Properties of dianionic oxyphosphorane intermediates: Implication to the reaction profile for base-catalyzed RNA hydrolysis

INIS

• levels 100%
• hydrolysis 100%
• rna 100%
• water 50%
• molecules 50%
• gases 50%
• prediction 50%
• depth 50%
• solvation 50%
• cleavage 50%
• phosphates 50%
• transfer reactions 50%
• hypothesis 50%
• ethylene 50%

Keyphrases

• Reaction Profile 100%
• RNA Hydrolysis 100%
• Pentacoordinate 100%
• Base Hydrolysis 100%
• Transition State 33%
• Solvation 16%
• Reaction Scheme 16%
• Water Molecule 16%
• Gas Phase 16%
• Methanolysis 16%
• Solvate 16%
• Ab Initio Calculations 16%
• Rate Limiting 16%
• Ethylenediamine Phosphate 16%
• Monoanion 16%
• G-levels 16%
• Phosphoryl Transfer Reaction 16%
• Well Depth 16%
• Stereoelectronic 16%
• Transition State Structure 16%

Chemistry

• Base 100%
• Enzymatic Hydrolysis 100%
• Ribonucleic Acid 100%
• Transition State 66%
• Solvation 33%
• Methanolysis 33%
• Ab Initio Calculation 33%
• Transfer Reaction 33%
• Ethylene 33%
• Phosphoryl 33%