Ozone-based batch atomic layer deposited Al2O3 for effective surface passivation

G von Gastrow (Corresponding Author), S Li, P Repo, Y Bao, Matti Putkonen, H Savin

    Research output: Contribution to journalArticleScientificpeer-review

    11 Citations (Scopus)

    Abstract

    In this paper we compare water and ozone as oxidants in the Al 2O3 ALD reaction in terms of surface passivation quality. The experiments show that O3 produces a high negative charge density up to 7·1012 cm-2 even in as-deposited film, which is different from water based Al2O3 that requires a separate annealing step to activate the negative charge. In general, the ozone process produces lower interface defect density (Dit) and higher negative charge density, which contributes to the higher lifetime value than corresponding water process. Most importantly, ozone-based Al2O 3 shows much better firing stability than water-based Al 2O3. Ozone concentration is also shown to play a role in the surface passivation quality. Finally, we found out that inserting a water pulse after the ozone pulse can lower the Dit further resulting in even higher lifetime.
    Original languageEnglish
    Pages (from-to)890-894
    JournalEnergy Procedia
    Volume38
    DOIs
    Publication statusPublished - 2013
    MoE publication typeNot Eligible
    Event3rd International Conference on Crystalline Silicon Photovoltaics, SiliconPV 2013 - Hamelin, Germany
    Duration: 25 Mar 201327 Mar 2013

    Fingerprint

    Passivation
    Ozone
    Water
    Charge density
    Defect density
    Oxidants
    Annealing
    Experiments

    Keywords

    • Aluminum oxide
    • atomic layer deposition
    • ozone
    • Si surface passivation

    Cite this

    von Gastrow, G., Li, S., Repo, P., Bao, Y., Putkonen, M., & Savin, H. (2013). Ozone-based batch atomic layer deposited Al2O3 for effective surface passivation. Energy Procedia, 38, 890-894. https://doi.org/10.1016/j.egypro.2013.07.361
    von Gastrow, G ; Li, S ; Repo, P ; Bao, Y ; Putkonen, Matti ; Savin, H. / Ozone-based batch atomic layer deposited Al2O3 for effective surface passivation. In: Energy Procedia. 2013 ; Vol. 38. pp. 890-894.
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    abstract = "In this paper we compare water and ozone as oxidants in the Al 2O3 ALD reaction in terms of surface passivation quality. The experiments show that O3 produces a high negative charge density up to 7·1012 cm-2 even in as-deposited film, which is different from water based Al2O3 that requires a separate annealing step to activate the negative charge. In general, the ozone process produces lower interface defect density (Dit) and higher negative charge density, which contributes to the higher lifetime value than corresponding water process. Most importantly, ozone-based Al2O 3 shows much better firing stability than water-based Al 2O3. Ozone concentration is also shown to play a role in the surface passivation quality. Finally, we found out that inserting a water pulse after the ozone pulse can lower the Dit further resulting in even higher lifetime.",
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    von Gastrow, G, Li, S, Repo, P, Bao, Y, Putkonen, M & Savin, H 2013, 'Ozone-based batch atomic layer deposited Al2O3 for effective surface passivation', Energy Procedia, vol. 38, pp. 890-894. https://doi.org/10.1016/j.egypro.2013.07.361

    Ozone-based batch atomic layer deposited Al2O3 for effective surface passivation. / von Gastrow, G (Corresponding Author); Li, S; Repo, P; Bao, Y; Putkonen, Matti; Savin, H.

    In: Energy Procedia, Vol. 38, 2013, p. 890-894.

    Research output: Contribution to journalArticleScientificpeer-review

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    AU - von Gastrow, G

    AU - Li, S

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    AU - Putkonen, Matti

    AU - Savin, H

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    AB - In this paper we compare water and ozone as oxidants in the Al 2O3 ALD reaction in terms of surface passivation quality. The experiments show that O3 produces a high negative charge density up to 7·1012 cm-2 even in as-deposited film, which is different from water based Al2O3 that requires a separate annealing step to activate the negative charge. In general, the ozone process produces lower interface defect density (Dit) and higher negative charge density, which contributes to the higher lifetime value than corresponding water process. Most importantly, ozone-based Al2O 3 shows much better firing stability than water-based Al 2O3. Ozone concentration is also shown to play a role in the surface passivation quality. Finally, we found out that inserting a water pulse after the ozone pulse can lower the Dit further resulting in even higher lifetime.

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