TY - JOUR
T1 - Multicomb polymeric supramolecules and their self-organization
T2 - Combination of coordination and ionic interactions
AU - Valkama, Sami
AU - Lehtonen, Olli
AU - Lappalainen, Kristian
AU - Kosonen, Harri
AU - Castro, Pascal
AU - Repo, Timo
AU - Torkkeli, Mika
AU - Serimaa, Ritva
AU - Brinke, Gerrit ten
AU - Leskelä, Markku
AU - Ikkala, Olli
PY - 2003
Y1 - 2003
N2 - Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self‐organized structures. 2,6‐Bis(octylaminomethyl)pyridine is Zn‐coordinated to poly(4‐vinylpyridine) (P4VP) with dodecylbenzenesulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6‐bis(octylaminomethyl)pyridine)(DBS)2]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self‐organized structures are characterized using X‐ray measurements.
AB - Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self‐organized structures. 2,6‐Bis(octylaminomethyl)pyridine is Zn‐coordinated to poly(4‐vinylpyridine) (P4VP) with dodecylbenzenesulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6‐bis(octylaminomethyl)pyridine)(DBS)2]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self‐organized structures are characterized using X‐ray measurements.
U2 - 10.1002/marc.200390084
DO - 10.1002/marc.200390084
M3 - Article
SN - 1022-1336
VL - 24
SP - 556
EP - 560
JO - Macromolecular Rapid Communications
JF - Macromolecular Rapid Communications
IS - 9
ER -