Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors

Katrianne Lehtipalo; Chao Yan; Lubna Dada; Federico Bianchi; Mao Xiao; Robert Wagner; Dominik Stolzenburg; Lauri R. Ahonen; Antonio Amorim; Andrea Baccarini; Paulus S. Bauer; Bernhard Baumgartner; Anton Bergen; Anne Kathrin Bernhammer; Martin Breitenlechner; Sophia Brilke; Angela Buchholz; Stephany Buenrostro Mazon; Dexian Chen; Xuemeng Chen; Antonio Dias; Josef Dommen; Danielle C. Draper; Jonathan Duplissy; Mikael Ehn; Henning Finkenzeller; Lukas Fischer; Carla Frege; Claudia Fuchs; Olga Garmash; Hamish Gordon; Jani Hakala; Xucheng He; Liine Heikkinen; Martin Heinritzi; Johanna C. Helm; Victoria Hofbauer; Christopher R. Hoyle; Tuija Jokinen; Juha Kangasluoma; Veli Matti Kerminen; Changhyuk Kim; Jasper Kirkby; Jenni Kontkanen; Andreas Kürten; Michael J. Lawler; Huajun Mai; Serge Mathot; Roy L. Mauldin; Ugo Molteni; Leonid Nichman; Wei Nie; Tuomo Nieminen; Andrea Ojdanic; Antti Onnela; Monica Passananti; Tuukka Petäjä; Felix Piel; Veronika Pospisilova; Lauriane L.J. Quéléver; Matti P. Rissanen; Clémence Rose; Nina Sarnela; Simon Schallhart; Simone Schuchmann; Kamalika Sengupta; Mario Simon; Mikko Sipilä; Christian Tauber; António Tomé; Jasmin Tröstl; Olli Väisänen; Alexander L. Vogel; Rainer Volkamer; Andrea C. Wagner; Mingyi Wang; Lena Weitz; Daniela Wimmer; Penglin Ye; Arttu Ylisirniö; Qiaozhi Zha; Kenneth S. Carslaw; Joachim Curtius; Neil M. Donahue; Richard C. Flagan; Armin Hansel; Ilona Riipinen; Annele Virtanen; Paul M. Winkler; Urs Baltensperger; Markku Kulmala; Douglas R. Worsnop

doi:10.1126/sciadv.aau5363

Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors

Katrianne Lehtipalo, Chao Yan, Lubna Dada, Federico Bianchi, Mao Xiao, Robert Wagner, Dominik Stolzenburg, Lauri R. Ahonen, Antonio Amorim, Andrea Baccarini, Paulus S. Bauer, Bernhard Baumgartner, Anton Bergen, Anne Kathrin Bernhammer, Martin Breitenlechner, Sophia Brilke, Angela Buchholz, Stephany Buenrostro Mazon, Dexian Chen, Xuemeng ChenAntonio Dias, Josef Dommen, Danielle C. Draper, Jonathan Duplissy, Mikael Ehn, Henning Finkenzeller, Lukas Fischer, Carla Frege, Claudia Fuchs, Olga Garmash, Hamish Gordon, Jani Hakala, Xucheng He, Liine Heikkinen, Martin Heinritzi, Johanna C. Helm, Victoria Hofbauer, Christopher R. Hoyle, Tuija Jokinen, Juha Kangasluoma, Veli Matti Kerminen, Changhyuk Kim, Jasper Kirkby, Jenni Kontkanen, Andreas Kürten, Michael J. Lawler, Huajun Mai, Serge Mathot, Roy L. Mauldin, Ugo Molteni, Leonid Nichman, Wei Nie, Tuomo Nieminen, Andrea Ojdanic, Antti Onnela, Monica Passananti, Tuukka Petäjä, Felix Piel, Veronika Pospisilova, Lauriane L.J. Quéléver, Matti P. Rissanen, Clémence Rose, Nina Sarnela, Simon Schallhart, Simone Schuchmann, Kamalika Sengupta, Mario Simon, Mikko Sipilä, Christian Tauber, António Tomé, Jasmin Tröstl, Olli Väisänen, Alexander L. Vogel, Rainer Volkamer, Andrea C. Wagner, Mingyi Wang, Lena Weitz, Daniela Wimmer, Penglin Ye, Arttu Ylisirniö, Qiaozhi Zha, Kenneth S. Carslaw, Joachim Curtius, Neil M. Donahue, Richard C. Flagan, Armin Hansel, Ilona Riipinen, Annele Virtanen, Paul M. Winkler, Urs Baltensperger, Markku Kulmala, Douglas R. Worsnop

