Phase behaviour and droplet size of oil-in-water Pickering emulsions stabilised with plant-derived nanocellulosic materials

Marie Gestranius (Corresponding Author), Per Stenius, Eero Kontturi, Johan Sjöblom, Tekla Tammelin

Research output: Contribution to journalArticleScientificpeer-review

38 Citations (Scopus)

Abstract

The preparation, stability and phase behaviour of oil-in-water emulsions formed by dodecane and water and stabilised by naturally amphiphilic, chemically unmodified cellulose nanofibrils (CNF), TEMPO-oxidized cellulose nanofibrils (T-CNF) and cellulose nanocrystals (CNC) were investigated. The stability towards prolonged storage, high temperature (maximum 85. °C), shear and dilution with water was evaluated. Droplet size distributions were determined from micrographs and by NMR diffusion measurements. Oil-in-water Pickering emulsions were formed at all stabiliser and O/W ratios (20-35% oil, 0.1-1.5% nanocellulose) for all three nanocellulosic materials, without the use of any additives. All emulsions creamed rapidly; the creaming layers remained stable for at least one month. The volume of creaming layers formed by CNF and T-CNF are larger and the stability towards coalescence, low shear and high temperature of CNF and T-CNF are higher than the corresponding properties of emulsions stabilised with CNC. This is probably due to the networks formed by the longer fibrils. T-CNF forms a dilute stable emulsion in equilibrium with the creaming layer. No emulsion droplets were visible in the water phases in equilibrium with the creaming layers formed by emulsions stabilised by CNC or CNF. The stability of the dilute T-CNF emulsions is probably due to the ionic charge of the nanofibrils, which is higher than that of the CNF or CNC. It seems that nanocellulosic materials primarily act as stabilisers against coalescence rather than flocculation.
Original languageEnglish
Pages (from-to)60-70
Number of pages11
JournalColloids and Surfaces A: Physicochemical and Engineering Aspects
Volume519
DOIs
Publication statusPublished - 20 Apr 2017
MoE publication typeA1 Journal article-refereed

Fingerprint

Phase behavior
Emulsions
cellulose
Cellulose
emulsions
oxidized cellulose
Oils
oils
Water
water
Nanocrystals
nanocrystals
Coalescence
coalescing
Flocculation
Dilution
shear
Nuclear magnetic resonance
TEMPO
Temperature

Keywords

  • cellulose nanocrystal
  • cellulose nanofibril
  • oil-in-water emulsion
  • phase behaviour
  • pickering emulsion
  • TEMPO-oxidized cellulose nanofibril

Cite this

@article{54e188f99eb4440181e956a8241c6b96,
title = "Phase behaviour and droplet size of oil-in-water Pickering emulsions stabilised with plant-derived nanocellulosic materials",
abstract = "The preparation, stability and phase behaviour of oil-in-water emulsions formed by dodecane and water and stabilised by naturally amphiphilic, chemically unmodified cellulose nanofibrils (CNF), TEMPO-oxidized cellulose nanofibrils (T-CNF) and cellulose nanocrystals (CNC) were investigated. The stability towards prolonged storage, high temperature (maximum 85. °C), shear and dilution with water was evaluated. Droplet size distributions were determined from micrographs and by NMR diffusion measurements. Oil-in-water Pickering emulsions were formed at all stabiliser and O/W ratios (20-35{\%} oil, 0.1-1.5{\%} nanocellulose) for all three nanocellulosic materials, without the use of any additives. All emulsions creamed rapidly; the creaming layers remained stable for at least one month. The volume of creaming layers formed by CNF and T-CNF are larger and the stability towards coalescence, low shear and high temperature of CNF and T-CNF are higher than the corresponding properties of emulsions stabilised with CNC. This is probably due to the networks formed by the longer fibrils. T-CNF forms a dilute stable emulsion in equilibrium with the creaming layer. No emulsion droplets were visible in the water phases in equilibrium with the creaming layers formed by emulsions stabilised by CNC or CNF. The stability of the dilute T-CNF emulsions is probably due to the ionic charge of the nanofibrils, which is higher than that of the CNF or CNC. It seems that nanocellulosic materials primarily act as stabilisers against coalescence rather than flocculation.",
keywords = "cellulose nanocrystal, cellulose nanofibril, oil-in-water emulsion, phase behaviour, pickering emulsion, TEMPO-oxidized cellulose nanofibril",
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volume = "519",
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journal = "Colloids and Surfaces A: Physicochemical and Engineering Aspects",
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Phase behaviour and droplet size of oil-in-water Pickering emulsions stabilised with plant-derived nanocellulosic materials. / Gestranius, Marie (Corresponding Author); Stenius, Per; Kontturi, Eero; Sjöblom, Johan; Tammelin, Tekla.

