Oxygen-Doped Nanodiamonds: Synthesis and Functionalizations

Andrey A. Fokin, Tatyana S. Zhuk, Alexander E. Pashenko, Pavlo O. Dral, Pavel A. Gunchenko, Jeremy E.P. Dahl, Robert M.K. Carlson, Tetyana Koso, Michael Serafin, Peter R. Schreiner

Research output: Contribution to journalArticleScientificpeer-review

49 Citations (Scopus)

Abstract

Oxadiamondoids representing a new class of carbon nanoparticles were prepared from the respective diamondoid ketones via an effective two-step procedure involving addition of methyl magnesium iodide and oxidation with trifluoroperacetic acid in trifluoroacetic acid. The reactivities of the oxacages are determined by the position of the dopant and are in good agreement with computational predictions.
Original languageEnglish
Pages (from-to)3068–3071
JournalOrganic Letters
Volume11
Issue number14
DOIs
Publication statusPublished - Aug 2009
MoE publication typeA1 Journal article-refereed

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