Recovery of hydrogen sulfide formed during black liquor gasification

Paterson McKeough

Research output: Book/ReportReport

Abstract

A process, in which the hydrogen sulfide formed during black liquor gasifi cation is absorbed into green liquor, was assessed. In particular, the stoichiometry and equilibria of the pertinent reactions were examined. The process was determined to be feasible at elevated pressures, except possibly for gasification processes with low yields of hydrogen sulfide . A condition is that, in the absorber, the mass transfer resistance in the gas phase is low. In all cases, the predicted lime requirement for recausticization of the final green liquor was higher than that of the conventional recovery process. Implications for the mill energy balance were evaluated.
Original languageEnglish
Place of PublicationEspoo
PublisherVTT Technical Research Centre of Finland
Number of pages32
ISBN (Print)951-38-4412-9
Publication statusPublished - 1994
MoE publication typeNot Eligible

Publication series

SeriesVTT Publications
Number174
ISSN1235-0621

Fingerprint

hydrogen sulfide
stoichiometry
energy balance
lime
mass transfer
mill
cation
gas
gasification

Keywords

  • black liquor
  • gasification
  • hydrogen sulfide
  • recovery
  • absorption

Cite this

McKeough, P. (1994). Recovery of hydrogen sulfide formed during black liquor gasification. Espoo: VTT Technical Research Centre of Finland. VTT Publications, No. 174
McKeough, Paterson. / Recovery of hydrogen sulfide formed during black liquor gasification. Espoo : VTT Technical Research Centre of Finland, 1994. 32 p. (VTT Publications; No. 174).
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McKeough, P 1994, Recovery of hydrogen sulfide formed during black liquor gasification. VTT Publications, no. 174, VTT Technical Research Centre of Finland, Espoo.

Recovery of hydrogen sulfide formed during black liquor gasification. / McKeough, Paterson.

Espoo : VTT Technical Research Centre of Finland, 1994. 32 p. (VTT Publications; No. 174).

Research output: Book/ReportReport

TY - BOOK

T1 - Recovery of hydrogen sulfide formed during black liquor gasification

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N1 - Project code: ENE41031

PY - 1994

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N2 - A process, in which the hydrogen sulfide formed during black liquor gasifi cation is absorbed into green liquor, was assessed. In particular, the stoichiometry and equilibria of the pertinent reactions were examined. The process was determined to be feasible at elevated pressures, except possibly for gasification processes with low yields of hydrogen sulfide . A condition is that, in the absorber, the mass transfer resistance in the gas phase is low. In all cases, the predicted lime requirement for recausticization of the final green liquor was higher than that of the conventional recovery process. Implications for the mill energy balance were evaluated.

AB - A process, in which the hydrogen sulfide formed during black liquor gasifi cation is absorbed into green liquor, was assessed. In particular, the stoichiometry and equilibria of the pertinent reactions were examined. The process was determined to be feasible at elevated pressures, except possibly for gasification processes with low yields of hydrogen sulfide . A condition is that, in the absorber, the mass transfer resistance in the gas phase is low. In all cases, the predicted lime requirement for recausticization of the final green liquor was higher than that of the conventional recovery process. Implications for the mill energy balance were evaluated.

KW - black liquor

KW - gasification

KW - hydrogen sulfide

KW - recovery

KW - absorption

M3 - Report

SN - 951-38-4412-9

T3 - VTT Publications

BT - Recovery of hydrogen sulfide formed during black liquor gasification

PB - VTT Technical Research Centre of Finland

CY - Espoo

ER -

McKeough P. Recovery of hydrogen sulfide formed during black liquor gasification. Espoo: VTT Technical Research Centre of Finland, 1994. 32 p. (VTT Publications; No. 174).