Pulping-tailored fiber properties from a novel Brazilian Eucalyptus hybrid

Marcel Coelho dos Santos Muguet (Corresponding Author), Fernando José Borges Gomes, Kyösti Ruuttunen, Leena-Sisko Johansson, Anna-Stiina Jääskeläinen, Jorge Luiz Colodette, Tapani Vuorinen

Research output: Contribution to journalArticleScientificpeer-review

1 Citation (Scopus)

Abstract

The chemical composition and morphology of pulp fibers have a significant impact on the properties of fiber products. Pulp samples from a novel unique Eucalyptus triple hybrid [Eucalyptus grandis × (Eucalyptus urophylla × Eucalyptus globulus)] were obtained by various pulping processes – kraft, soda-anthraquinone (NaOH-AQ), and thermomechanical pulping (TMP). The chemical composition of the fiber surfaces was evaluated by X-ray photoelectron spectroscopy (XPS). The surface lignin content of NaOH-AQ pulp fibers was lower than that of the kraft counterpart. However, kraft pulp handsheets showed better physical and mechanical properties. XPS data strongly suggests that together with the pulp bulk chemical composition the xylan is more abundant on the surface of kraft fibers, which is reflected on their better mechanical properties. Moreover, the relatively low surface lignin content in TMP pulp compared to wood suggests that defibration takes place in the secondary wall, where lignin is less concentrated.
Original languageEnglish
Pages (from-to)273-282
Number of pages9
JournalHolzforschung
Volume68
Issue number3
DOIs
Publication statusPublished - 2014
MoE publication typeA1 Journal article-refereed

Fingerprint

Pulp
Lignin
Fibers
X ray photoelectron spectroscopy
Chemical analysis
Kraft process
Xylans
Anthraquinones
Mechanical properties
Kraft pulp
Wood
Physical properties

Keywords

  • eucalyptus
  • pulp
  • kraft
  • soda-anthraquinone (NaOH-AQ)
  • thermomechanical pulping
  • X-ray photoelectron spectroscopy

Cite this

Muguet, M. C. D. S., Gomes, F. J. B., Ruuttunen, K., Johansson, L-S., Jääskeläinen, A-S., Colodette, J. L., & Vuorinen, T. (2014). Pulping-tailored fiber properties from a novel Brazilian Eucalyptus hybrid. Holzforschung, 68(3), 273-282. https://doi.org/10.1515/hf-2013-0114
Muguet, Marcel Coelho dos Santos ; Gomes, Fernando José Borges ; Ruuttunen, Kyösti ; Johansson, Leena-Sisko ; Jääskeläinen, Anna-Stiina ; Colodette, Jorge Luiz ; Vuorinen, Tapani. / Pulping-tailored fiber properties from a novel Brazilian Eucalyptus hybrid. In: Holzforschung. 2014 ; Vol. 68, No. 3. pp. 273-282.
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abstract = "The chemical composition and morphology of pulp fibers have a significant impact on the properties of fiber products. Pulp samples from a novel unique Eucalyptus triple hybrid [Eucalyptus grandis × (Eucalyptus urophylla × Eucalyptus globulus)] were obtained by various pulping processes – kraft, soda-anthraquinone (NaOH-AQ), and thermomechanical pulping (TMP). The chemical composition of the fiber surfaces was evaluated by X-ray photoelectron spectroscopy (XPS). The surface lignin content of NaOH-AQ pulp fibers was lower than that of the kraft counterpart. However, kraft pulp handsheets showed better physical and mechanical properties. XPS data strongly suggests that together with the pulp bulk chemical composition the xylan is more abundant on the surface of kraft fibers, which is reflected on their better mechanical properties. Moreover, the relatively low surface lignin content in TMP pulp compared to wood suggests that defibration takes place in the secondary wall, where lignin is less concentrated.",
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Muguet, MCDS, Gomes, FJB, Ruuttunen, K, Johansson, L-S, Jääskeläinen, A-S, Colodette, JL & Vuorinen, T 2014, 'Pulping-tailored fiber properties from a novel Brazilian Eucalyptus hybrid', Holzforschung, vol. 68, no. 3, pp. 273-282. https://doi.org/10.1515/hf-2013-0114

Pulping-tailored fiber properties from a novel Brazilian Eucalyptus hybrid. / Muguet, Marcel Coelho dos Santos (Corresponding Author); Gomes, Fernando José Borges; Ruuttunen, Kyösti; Johansson, Leena-Sisko; Jääskeläinen, Anna-Stiina; Colodette, Jorge Luiz; Vuorinen, Tapani.

In: Holzforschung, Vol. 68, No. 3, 2014, p. 273-282.

Research output: Contribution to journalArticleScientificpeer-review

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AU - Muguet, Marcel Coelho dos Santos

AU - Gomes, Fernando José Borges

AU - Ruuttunen, Kyösti

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AU - Jääskeläinen, Anna-Stiina

AU - Colodette, Jorge Luiz

AU - Vuorinen, Tapani

PY - 2014

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AB - The chemical composition and morphology of pulp fibers have a significant impact on the properties of fiber products. Pulp samples from a novel unique Eucalyptus triple hybrid [Eucalyptus grandis × (Eucalyptus urophylla × Eucalyptus globulus)] were obtained by various pulping processes – kraft, soda-anthraquinone (NaOH-AQ), and thermomechanical pulping (TMP). The chemical composition of the fiber surfaces was evaluated by X-ray photoelectron spectroscopy (XPS). The surface lignin content of NaOH-AQ pulp fibers was lower than that of the kraft counterpart. However, kraft pulp handsheets showed better physical and mechanical properties. XPS data strongly suggests that together with the pulp bulk chemical composition the xylan is more abundant on the surface of kraft fibers, which is reflected on their better mechanical properties. Moreover, the relatively low surface lignin content in TMP pulp compared to wood suggests that defibration takes place in the secondary wall, where lignin is less concentrated.

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KW - soda-anthraquinone (NaOH-AQ)

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Muguet MCDS, Gomes FJB, Ruuttunen K, Johansson L-S, Jääskeläinen A-S, Colodette JL et al. Pulping-tailored fiber properties from a novel Brazilian Eucalyptus hybrid. Holzforschung. 2014;68(3):273-282. https://doi.org/10.1515/hf-2013-0114