Quantitative characterization of pore structure of several biochars with 3D imaging

Jari Hyväluoma, Sampo Kulju, Markus Hannula, Hanne Wikberg, Anssi Källi, Kimmo Rasa

    Research output: Contribution to journalArticleScientificpeer-review

    24 Citations (Scopus)

    Abstract

    Pore space characteristics of biochars may vary depending on the used raw material and processing technology. Pore structure has significant effects on the water retention properties of biochar amended soils. In this work, several biochars were characterized with three-dimensional imaging and image analysis. X-ray computed microtomography was used to image biochars at resolution of 1.14 µm and the obtained images were analysed for porosity, pore size distribution, specific surface area and structural anisotropy. In addition, random walk simulations were used to relate structural anisotropy to diffusive transport. Image analysis showed that considerable part of the biochar volume consist of pores in size range relevant to hydrological processes and storage of plant available water. Porosity and pore size distribution were found to depend on the biochar type and the structural anisotopy analysis showed that used raw material considerably affects the pore characteristics at micrometre scale. Therefore, attention should be paid to raw material selection and quality in applications requiring optimized pore structure.
    Original languageEnglish
    Pages (from-to)25648–25658
    Number of pages11
    JournalEnvironmental Science and Pollution Research
    Volume25
    Issue number26
    Early online date2017
    DOIs
    Publication statusPublished - 2018
    MoE publication typeA1 Journal article-refereed

    Keywords

    • biochar
    • image analysis
    • pore structure
    • soil amendment
    • water retention
    • x-ray tomography

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