Physicochemical characterization of fine particles from small-scale wood combustion

Heikki Lamberg (Corresponding Author), Kati Nuutinen, Jarkko Tissari, Jarno Ruusunen, Pasi Yli-Pirilä, Olli Sippula, Maija Tapanainen, Pasi Jalava, Ulla Makkonen, Kimmo Teinilä, Karri Saarnio, Risto Hillamo, Maija-Riitta Hirvonen, Jorma Jokiniemi

Research output: Contribution to journalArticleScientificpeer-review

107 Citations (Scopus)

Abstract

Emissions from small-scale wood combustion appliances are of special interest since fine particles have been consistently associated with adverse health effects. It has been reported that the physicochemical characteristics of the emitted particles affect also their toxic properties but the mechanisms behind these phenomena and the causative role of particles from wood combustion sources are still mostly unknown. Combustion situations vary significantly in small-scale appliances, especially in batch combustion. Combustion behaviour is affected by fuel properties, appliance type and operational practice. Particle samples were collected from six appliances representing different combustion situations in small-scale combustion. These appliances were five wood log fuelled stoves, including one stove equipped with modern combustion technology, three different conventional combustion appliances and one sauna stove. In addition, a modern small-scale pellet boiler represented advanced continuous combustion technology. The aim of the study was to analyze gas composition and fine particle properties over different combustion situations. Fine particle (PM1) emissions and their chemical constituents emerging from different combustion situations were compared and this physicochemical data was combined with the toxicological data on cellular responses induced by the same particles (see Tapanainen et al., 2011). There were significant differences in the particle emissions from different combustion situations. Overall, the efficient combustion in the pellet boiler produced the smallest emissions whereas inefficient batch combustion in a sauna stove created the largest emissions. Improved batch combustion with air-staging produced about 2.5-fold PM1 emissions compared to the modern pellet boiler (50.7 mg MJ−1 and 19.7 mg MJ−1, respectively), but the difference in the total particulate PAH content was 750-fold (90 μg MJ−1 and 0.12 μg MJ−1, respectively). Improved batch combustion and conventional batch combustion showed almost the same PM1 emissions (51.6 mg MJ−1), but a 10-fold difference in total particulate PAH emissions (910 μg MJ−1). These results highlight that same PM1 emissions can be associated with very different chemical compositions, potentially leading to different toxic properties of the particles. Thus, changing from an old, less efficient, combustion appliance to a modern appliance can have a greater impact on toxic properties than the emitted PM1 mass might indicate.
Original languageEnglish
Pages (from-to)7635-7643
JournalAtmospheric Environment
Volume45
Issue number40
DOIs
Publication statusPublished - 2011
MoE publication typeA1 Journal article-refereed
Event3rd American Association for Aerosol Research (AAAR) International Specialty Conference: “Air Pollution and Health: Bridging the Gap from Sources to Health Outcomes” - San Diego, United States
Duration: 22 Mar 201026 Mar 2010

