N,N'-diallylaldardiamides and their use as cross-linkers in xylan hydrogels

Helinä Talja, Harri Setälä

Research output: Contribution to conferenceConference AbstractScientificpeer-review

Abstract

N, N-diallylaldardiamides were synthesized from galactaric, xylaric and arabinaric acid. Hydrogels were prepared in water solution by UV induced free-radical crosslinking polymerization of xylan polymer in the presence of 1 or 5 mass-% of N, N-diallylaldardiamide crosslinker. Commercially available N, N-diallyltartardiamide (DATDA) was also used. Xylan polymers had different degrees of substitution of allyl groups which were calculated according to 1H-NMR spectra. Elemental analysis proved the crosslinking successful. Water absorption of the gels was examined and gels with less crosslinker and lowest degree of substitution turned out to absorb the most. The swollen morphology of the hydrogels was assessed by scanning electron microscopy.
Original languageEnglish
Publication statusPublished - 2011
MoE publication typeNot Eligible
Event241st American Chemical Society National Meeting & Exposition - Anaheim, United States
Duration: 27 Mar 201131 Mar 2011

Conference

Conference241st American Chemical Society National Meeting & Exposition
Abbreviated title241st ACS National Meeting
CountryUnited States
CityAnaheim
Period27/03/1131/03/11

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    Talja, H., & Setälä, H. (2011). N,N'-diallylaldardiamides and their use as cross-linkers in xylan hydrogels. Abstract from 241st American Chemical Society National Meeting & Exposition, Anaheim, United States.