Novel photo-switchable polymers based on calix[4]arenes

Szymon Wiktorowicz, Vladimir Aseyev, Heikki Tenhu

Research output: Contribution to journalArticleScientificpeer-review

10 Citations (Scopus)

Abstract

5,17-Dinitrocalix[4]arenes with varying lower rim substituents (butyl, dodecyl chains), locked in the cone conformation, were synthesized and further subjected to reductive coupling reactions to yield a new type of photoswitchable polymers - poly(azocalix[4]arenes). These rigid polymers can undergo reversible photoswitching between the trans and cis form upon irradiation with specific wavelengths, as well as slow thermal isomerisation back to the preferred trans form.

Original languageEnglish
Pages (from-to)1126-1129
Number of pages4
JournalPolymer Chemistry
Volume3
Issue number5
DOIs
Publication statusPublished - 1 Jan 2012
MoE publication typeA1 Journal article-refereed

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