Production of silica and calcium carbonate particles from silicate minerals for ink jet paper coating and filler purposes

Sebastian Teir, John Kettle, Ali Harlin, Juha Sarlin

Research output: Chapter in Book/Report/Conference proceedingConference article in proceedingsScientificpeer-review

Abstract

In this work, the possibility to produce silica and calcium carbonate particles of nanoscopic scale is studied. The work focuses on processes that can use magnesium- and calcium silicate minerals, such as serpentine, olivine and wollastonite, as raw materials. Experimental research has been initiated studying two different main routes: one using pressurised CO2 as a solvent and another one using strongly acidic solvents. The developed material is to be used as the top coating layer of high quality inkjet papers for high speed printing. The technical concept is to replace the expensive, relatively thick top coating layer of multiple coated premium inkjet paper with a thin top coating of nano silica particles applied directly onto the paper printing surface using either a foam or curtain coating technique. Although our ongoing experimental work has shown that wollastonite can be partially carbonated already at 10 bar total pressure, strongly acidic solvents seem far more favourable for mobilising the silica and allowing the production of pure materials. So far, our experiments have yielded >99 % pure calcite and vaterite particles with crystal sizes in the range of 50 nm to 5 ?m. Pure amorphous silica particles have also been produced with diameters in the range of tens of micrometers, but more work is required to reduce the particle size.
Original languageEnglish
Title of host publication3th International Conference on accelerated carbonation for environmental and materials engineering
Place of PublicationTurku
PublisherÅbo Akademi
Pages63-74
ISBN (Electronic)978-952-12-2506-2
ISBN (Print)978-952-12-2505-5
Publication statusPublished - 2010
MoE publication typeA4 Article in a conference publication
EventACEME10 Third International Conference on Accelerated Carbonation for Environmental and Materials Engineering - Turku, Finland
Duration: 29 Nov 20101 Dec 2010

Conference

ConferenceACEME10 Third International Conference on Accelerated Carbonation for Environmental and Materials Engineering
Abbreviated titleACEME10
CountryFinland
CityTurku
Period29/11/101/12/10

Fingerprint

calcium carbonates
inks
fillers
silicates
carbonates
minerals
silicon dioxide
coatings
printing
calcium silicates
curtains
calcite
olivine
foams
coating
magnesium
micrometers
routes
high speed
crystals

Keywords

  • silica
  • nanosilica
  • silicate
  • olivine
  • serpentine
  • wollastonite

Cite this

Teir, S., Kettle, J., Harlin, A., & Sarlin, J. (2010). Production of silica and calcium carbonate particles from silicate minerals for ink jet paper coating and filler purposes. In 3th International Conference on accelerated carbonation for environmental and materials engineering (pp. 63-74). Turku: Åbo Akademi.
Teir, Sebastian ; Kettle, John ; Harlin, Ali ; Sarlin, Juha. / Production of silica and calcium carbonate particles from silicate minerals for ink jet paper coating and filler purposes. 3th International Conference on accelerated carbonation for environmental and materials engineering. Turku : Åbo Akademi, 2010. pp. 63-74
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title = "Production of silica and calcium carbonate particles from silicate minerals for ink jet paper coating and filler purposes",
abstract = "In this work, the possibility to produce silica and calcium carbonate particles of nanoscopic scale is studied. The work focuses on processes that can use magnesium- and calcium silicate minerals, such as serpentine, olivine and wollastonite, as raw materials. Experimental research has been initiated studying two different main routes: one using pressurised CO2 as a solvent and another one using strongly acidic solvents. The developed material is to be used as the top coating layer of high quality inkjet papers for high speed printing. The technical concept is to replace the expensive, relatively thick top coating layer of multiple coated premium inkjet paper with a thin top coating of nano silica particles applied directly onto the paper printing surface using either a foam or curtain coating technique. Although our ongoing experimental work has shown that wollastonite can be partially carbonated already at 10 bar total pressure, strongly acidic solvents seem far more favourable for mobilising the silica and allowing the production of pure materials. So far, our experiments have yielded >99 {\%} pure calcite and vaterite particles with crystal sizes in the range of 50 nm to 5 ?m. Pure amorphous silica particles have also been produced with diameters in the range of tens of micrometers, but more work is required to reduce the particle size.",
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Teir, S, Kettle, J, Harlin, A & Sarlin, J 2010, Production of silica and calcium carbonate particles from silicate minerals for ink jet paper coating and filler purposes. in 3th International Conference on accelerated carbonation for environmental and materials engineering. Åbo Akademi, Turku, pp. 63-74, ACEME10 Third International Conference on Accelerated Carbonation for Environmental and Materials Engineering, Turku, Finland, 29/11/10.