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Abstract

A major fraction of atmospheric aerosol particles, which affect both air quality and climate, form from gaseous precursors in the atmosphere. Highly oxygenated organic molecules (HOMs), formed by oxidation of biogenic volatile organic compounds, are known to participate in particle formation and growth. However, it is not well understood how they interact with atmospheric pollutants, such as nitrogen oxides (NO_x) and sulfur oxides (SO_x) from fossil fuel combustion, as well as ammonia (NH₃) from livestock and fertilizers. Here, we show how NO_x suppresses particle formation, while HOMs, sulfuric acid, and NH₃ have a synergistic enhancing effect on particle formation. We postulate a novel mechanism, involving HOMs, sulfuric acid, and ammonia, which is able to closely reproduce observations of particle formation and growth in daytime boreal forest and similar environments. The findings elucidate the complex interactions between biogenic and anthropogenic vapors in the atmospheric aerosol system.

Original language	English
Article number	eaau5363
Journal	Science advances
Volume	4
Issue number	12
DOIs	https://doi.org/10.1126/sciadv.aau5363
Publication status	Published - 12 Dec 2018
MoE publication type	A1 Journal article-refereed

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10.1126/sciadv.aau5363

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Lehtipalo, K., Yan, C., Dada, L., Bianchi, F., Xiao, M., Wagner, R., Stolzenburg, D., Ahonen, L. R., Amorim, A., Baccarini, A., Bauer, P. S., Baumgartner, B., Bergen, A., Bernhammer, A. K., Breitenlechner, M., Brilke, S., Buchholz, A., Mazon, S. B., Chen, D., ... Worsnop, D. R. (2018). Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors. Science advances, 4(12), Article eaau5363. https://doi.org/10.1126/sciadv.aau5363

@article{0f4515d4c75d4d7d961d6a59c733eda2,

title = "Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors",

abstract = "A major fraction of atmospheric aerosol particles, which affect both air quality and climate, form from gaseous precursors in the atmosphere. Highly oxygenated organic molecules (HOMs), formed by oxidation of biogenic volatile organic compounds, are known to participate in particle formation and growth. However, it is not well understood how they interact with atmospheric pollutants, such as nitrogen oxides (NOx) and sulfur oxides (SOx) from fossil fuel combustion, as well as ammonia (NH3) from livestock and fertilizers. Here, we show how NOx suppresses particle formation, while HOMs, sulfuric acid, and NH3 have a synergistic enhancing effect on particle formation. We postulate a novel mechanism, involving HOMs, sulfuric acid, and ammonia, which is able to closely reproduce observations of particle formation and growth in daytime boreal forest and similar environments. The findings elucidate the complex interactions between biogenic and anthropogenic vapors in the atmospheric aerosol system.",

author = "Katrianne Lehtipalo and Chao Yan and Lubna Dada and Federico Bianchi and Mao Xiao and Robert Wagner and Dominik Stolzenburg and Ahonen, {Lauri R.} and Antonio Amorim and Andrea Baccarini and Bauer, {Paulus S.} and Bernhard Baumgartner and Anton Bergen and Bernhammer, {Anne Kathrin} and Martin Breitenlechner and Sophia Brilke and Angela Buchholz and Mazon, {Stephany Buenrostro} and Dexian Chen and Xuemeng Chen and Antonio Dias and Josef Dommen and Draper, {Danielle C.} and Jonathan Duplissy and Mikael Ehn and Henning Finkenzeller and Lukas Fischer and Carla Frege and Claudia Fuchs and Olga Garmash and Hamish Gordon and Jani Hakala and Xucheng He and Liine Heikkinen and Martin Heinritzi and Helm, {Johanna C.} and Victoria Hofbauer and Hoyle, {Christopher R.} and Tuija Jokinen and Juha Kangasluoma and Kerminen, {Veli Matti} and Changhyuk Kim and Jasper Kirkby and Jenni Kontkanen and Andreas K{\"u}rten and Lawler, {Michael J.} and Huajun Mai and Serge Mathot and Mauldin, {Roy L.} and Ugo Molteni and Leonid Nichman and Wei Nie and Tuomo Nieminen and Andrea Ojdanic and Antti Onnela and Monica Passananti and Tuukka Pet{\"a}j{\"a} and Felix Piel and Veronika Pospisilova and Qu{\'e}l{\'e}ver, {Lauriane L.J.} and Rissanen, {Matti P.} and Cl{\'e}mence Rose and Nina Sarnela and Simon Schallhart and Simone Schuchmann and Kamalika Sengupta and Mario Simon and Mikko Sipil{\"a} and Christian Tauber and Ant{\'o}nio Tom{\'e} and Jasmin Tr{\"o}stl and Olli V{\"a}is{\"a}nen and Vogel, {Alexander L.} and Rainer Volkamer and Wagner, {Andrea C.} and Mingyi Wang and Lena Weitz and Daniela Wimmer and Penglin Ye and Arttu Ylisirni{\"o} and Qiaozhi Zha and Carslaw, {Kenneth S.} and Joachim Curtius and Donahue, {Neil M.} and Flagan, {Richard C.} and Armin Hansel and Ilona Riipinen and Annele Virtanen and Winkler, {Paul M.} and Urs Baltensperger and Markku Kulmala and Worsnop, {Douglas R.}",