In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 519, 20.04.2017, p. 60-70.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Phase behaviour and droplet size of oil-in-water Pickering emulsions stabilised with plant-derived nanocellulosic materials

AU - Gestranius, Marie

AU - Stenius, Per

AU - Kontturi, Eero

AU - Sjöblom, Johan

AU - Tammelin, Tekla

PY - 2017/4/20

Y1 - 2017/4/20

N2 - The preparation, stability and phase behaviour of oil-in-water emulsions formed by dodecane and water and stabilised by naturally amphiphilic, chemically unmodified cellulose nanofibrils (CNF), TEMPO-oxidized cellulose nanofibrils (T-CNF) and cellulose nanocrystals (CNC) were investigated. The stability towards prolonged storage, high temperature (maximum 85. °C), shear and dilution with water was evaluated. Droplet size distributions were determined from micrographs and by NMR diffusion measurements. Oil-in-water Pickering emulsions were formed at all stabiliser and O/W ratios (20-35% oil, 0.1-1.5% nanocellulose) for all three nanocellulosic materials, without the use of any additives. All emulsions creamed rapidly; the creaming layers remained stable for at least one month. The volume of creaming layers formed by CNF and T-CNF are larger and the stability towards coalescence, low shear and high temperature of CNF and T-CNF are higher than the corresponding properties of emulsions stabilised with CNC. This is probably due to the networks formed by the longer fibrils. T-CNF forms a dilute stable emulsion in equilibrium with the creaming layer. No emulsion droplets were visible in the water phases in equilibrium with the creaming layers formed by emulsions stabilised by CNC or CNF. The stability of the dilute T-CNF emulsions is probably due to the ionic charge of the nanofibrils, which is higher than that of the CNF or CNC. It seems that nanocellulosic materials primarily act as stabilisers against coalescence rather than flocculation.

AB - The preparation, stability and phase behaviour of oil-in-water emulsions formed by dodecane and water and stabilised by naturally amphiphilic, chemically unmodified cellulose nanofibrils (CNF), TEMPO-oxidized cellulose nanofibrils (T-CNF) and cellulose nanocrystals (CNC) were investigated. The stability towards prolonged storage, high temperature (maximum 85. °C), shear and dilution with water was evaluated. Droplet size distributions were determined from micrographs and by NMR diffusion measurements. Oil-in-water Pickering emulsions were formed at all stabiliser and O/W ratios (20-35% oil, 0.1-1.5% nanocellulose) for all three nanocellulosic materials, without the use of any additives. All emulsions creamed rapidly; the creaming layers remained stable for at least one month. The volume of creaming layers formed by CNF and T-CNF are larger and the stability towards coalescence, low shear and high temperature of CNF and T-CNF are higher than the corresponding properties of emulsions stabilised with CNC. This is probably due to the networks formed by the longer fibrils. T-CNF forms a dilute stable emulsion in equilibrium with the creaming layer. No emulsion droplets were visible in the water phases in equilibrium with the creaming layers formed by emulsions stabilised by CNC or CNF. The stability of the dilute T-CNF emulsions is probably due to the ionic charge of the nanofibrils, which is higher than that of the CNF or CNC. It seems that nanocellulosic materials primarily act as stabilisers against coalescence rather than flocculation.

KW - cellulose nanocrystal

KW - cellulose nanofibril

KW - oil-in-water emulsion

KW - phase behaviour

KW - pickering emulsion

KW - TEMPO-oxidized cellulose nanofibril

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U2 - 10.1016/j.colsurfa.2016.04.025

DO - 10.1016/j.colsurfa.2016.04.025

M3 - Article

VL - 519

SP - 60

EP - 70

JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects

JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects

SN - 0927-7757

ER -