Fingerprint

combustion
particle
fold
PAH
induced response
chemical composition

Keywords

  • Wood combustion
  • emission
  • fine particles
  • particle characteristics

Cite this

Lamberg, H., Nuutinen, K., Tissari, J., Ruusunen, J., Yli-Pirilä, P., Sippula, O., ... Jokiniemi, J. (2011). Physicochemical characterization of fine particles from small-scale wood combustion. Atmospheric Environment, 45(40), 7635-7643. https://doi.org/10.1016/j.atmosenv.2011.02.072
Lamberg, Heikki ; Nuutinen, Kati ; Tissari, Jarkko ; Ruusunen, Jarno ; Yli-Pirilä, Pasi ; Sippula, Olli ; Tapanainen, Maija ; Jalava, Pasi ; Makkonen, Ulla ; Teinilä, Kimmo ; Saarnio, Karri ; Hillamo, Risto ; Hirvonen, Maija-Riitta ; Jokiniemi, Jorma. / Physicochemical characterization of fine particles from small-scale wood combustion. In: Atmospheric Environment. 2011 ; Vol. 45, No. 40. pp. 7635-7643.
@article{155d2b5528914ce4b4a3447fa5c6a2a1,
title = "Physicochemical characterization of fine particles from small-scale wood combustion",
abstract = "Emissions from small-scale wood combustion appliances are of special interest since fine particles have been consistently associated with adverse health effects. It has been reported that the physicochemical characteristics of the emitted particles affect also their toxic properties but the mechanisms behind these phenomena and the causative role of particles from wood combustion sources are still mostly unknown. Combustion situations vary significantly in small-scale appliances, especially in batch combustion. Combustion behaviour is affected by fuel properties, appliance type and operational practice. Particle samples were collected from six appliances representing different combustion situations in small-scale combustion. These appliances were five wood log fuelled stoves, including one stove equipped with modern combustion technology, three different conventional combustion appliances and one sauna stove. In addition, a modern small-scale pellet boiler represented advanced continuous combustion technology. The aim of the study was to analyze gas composition and fine particle properties over different combustion situations. Fine particle (PM1) emissions and their chemical constituents emerging from different combustion situations were compared and this physicochemical data was combined with the toxicological data on cellular responses induced by the same particles (see Tapanainen et al., 2011). There were significant differences in the particle emissions from different combustion situations. Overall, the efficient combustion in the pellet boiler produced the smallest emissions whereas inefficient batch combustion in a sauna stove created the largest emissions. Improved batch combustion with air-staging produced about 2.5-fold PM1 emissions compared to the modern pellet boiler (50.7 mg MJ−1 and 19.7 mg MJ−1, respectively), but the difference in the total particulate PAH content was 750-fold (90 μg MJ−1 and 0.12 μg MJ−1, respectively). Improved batch combustion and conventional batch combustion showed almost the same PM1 emissions (51.6 mg MJ−1), but a 10-fold difference in total particulate PAH emissions (910 μg MJ−1). These results highlight that same PM1 emissions can be associated with very different chemical compositions, potentially leading to different toxic properties of the particles. Thus, changing from an old, less efficient, combustion appliance to a modern appliance can have a greater impact on toxic properties than the emitted PM1 mass might indicate.",
keywords = "Wood combustion, emission, fine particles, particle characteristics",
author = "Heikki Lamberg and Kati Nuutinen and Jarkko Tissari and Jarno Ruusunen and Pasi Yli-Piril{\"a} and Olli Sippula and Maija Tapanainen and Pasi Jalava and Ulla Makkonen and Kimmo Teinil{\"a} and Karri Saarnio and Risto Hillamo and Maija-Riitta Hirvonen and Jorma Jokiniemi",
year = "2011",
doi = "10.1016/j.atmosenv.2011.02.072",
language = "English",
volume = "45",
pages = "7635--7643",
journal = "Atmospheric Environment",
issn = "1352-2310",
publisher = "Elsevier",
number = "40",

}

Lamberg, H, Nuutinen, K, Tissari, J, Ruusunen, J, Yli-Pirilä, P, Sippula, O, Tapanainen, M, Jalava, P, Makkonen, U, Teinilä, K, Saarnio, K, Hillamo, R, Hirvonen, M-R & Jokiniemi, J 2011, 'Physicochemical characterization of fine particles from small-scale wood combustion', Atmospheric Environment, vol. 45, no. 40, pp. 7635-7643. https://doi.org/10.1016/j.atmosenv.2011.02.072

Physicochemical characterization of fine particles from small-scale wood combustion. / Lamberg, Heikki (Corresponding Author); Nuutinen, Kati; Tissari, Jarkko; Ruusunen, Jarno; Yli-Pirilä, Pasi; Sippula, Olli; Tapanainen, Maija; Jalava, Pasi; Makkonen, Ulla; Teinilä, Kimmo; Saarnio, Karri; Hillamo, Risto; Hirvonen, Maija-Riitta; Jokiniemi, Jorma.

In: Atmospheric Environment, Vol. 45, No. 40, 2011, p. 7635-7643.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Physicochemical characterization of fine particles from small-scale wood combustion