note = "Publisher Copyright: Copyright {\textcopyright} 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution License 4.0 (CC BY).",

year = "2018",

month = dec,

day = "12",

doi = "10.1126/sciadv.aau5363",

language = "English",

volume = "4",

journal = "Science advances",

issn = "2375-2548",

publisher = "American Association for the Advancement of Science",

number = "12",

}

Lehtipalo, K, Yan, C, Dada, L, Bianchi, F, Xiao, M, Wagner, R, Stolzenburg, D, Ahonen, LR, Amorim, A, Baccarini, A, Bauer, PS, Baumgartner, B, Bergen, A, Bernhammer, AK, Breitenlechner, M, Brilke, S, Buchholz, A, Mazon, SB, Chen, D, Chen, X, Dias, A, Dommen, J, Draper, DC, Duplissy, J, Ehn, M, Finkenzeller, H, Fischer, L, Frege, C, Fuchs, C, Garmash, O, Gordon, H, Hakala, J, He, X, Heikkinen, L, Heinritzi, M, Helm, JC, Hofbauer, V, Hoyle, CR, Jokinen, T, Kangasluoma, J, Kerminen, VM, Kim, C, Kirkby, J, Kontkanen, J, Kürten, A, Lawler, MJ, Mai, H, Mathot, S, Mauldin, RL, Molteni, U, Nichman, L, Nie, W, Nieminen, T, Ojdanic, A, Onnela, A, Passananti, M, Petäjä, T, Piel, F, Pospisilova, V, Quéléver, LLJ, Rissanen, MP, Rose, C, Sarnela, N, Schallhart, S, Schuchmann, S, Sengupta, K, Simon, M, Sipilä, M, Tauber, C, Tomé, A, Tröstl, J, Väisänen, O, Vogel, AL, Volkamer, R, Wagner, AC, Wang, M, Weitz, L, Wimmer, D, Ye, P, Ylisirniö, A, Zha, Q, Carslaw, KS, Curtius, J, Donahue, NM, Flagan, RC, Hansel, A, Riipinen, I, Virtanen, A, Winkler, PM, Baltensperger, U, Kulmala, M & Worsnop, DR 2018, 'Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors', Science advances, vol. 4, no. 12, eaau5363. https://doi.org/10.1126/sciadv.aau5363

TY - JOUR

T1 - Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors

AU - Lehtipalo, Katrianne

AU - Yan, Chao

AU - Dada, Lubna

AU - Bianchi, Federico

AU - Xiao, Mao

AU - Wagner, Robert

AU - Stolzenburg, Dominik

AU - Ahonen, Lauri R.

AU - Amorim, Antonio

AU - Baccarini, Andrea

AU - Bauer, Paulus S.

AU - Baumgartner, Bernhard

AU - Bergen, Anton

AU - Bernhammer, Anne Kathrin

AU - Breitenlechner, Martin

AU - Brilke, Sophia

AU - Buchholz, Angela

AU - Mazon, Stephany Buenrostro

AU - Chen, Dexian

AU - Chen, Xuemeng

AU - Dias, Antonio

AU - Dommen, Josef

AU - Draper, Danielle C.

AU - Duplissy, Jonathan

AU - Ehn, Mikael

AU - Finkenzeller, Henning

AU - Fischer, Lukas

AU - Frege, Carla

AU - Fuchs, Claudia

AU - Garmash, Olga

AU - Gordon, Hamish

AU - Hakala, Jani

AU - He, Xucheng

AU - Heikkinen, Liine

AU - Heinritzi, Martin

AU - Helm, Johanna C.