Production of silica and calcium carbonate particles from silicate minerals for ink jet paper coating and filler purposes. / Teir, Sebastian; Kettle, John; Harlin, Ali; Sarlin, Juha.

3th International Conference on accelerated carbonation for environmental and materials engineering. Turku : Åbo Akademi, 2010. p. 63-74.

Research output: Chapter in Book/Report/Conference proceedingConference article in proceedingsScientificpeer-review

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T1 - Production of silica and calcium carbonate particles from silicate minerals for ink jet paper coating and filler purposes

AU - Teir, Sebastian

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AU - Harlin, Ali

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PY - 2010

Y1 - 2010

N2 - In this work, the possibility to produce silica and calcium carbonate particles of nanoscopic scale is studied. The work focuses on processes that can use magnesium- and calcium silicate minerals, such as serpentine, olivine and wollastonite, as raw materials. Experimental research has been initiated studying two different main routes: one using pressurised CO2 as a solvent and another one using strongly acidic solvents. The developed material is to be used as the top coating layer of high quality inkjet papers for high speed printing. The technical concept is to replace the expensive, relatively thick top coating layer of multiple coated premium inkjet paper with a thin top coating of nano silica particles applied directly onto the paper printing surface using either a foam or curtain coating technique. Although our ongoing experimental work has shown that wollastonite can be partially carbonated already at 10 bar total pressure, strongly acidic solvents seem far more favourable for mobilising the silica and allowing the production of pure materials. So far, our experiments have yielded >99 % pure calcite and vaterite particles with crystal sizes in the range of 50 nm to 5 ?m. Pure amorphous silica particles have also been produced with diameters in the range of tens of micrometers, but more work is required to reduce the particle size.

AB - In this work, the possibility to produce silica and calcium carbonate particles of nanoscopic scale is studied. The work focuses on processes that can use magnesium- and calcium silicate minerals, such as serpentine, olivine and wollastonite, as raw materials. Experimental research has been initiated studying two different main routes: one using pressurised CO2 as a solvent and another one using strongly acidic solvents. The developed material is to be used as the top coating layer of high quality inkjet papers for high speed printing. The technical concept is to replace the expensive, relatively thick top coating layer of multiple coated premium inkjet paper with a thin top coating of nano silica particles applied directly onto the paper printing surface using either a foam or curtain coating technique. Although our ongoing experimental work has shown that wollastonite can be partially carbonated already at 10 bar total pressure, strongly acidic solvents seem far more favourable for mobilising the silica and allowing the production of pure materials. So far, our experiments have yielded >99 % pure calcite and vaterite particles with crystal sizes in the range of 50 nm to 5 ?m. Pure amorphous silica particles have also been produced with diameters in the range of tens of micrometers, but more work is required to reduce the particle size.

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BT - 3th International Conference on accelerated carbonation for environmental and materials engineering

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Teir S, Kettle J, Harlin A, Sarlin J. Production of silica and calcium carbonate particles from silicate minerals for ink jet paper coating and filler purposes. In 3th International Conference on accelerated carbonation for environmental and materials engineering. Turku: Åbo Akademi. 2010. p. 63-74