Phase behaviour and droplet size of oil-in-water Pickering emulsions stabilised with plant-derived nanocellulosic materials

Marie Gestranius (Corresponding Author), Per Stenius, Eero Kontturi, Johan Sjöblom, Tekla Tammelin

    Research output: Contribution to journalArticleScientificpeer-review

    46 Citations (Scopus)

    Abstract

    The preparation, stability and phase behaviour of oil-in-water emulsions formed by dodecane and water and stabilised by naturally amphiphilic, chemically unmodified cellulose nanofibrils (CNF), TEMPO-oxidized cellulose nanofibrils (T-CNF) and cellulose nanocrystals (CNC) were investigated. The stability towards prolonged storage, high temperature (maximum 85. °C), shear and dilution with water was evaluated. Droplet size distributions were determined from micrographs and by NMR diffusion measurements. Oil-in-water Pickering emulsions were formed at all stabiliser and O/W ratios (20-35% oil, 0.1-1.5% nanocellulose) for all three nanocellulosic materials, without the use of any additives. All emulsions creamed rapidly; the creaming layers remained stable for at least one month. The volume of creaming layers formed by CNF and T-CNF are larger and the stability towards coalescence, low shear and high temperature of CNF and T-CNF are higher than the corresponding properties of emulsions stabilised with CNC. This is probably due to the networks formed by the longer fibrils. T-CNF forms a dilute stable emulsion in equilibrium with the creaming layer. No emulsion droplets were visible in the water phases in equilibrium with the creaming layers formed by emulsions stabilised by CNC or CNF. The stability of the dilute T-CNF emulsions is probably due to the ionic charge of the nanofibrils, which is higher than that of the CNF or CNC. It seems that nanocellulosic materials primarily act as stabilisers against coalescence rather than flocculation.
    Original languageEnglish
    Pages (from-to)60-70
    Number of pages11
    JournalColloids and Surfaces A: Physicochemical and Engineering Aspects
    Volume519
    DOIs
    Publication statusPublished - 20 Apr 2017
    MoE publication typeA1 Journal article-refereed

    Fingerprint

    Phase behavior
    Emulsions
    cellulose
    Cellulose
    emulsions
    oxidized cellulose
    Oils
    oils
    Water
    water
    Nanocrystals
    nanocrystals
    Coalescence
    coalescing
    Flocculation
    Dilution
    shear
    Nuclear magnetic resonance
    TEMPO
    Temperature

    Keywords

    • cellulose nanocrystal
    • cellulose nanofibril
    • oil-in-water emulsion
    • phase behaviour
    • pickering emulsion
    • TEMPO-oxidized cellulose nanofibril

    Cite this

    @article{54e188f99eb4440181e956a8241c6b96,
    title = "Phase behaviour and droplet size of oil-in-water Pickering emulsions stabilised with plant-derived nanocellulosic materials",
    abstract = "The preparation, stability and phase behaviour of oil-in-water emulsions formed by dodecane and water and stabilised by naturally amphiphilic, chemically unmodified cellulose nanofibrils (CNF), TEMPO-oxidized cellulose nanofibrils (T-CNF) and cellulose nanocrystals (CNC) were investigated. The stability towards prolonged storage, high temperature (maximum 85. °C), shear and dilution with water was evaluated. Droplet size distributions were determined from micrographs and by NMR diffusion measurements. Oil-in-water Pickering emulsions were formed at all stabiliser and O/W ratios (20-35{\%} oil, 0.1-1.5{\%} nanocellulose) for all three nanocellulosic materials, without the use of any additives. All emulsions creamed rapidly; the creaming layers remained stable for at least one month. The volume of creaming layers formed by CNF and T-CNF are larger and the stability towards coalescence, low shear and high temperature of CNF and T-CNF are higher than the corresponding properties of emulsions stabilised with CNC. This is probably due to the networks formed by the longer fibrils. T-CNF forms a dilute stable emulsion in equilibrium with the creaming layer. No emulsion droplets were visible in the water phases in equilibrium with the creaming layers formed by emulsions stabilised by CNC or CNF. The stability of the dilute T-CNF emulsions is probably due to the ionic charge of the nanofibrils, which is higher than that of the CNF or CNC. It seems that nanocellulosic materials primarily act as stabilisers against coalescence rather than flocculation.",
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    Phase behaviour and droplet size of oil-in-water Pickering emulsions stabilised with plant-derived nanocellulosic materials. / Gestranius, Marie (Corresponding Author); Stenius, Per; Kontturi, Eero; Sjöblom, Johan; Tammelin, Tekla.

    In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 519, 20.04.2017, p. 60-70.

    Research output: Contribution to journalArticleScientificpeer-review

    TY - JOUR

    T1 - Phase behaviour and droplet size of oil-in-water Pickering emulsions stabilised with plant-derived nanocellulosic materials

    AU - Gestranius, Marie

    AU - Stenius, Per

    AU - Kontturi, Eero

    AU - Sjöblom, Johan

    AU - Tammelin, Tekla

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    AB - The preparation, stability and phase behaviour of oil-in-water emulsions formed by dodecane and water and stabilised by naturally amphiphilic, chemically unmodified cellulose nanofibrils (CNF), TEMPO-oxidized cellulose nanofibrils (T-CNF) and cellulose nanocrystals (CNC) were investigated. The stability towards prolonged storage, high temperature (maximum 85. °C), shear and dilution with water was evaluated. Droplet size distributions were determined from micrographs and by NMR diffusion measurements. Oil-in-water Pickering emulsions were formed at all stabiliser and O/W ratios (20-35% oil, 0.1-1.5% nanocellulose) for all three nanocellulosic materials, without the use of any additives. All emulsions creamed rapidly; the creaming layers remained stable for at least one month. The volume of creaming layers formed by CNF and T-CNF are larger and the stability towards coalescence, low shear and high temperature of CNF and T-CNF are higher than the corresponding properties of emulsions stabilised with CNC. This is probably due to the networks formed by the longer fibrils. T-CNF forms a dilute stable emulsion in equilibrium with the creaming layer. No emulsion droplets were visible in the water phases in equilibrium with the creaming layers formed by emulsions stabilised by CNC or CNF. The stability of the dilute T-CNF emulsions is probably due to the ionic charge of the nanofibrils, which is higher than that of the CNF or CNC. It seems that nanocellulosic materials primarily act as stabilisers against coalescence rather than flocculation.

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    KW - cellulose nanofibril

    KW - oil-in-water emulsion

    KW - phase behaviour

    KW - pickering emulsion

    KW - TEMPO-oxidized cellulose nanofibril

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    M3 - Article

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    EP - 70

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    JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects

    SN - 0927-7757

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