Poly(ethylene glycol)-Based Poly(ionic liquid) Block Copolymers through 1,2,3-Triazole Click Reactions

Jukka Niskanen, Mathieu N. Tousignant, Alexander J. Peltekoff, Benoît H. Lessard (Corresponding Author)

Research output: Contribution to journalArticleScientificpeer-review

Abstract

1,2,3-Triazolium-based polyionic liquids (PILs) were made by a copper-catalyzed azide-alkyne cycloaddition (CuAAC) “click” reaction from poly(4-vinylbenzyl chloride). The click reaction facilitates the design and manipulation of the polymer architecture by selecting the desired alkynes, the azide-containing moieties, and the alkylating group of the 1,2,3-triazole group. Using this versatile chemistry and design, we prepared PILs with comblike homo- and block copolymer architectures using bistrifluoromethanesulfonimidate (TFSI-) as counterions. The block copolymer self-assembles into an ordered morphology. The block copolymer was integrated into metal-insulator-metal capacitors and found to display a prominent electrical double layer when characterized by electrochemical impedance spectroscopy.

Original languageEnglish
Pages (from-to)1559-1564
Number of pages6
JournalACS Applied Polymer Materials
Volume4
Issue number3
DOIs
Publication statusPublished - 11 Mar 2022
MoE publication typeA1 Journal article-refereed

Keywords

  • 1,2,3-triazolium
  • block copolymer self-assembly
  • capacitor
  • conductivity
  • copper-catalyzed azide−alkyne cycloaddition
  • poly(ionic liquid)s

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