Multicomb polymeric supramolecules and their self-organization: Combination of coordination and ionic interactions

Sami Valkama; Olli Lehtonen; Kristian Lappalainen; Harri Kosonen; Pascal Castro; Timo Repo; Mika Torkkeli; Ritva Serimaa; Gerrit ten Brinke; Markku Leskelä; Olli Ikkala

doi:10.1002/marc.200390084

Multicomb polymeric supramolecules and their self-organization: Combination of coordination and ionic interactions

Sami Valkama
, Olli Lehtonen
, Kristian Lappalainen
, Harri Kosonen
, Pascal Castro
, Timo Repo
, Mika Torkkeli
, Ritva Serimaa
, Gerrit ten Brinke
, Markku Leskelä
, Olli Ikkala^*

^*Corresponding author for this work

VTT Technical Research Centre of Finland

Research output: Contribution to journal › Article › Scientific › peer-review

59 Citations (Scopus)

Abstract

Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self-organized structures. 2,6-Bis(octylaminomethyl)pyridine is Zn-coordinated to poly(4-vinylpyridine) (P4VP) with dodecylbenzenesulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6-bis(octylaminomethyl)pyridine)(DBS)₂]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self-organized structures are characterized using X-ray measurements.

Original language	English
Pages (from-to)	556-560
Journal	Macromolecular Rapid Communications
Volume	24
Issue number	9
DOIs	https://doi.org/10.1002/marc.200390084
Publication status	Published - 2003
MoE publication type	A1 Journal article-refereed

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title = "Multicomb polymeric supramolecules and their self-organization: Combination of coordination and ionic interactions",

abstract = "Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self-organized structures. 2,6-Bis(octylaminomethyl)pyridine is Zn-coordinated to poly(4-vinylpyridine) (P4VP) with dodecylbenzenesulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6-bis(octylaminomethyl)pyridine)(DBS)2]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self-organized structures are characterized using X-ray measurements.",

author = "Sami Valkama and Olli Lehtonen and Kristian Lappalainen and Harri Kosonen and Pascal Castro and Timo Repo and Mika Torkkeli and Ritva Serimaa and Brinke, \{Gerrit ten\} and Markku Leskel{\"a} and Olli Ikkala",

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doi = "10.1002/marc.200390084",

language = "English",

volume = "24",

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TY - JOUR

T1 - Multicomb polymeric supramolecules and their self-organization

T2 - Combination of coordination and ionic interactions

AU - Valkama, Sami

AU - Lehtonen, Olli

AU - Lappalainen, Kristian

AU - Kosonen, Harri

AU - Castro, Pascal

AU - Repo, Timo

AU - Torkkeli, Mika

AU - Serimaa, Ritva

AU - Brinke, Gerrit ten

AU - Leskelä, Markku

AU - Ikkala, Olli

PY - 2003

Y1 - 2003

N2 - Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self-organized structures. 2,6-Bis(octylaminomethyl)pyridine is Zn-coordinated to poly(4-vinylpyridine) (P4VP) with dodecylbenzenesulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6-bis(octylaminomethyl)pyridine)(DBS)2]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self-organized structures are characterized using X-ray measurements.

AB - Several alkyl side chains are bonded to each polymeric repeat unit using both coordinated ligands and electrostatically bound counterions to directly control the interface curvature of the self-organized structures. 2,6-Bis(octylaminomethyl)pyridine is Zn-coordinated to poly(4-vinylpyridine) (P4VP) with dodecylbenzenesulfonate (DBS) counterions, leading to multicomb polymeric supramolecules, poly[(4VP)Zn(2,6-bis(octylaminomethyl)pyridine)(DBS)2]. Coordination is evidenced by infrared spectroscopy and visualized by quantum chemical calculations. The amorphous hexagonal self-organized structures are characterized using X-ray measurements.

U2 - 10.1002/marc.200390084

DO - 10.1002/marc.200390084

M3 - Article

SN - 1022-1336

VL - 24

SP - 556

EP - 560

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 9

ER -

Multicomb polymeric supramolecules and their self-organization: Combination of coordination and ionic interactions

Abstract

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