AU - Hofbauer, Victoria

AU - Hoyle, Christopher R.

AU - Jokinen, Tuija

AU - Kangasluoma, Juha

AU - Kerminen, Veli Matti

AU - Kim, Changhyuk

AU - Kirkby, Jasper

AU - Kontkanen, Jenni

AU - Kürten, Andreas

AU - Lawler, Michael J.

AU - Mai, Huajun

AU - Mathot, Serge

AU - Mauldin, Roy L.

AU - Molteni, Ugo

AU - Nichman, Leonid

AU - Nie, Wei

AU - Nieminen, Tuomo

AU - Ojdanic, Andrea

AU - Onnela, Antti

AU - Passananti, Monica

AU - Petäjä, Tuukka

AU - Piel, Felix

AU - Pospisilova, Veronika

AU - Quéléver, Lauriane L.J.

AU - Rissanen, Matti P.

AU - Rose, Clémence

AU - Sarnela, Nina

AU - Schallhart, Simon

AU - Schuchmann, Simone

AU - Sengupta, Kamalika

AU - Simon, Mario

AU - Sipilä, Mikko

AU - Tauber, Christian

AU - Tomé, António

AU - Tröstl, Jasmin

AU - Väisänen, Olli

AU - Vogel, Alexander L.

AU - Volkamer, Rainer

AU - Wagner, Andrea C.

AU - Wang, Mingyi

AU - Weitz, Lena

AU - Wimmer, Daniela

AU - Ye, Penglin

AU - Ylisirniö, Arttu

AU - Zha, Qiaozhi

AU - Carslaw, Kenneth S.

AU - Curtius, Joachim

AU - Donahue, Neil M.

AU - Flagan, Richard C.

AU - Hansel, Armin

AU - Riipinen, Ilona

AU - Virtanen, Annele

AU - Winkler, Paul M.

AU - Baltensperger, Urs

AU - Kulmala, Markku

AU - Worsnop, Douglas R.

N1 - Publisher Copyright: Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution License 4.0 (CC BY).

PY - 2018/12/12

Y1 - 2018/12/12

N2 - A major fraction of atmospheric aerosol particles, which affect both air quality and climate, form from gaseous precursors in the atmosphere. Highly oxygenated organic molecules (HOMs), formed by oxidation of biogenic volatile organic compounds, are known to participate in particle formation and growth. However, it is not well understood how they interact with atmospheric pollutants, such as nitrogen oxides (NOx) and sulfur oxides (SOx) from fossil fuel combustion, as well as ammonia (NH3) from livestock and fertilizers. Here, we show how NOx suppresses particle formation, while HOMs, sulfuric acid, and NH3 have a synergistic enhancing effect on particle formation. We postulate a novel mechanism, involving HOMs, sulfuric acid, and ammonia, which is able to closely reproduce observations of particle formation and growth in daytime boreal forest and similar environments. The findings elucidate the complex interactions between biogenic and anthropogenic vapors in the atmospheric aerosol system.

AB - A major fraction of atmospheric aerosol particles, which affect both air quality and climate, form from gaseous precursors in the atmosphere. Highly oxygenated organic molecules (HOMs), formed by oxidation of biogenic volatile organic compounds, are known to participate in particle formation and growth. However, it is not well understood how they interact with atmospheric pollutants, such as nitrogen oxides (NOx) and sulfur oxides (SOx) from fossil fuel combustion, as well as ammonia (NH3) from livestock and fertilizers. Here, we show how NOx suppresses particle formation, while HOMs, sulfuric acid, and NH3 have a synergistic enhancing effect on particle formation. We postulate a novel mechanism, involving HOMs, sulfuric acid, and ammonia, which is able to closely reproduce observations of particle formation and growth in daytime boreal forest and similar environments. The findings elucidate the complex interactions between biogenic and anthropogenic vapors in the atmospheric aerosol system.

UR - http://www.scopus.com/inward/record.url?scp=85058725307&partnerID=8YFLogxK

U2 - 10.1126/sciadv.aau5363

DO - 10.1126/sciadv.aau5363

M3 - Article

C2 - 30547087

AN - SCOPUS:85058725307

SN - 2375-2548

VL - 4

JO - Science advances

JF - Science advances

IS - 12

M1 - eaau5363

ER -

Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors

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