Overlapping of the devolatilization and char combustion stages in the burning of coal particles

Carlos Gurgel-Veras, Jaakko Saastamoinen (Corresponding Author), J. Carvalho, Martti Aho

Research output: Contribution to journalArticleScientificpeer-review

67 Citations (Scopus)

Abstract

The oxygen content at the surface of a fuel particle can significantly exceed zero during the devolatilization stage of combustion, despite the flux of volatiles from the surface and also gas phase reactions. This implies that char oxidation can take place simultaneously. This overlapping of the devolatilization and char combustion stages is studied by modeling. The rates of gas phase reactions around the particle influence the availability of oxygen at the surface of a burning particle and they are accounted for by using a two-step global model for combustion of volatiles. The effects of particle size, ambient temperature, and oxygen concentration on the degree of overlap are studied. The study provides theoretical and experimental evidence that the combustion time of a particle does not always increase with its size at constant ambient conditions, but there can be a specific particle size giving a maximum combustion rate.
Original languageEnglish
Pages (from-to)567-579
Number of pages13
JournalCombustion and Flame
Volume116
Issue number4
DOIs
Publication statusPublished - 1999
MoE publication typeA1 Journal article-refereed

Fingerprint

Coal
coal
Oxygen
oxygen
Gases
Particle size
vapor phases
ambient temperature
availability
Availability
Fluxes
Oxidation
oxidation

Keywords

  • fuels
  • properties
  • devolatilization
  • char
  • combustion

Cite this

Gurgel-Veras, Carlos ; Saastamoinen, Jaakko ; Carvalho, J. ; Aho, Martti. / Overlapping of the devolatilization and char combustion stages in the burning of coal particles. In: Combustion and Flame. 1999 ; Vol. 116, No. 4. pp. 567-579.
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Overlapping of the devolatilization and char combustion stages in the burning of coal particles. / Gurgel-Veras, Carlos; Saastamoinen, Jaakko (Corresponding Author); Carvalho, J.; Aho, Martti.

In: Combustion and Flame, Vol. 116, No. 4, 1999, p. 567-579.

Research output: Contribution to journalArticleScientificpeer-review

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PY - 1999

Y1 - 1999

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AB - The oxygen content at the surface of a fuel particle can significantly exceed zero during the devolatilization stage of combustion, despite the flux of volatiles from the surface and also gas phase reactions. This implies that char oxidation can take place simultaneously. This overlapping of the devolatilization and char combustion stages is studied by modeling. The rates of gas phase reactions around the particle influence the availability of oxygen at the surface of a burning particle and they are accounted for by using a two-step global model for combustion of volatiles. The effects of particle size, ambient temperature, and oxygen concentration on the degree of overlap are studied. The study provides theoretical and experimental evidence that the combustion time of a particle does not always increase with its size at constant ambient conditions, but there can be a specific particle size giving a maximum combustion rate.

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