Raman investigation of minor component reaction during polymer synthesis process

Marcin Gnyba, Mikko Keränen, Janne Suhonen, Pentti Niemelä, Robert Bogdanowicz, Malgorzata Jedrzejewska-Szczerska

    Research output: Chapter in Book/Report/Conference proceedingConference article in proceedingsScientificpeer-review

    1 Citation (Scopus)

    Abstract

    Raman spectroscopy was applied to study the reactions between amine and epoxy groups, which had been expected to proceed during synthesis of hybrid polymer based on three monomers: 3-aminopropyltrimethoxysilane (APTES), 3-glycidyloxypropyl-trimethoxysilane (GPTS) and methacryloxy-propyltrimethoxysilane (MPTS). Efficiency of the investigated reaction determines the molecular structure of the organic network and consequently - mechanical and optical properties of manufactured material. An optical system developed for the real-time Raman monitoring was connected with typical glass reaction vessel and non-invasive measurements were made. Additional FT-Raman investigation was carried out to confirm obtained results. Transformation of primary amine as well as epoxy ring opening was confirmed and role of catalyzers was discussed.
    Original languageEnglish
    Title of host publicationIV Workshop on Atomic and Molecular Physics
    EditorsJozef Heldt
    PublisherInternational Society for Optics and Photonics SPIE
    Pages182-185
    DOIs
    Publication statusPublished - 2003
    MoE publication typeA4 Article in a conference publication
    EventIV Workshop on Atomic and Molecular Physics - Jurata, Poland
    Duration: 19 Sept 200321 Sept 2003

    Publication series

    SeriesProceedings of SPIE
    Volume5258
    ISSN0277-786X

    Conference

    ConferenceIV Workshop on Atomic and Molecular Physics
    Country/TerritoryPoland
    CityJurata
    Period19/09/0321/09/03

    Keywords

    • hybrid polymers
    • Raman spectroscopy

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