinke, Markku Leskelä, Olli Ikkala (Corresponding Author)

Research output: Contribution to journalArticleScientificpeer-review

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Abstract

Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self‐organized structures. 2,6‐Bis(octylaminomethyl)pyridine is Zn‐coordinated to poly(4‐vinylpyridine) (P4VP) with dodecylbenzenesulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6‐bis(octylaminomethyl)pyridine)(DBS)2]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self‐organized structures are characterized using X‐ray measurements.
Original languageEnglish
Pages (from-to)556-560
JournalMacromolecular Rapid Communications
Volume24
Issue number9
DOIs
Publication statusPublished - 2003
MoE publication typeA1 Journal article-refereed

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Pyridine
Infrared spectroscopy
Ligands
pyridine

Cite this

Valkama, Sami ; Lehtonen, Olli ; Lappalainen, Kristian ; Kosonen, Harri ; Castro, Pascal ; Repo, Timo ; Torkkeli, Mika ; Serimaa, Ritva ; Brinke, Gerrit ten ; Leskelä, Markku ; Ikkala, Olli. / Multicomb polymeric supramolecules and their self-organization : Combination of coordination and ionic interactions. In: Macromolecular Rapid Communications. 2003 ; Vol. 24, No. 9. pp. 556-560.
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title = "Multicomb polymeric supramolecules and their self-organization: Combination of coordination and ionic interactions",
abstract = "Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self‐organized structures. 2,6‐Bis(octylaminomethyl)pyridine is Zn‐coordinated to poly(4‐vinylpyridine) (P4VP) with dodecylbenzenesulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6‐bis(octylaminomethyl)pyridine)(DBS)2]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self‐organized structures are characterized using X‐ray measurements.",
author = "Sami Valkama and Olli Lehtonen and Kristian Lappalainen and Harri Kosonen and Pascal Castro and Timo Repo and Mika Torkkeli and Ritva Serimaa and Brinke, {Gerrit ten} and Markku Leskel{\"a} and Olli Ikkala",
year = "2003",
doi = "10.1002/marc.200390084",
language = "English",
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Valkama, S, Lehtonen, O, Lappalainen, K, Kosonen, H, Castro, P, Repo, T, Torkkeli, M, Serimaa, R, Brinke, GT, Leskelä, M & Ikkala, O 2003, 'Multicomb polymeric supramolecules and their self-organization: Combination of coordination and ionic interactions', Macromolecular Rapid Communications, vol. 24, no. 9, pp. 556-560. https://doi.org/10.1002/marc.200390084

Multicomb polymeric supramolecules and their self-organization : Combination of coordination and ionic interactions. / Valkama, Sami; Lehtonen, Olli; Lappalainen, Kristian; Kosonen, Harri; Castro, Pascal; Repo, Timo; Torkkeli, Mika; Serimaa, Ritva; Brinke, Gerrit ten; Leskelä, Markku; Ikkala, Olli (Corresponding Author).

In: Macromolecular Rapid Communications, Vol. 24, No. 9, 2003, p. 556-560.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Multicomb polymeric supramolecules and their self-organization

T2 - Combination of coordination and ionic interactions

AU - Valkama, Sami

AU - Lehtonen, Olli

AU - Lappalainen, Kristian

AU - Kosonen, Harri

AU - Castro, Pascal

AU - Repo, Timo

AU - Torkkeli, Mika

AU - Serimaa, Ritva

AU - Brinke, Gerrit ten

AU - Leskelä, Markku

AU - Ikkala, Olli

PY - 2003

Y1 - 2003

N2 - Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self‐organized structures. 2,6‐Bis(octylaminomethyl)pyridine is Zn‐coordinated to poly(4‐vinylpyridine) (P4VP) with dodecylbenzenesulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6‐bis(octylaminomethyl)pyridine)(DBS)2]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self‐organized structures are characterized using X‐ray measurements.

AB - Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self‐organized structures. 2,6‐Bis(octylaminomethyl)pyridine is Zn‐coordinated to poly(4‐vinylpyridine) (P4VP) with dodecylbenzenesulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6‐bis(octylaminomethyl)pyridine)(DBS)2]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self‐organized structures are characterized using X‐ray measurements.

U2 - 10.1002/marc.200390084

DO - 10.1002/marc.200390084

M3 - Article

VL - 24

SP - 556

EP - 560

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

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