AU - Lamberg, Heikki

AU - Nuutinen, Kati

AU - Tissari, Jarkko

AU - Ruusunen, Jarno

AU - Yli-Pirilä, Pasi

AU - Sippula, Olli

AU - Tapanainen, Maija

AU - Jalava, Pasi

AU - Makkonen, Ulla

AU - Teinilä, Kimmo

AU - Saarnio, Karri

AU - Hillamo, Risto

AU - Hirvonen, Maija-Riitta

AU - Jokiniemi, Jorma

PY - 2011

Y1 - 2011

N2 - Emissions from small-scale wood combustion appliances are of special interest since fine particles have been consistently associated with adverse health effects. It has been reported that the physicochemical characteristics of the emitted particles affect also their toxic properties but the mechanisms behind these phenomena and the causative role of particles from wood combustion sources are still mostly unknown. Combustion situations vary significantly in small-scale appliances, especially in batch combustion. Combustion behaviour is affected by fuel properties, appliance type and operational practice. Particle samples were collected from six appliances representing different combustion situations in small-scale combustion. These appliances were five wood log fuelled stoves, including one stove equipped with modern combustion technology, three different conventional combustion appliances and one sauna stove. In addition, a modern small-scale pellet boiler represented advanced continuous combustion technology. The aim of the study was to analyze gas composition and fine particle properties over different combustion situations. Fine particle (PM1) emissions and their chemical constituents emerging from different combustion situations were compared and this physicochemical data was combined with the toxicological data on cellular responses induced by the same particles (see Tapanainen et al., 2011). There were significant differences in the particle emissions from different combustion situations. Overall, the efficient combustion in the pellet boiler produced the smallest emissions whereas inefficient batch combustion in a sauna stove created the largest emissions. Improved batch combustion with air-staging produced about 2.5-fold PM1 emissions compared to the modern pellet boiler (50.7 mg MJ−1 and 19.7 mg MJ−1, respectively), but the difference in the total particulate PAH content was 750-fold (90 μg MJ−1 and 0.12 μg MJ−1, respectively). Improved batch combustion and conventional batch combustion showed almost the same PM1 emissions (51.6 mg MJ−1), but a 10-fold difference in total particulate PAH emissions (910 μg MJ−1). These results highlight that same PM1 emissions can be associated with very different chemical compositions, potentially leading to different toxic properties of the particles. Thus, changing from an old, less efficient, combustion appliance to a modern appliance can have a greater impact on toxic properties than the emitted PM1 mass might indicate.

AB - Emissions from small-scale wood combustion appliances are of special interest since fine particles have been consistently associated with adverse health effects. It has been reported that the physicochemical characteristics of the emitted particles affect also their toxic properties but the mechanisms behind these phenomena and the causative role of particles from wood combustion sources are still mostly unknown. Combustion situations vary significantly in small-scale appliances, especially in batch combustion. Combustion behaviour is affected by fuel properties, appliance type and operational practice. Particle samples were collected from six appliances representing different combustion situations in small-scale combustion. These appliances were five wood log fuelled stoves, including one stove equipped with modern combustion technology, three different conventional combustion appliances and one sauna stove. In addition, a modern small-scale pellet boiler represented advanced continuous combustion technology. The aim of the study was to analyze gas composition and fine particle properties over different combustion situations. Fine particle (PM1) emissions and their chemical constituents emerging from different combustion situations were compared and this physicochemical data was combined with the toxicological data on cellular responses induced by the same particles (see Tapanainen et al., 2011). There were significant differences in the particle emissions from different combustion situations. Overall, the efficient combustion in the pellet boiler produced the smallest emissions whereas inefficient batch combustion in a sauna stove created the largest emissions. Improved batch combustion with air-staging produced about 2.5-fold PM1 emissions compared to the modern pellet boiler (50.7 mg MJ−1 and 19.7 mg MJ−1, respectively), but the difference in the total particulate PAH content was 750-fold (90 μg MJ−1 and 0.12 μg MJ−1, respectively). Improved batch combustion and conventional batch combustion showed almost the same PM1 emissions (51.6 mg MJ−1), but a 10-fold difference in total particulate PAH emissions (910 μg MJ−1). These results highlight that same PM1 emissions can be associated with very different chemical compositions, potentially leading to different toxic properties of the particles. Thus, changing from an old, less efficient, combustion appliance to a modern appliance can have a greater impact on toxic properties than the emitted PM1 mass might indicate.

KW - Wood combustion

KW - emission

KW - fine particles

KW - particle characteristics

U2 - 10.1016/j.atmosenv.2011.02.072

DO - 10.1016/j.atmosenv.2011.02.072

M3 - Article

VL - 45

SP - 7635

EP - 7643

JO - Atmospheric Environment

JF - Atmospheric Environment

SN - 1352-2310

IS - 40

ER -

Lamberg H, Nuutinen K, Tissari J, Ruusunen J, Yli-Pirilä P, Sippula O et al. Physicochemical characterization of fine particles from small-scale wood combustion. Atmospheric Environment. 2011;45(40):7635-7643. https://doi.org/10.1016/j.atmosenv.2011.02.072