Oxygen-Doped Nanodiamonds: Synthesis and Functionalizations

Andrey A. Fokin; Tatyana S. Zhuk; Alexander E. Pashenko; Pavlo O. Dral; Pavel A. Gunchenko; Jeremy E.P. Dahl; Robert M.K. Carlson; Tetyana Koso; Michael Serafin; Peter R. Schreiner

doi:10.1021/ol901089h

Oxygen-Doped Nanodiamonds: Synthesis and Functionalizations

Andrey A. Fokin
, Tatyana S. Zhuk
, Alexander E. Pashenko
, Pavlo O. Dral
, Pavel A. Gunchenko
, Jeremy E.P. Dahl
, Robert M.K. Carlson
, Tetyana Koso
, Michael Serafin
, Peter R. Schreiner

Not published at VTT

Justus-Liebig-University
Chevron Technology Ventures L.L.C.
Igor Sikorsky Kiev Polytechnic Institute

Research output: Contribution to journal › Article › Scientific › peer-review

52 Citations (Scopus)

Abstract

Oxadiamondoids representing a new class of carbon nanoparticles were prepared from the respective diamondoid ketones via an effective two-step procedure involving addition of methyl magnesium iodide and oxidation with trifluoroperacetic acid in trifluoroacetic acid. The reactivities of the oxacages are determined by the position of the dopant and are in good agreement with computational predictions.

Original language	English
Pages (from-to)	3068–3071
Journal	Organic Letters
Volume	11
Issue number	14
DOIs	https://doi.org/10.1021/ol901089h
Publication status	Published - Aug 2009
MoE publication type	A1 Journal article-refereed

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10.1021/ol901089h

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title = "Oxygen-Doped Nanodiamonds: Synthesis and Functionalizations",

abstract = "Oxadiamondoids representing a new class of carbon nanoparticles were prepared from the respective diamondoid ketones via an effective two-step procedure involving addition of methyl magnesium iodide and oxidation with trifluoroperacetic acid in trifluoroacetic acid. The reactivities of the oxacages are determined by the position of the dopant and are in good agreement with computational predictions.",

author = "Fokin, \{Andrey A.\} and Zhuk, \{Tatyana S.\} and Pashenko, \{Alexander E.\} and Dral, \{Pavlo O.\} and Gunchenko, \{Pavel A.\} and Dahl, \{Jeremy E.P.\} and Carlson, \{Robert M.K.\} and Tetyana Koso and Michael Serafin and Schreiner, \{Peter R.\}",

year = "2009",

month = aug,

doi = "10.1021/ol901089h",

language = "English",

volume = "11",

pages = "3068–3071",

journal = "Organic Letters",

issn = "1523-7060",

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T1 - Oxygen-Doped Nanodiamonds: Synthesis and Functionalizations

AU - Fokin, Andrey A.

AU - Zhuk, Tatyana S.

AU - Pashenko, Alexander E.

AU - Dral, Pavlo O.

AU - Gunchenko, Pavel A.

AU - Dahl, Jeremy E.P.

AU - Carlson, Robert M.K.

AU - Koso, Tetyana

AU - Serafin, Michael

AU - Schreiner, Peter R.

PY - 2009/8

Y1 - 2009/8

N2 - Oxadiamondoids representing a new class of carbon nanoparticles were prepared from the respective diamondoid ketones via an effective two-step procedure involving addition of methyl magnesium iodide and oxidation with trifluoroperacetic acid in trifluoroacetic acid. The reactivities of the oxacages are determined by the position of the dopant and are in good agreement with computational predictions.

AB - Oxadiamondoids representing a new class of carbon nanoparticles were prepared from the respective diamondoid ketones via an effective two-step procedure involving addition of methyl magnesium iodide and oxidation with trifluoroperacetic acid in trifluoroacetic acid. The reactivities of the oxacages are determined by the position of the dopant and are in good agreement with computational predictions.

UR - https://researchportal.helsinki.fi/en/publications/597ee439-9079-426a-9450-86b275493a32

U2 - 10.1021/ol901089h

DO - 10.1021/ol901089h

M3 - Article

SN - 1523-7060

VL - 11

SP - 3068

EP - 3071

JO - Organic Letters

JF - Organic Letters

IS - 14

ER -

Oxygen-Doped Nanodiamonds: Synthesis and Functionalizations

Abstract

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