Remote plasma ALD silver nanoparticles on graphene

Sanna Arpiainen, Y. Chen, M. Mäkelä, J. Niinistö, Harri Lipsanen, Jouni Ahopelto, M. Ritala, M. Leskelä

    Research output: Chapter in Book/Report/Conference proceedingConference abstract in proceedingsScientific

    Abstract

    We report on the growth of silver nanoparticles (AgNPs) on graphene and study the applicability of the material for Surface Enhanced Raman Spectroscopy (SERS). Graphene has been shown to enhance the SERS signal with AgNPs by a factor of 2 - 17 due to charge transfer effects. Direct deposition of NPs can provide more uniform spatial distribution than spin on deposition of chemically derived NPs, and ALD has more potential for tuning the NP size and density if compared to evaporation. In experiments, the relative enhancement in R6G SERS signal was similar on both SIO2 and graphene templates, despite the lower density of the AgNPs on graphene. Most importantly, graphene was found to quench the background fluorescence by an order of magnitude when compared to SiO2.
    Original languageEnglish
    Title of host publicationBALD2014 Abstract book
    Publication statusPublished - 2014
    MoE publication typeNot Eligible
    Event12th International Baltic Conference on Atomic Layer Deposition, Baltic ALD 2014 - Helsinki, Finland
    Duration: 12 May 201413 May 2014
    Conference number: 12
    http://www.aldcoe.fi/bald2014/program.pdf (Program)
    http://www.aldcoe.fi/bald2014/posters.pdf (Posters)

    Conference

    Conference12th International Baltic Conference on Atomic Layer Deposition, Baltic ALD 2014
    Abbreviated titleBaltic ALD 2014
    CountryFinland
    CityHelsinki
    Period12/05/1413/05/14
    OtherAbstracts reviewed and published.
    Internet address

    Fingerprint

    Graphite
    Silver
    Nanoparticles
    Plasmas
    Raman spectroscopy
    Spatial distribution
    Charge transfer
    Evaporation
    Tuning
    Fluorescence
    Experiments

    Keywords

    • graphene
    • remote plasma ALD
    • nanoparticle
    • SERS

    Cite this

    Arpiainen, S., Chen, Y., Mäkelä, M., Niinistö, J., Lipsanen, H., Ahopelto, J., ... Leskelä, M. (2014). Remote plasma ALD silver nanoparticles on graphene. In BALD2014 Abstract book
    Arpiainen, Sanna ; Chen, Y. ; Mäkelä, M. ; Niinistö, J. ; Lipsanen, Harri ; Ahopelto, Jouni ; Ritala, M. ; Leskelä, M. / Remote plasma ALD silver nanoparticles on graphene. BALD2014 Abstract book. 2014.
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    title = "Remote plasma ALD silver nanoparticles on graphene",
    abstract = "We report on the growth of silver nanoparticles (AgNPs) on graphene and study the applicability of the material for Surface Enhanced Raman Spectroscopy (SERS). Graphene has been shown to enhance the SERS signal with AgNPs by a factor of 2 - 17 due to charge transfer effects. Direct deposition of NPs can provide more uniform spatial distribution than spin on deposition of chemically derived NPs, and ALD has more potential for tuning the NP size and density if compared to evaporation. In experiments, the relative enhancement in R6G SERS signal was similar on both SIO2 and graphene templates, despite the lower density of the AgNPs on graphene. Most importantly, graphene was found to quench the background fluorescence by an order of magnitude when compared to SiO2.",
    keywords = "graphene, remote plasma ALD, nanoparticle, SERS",
    author = "Sanna Arpiainen and Y. Chen and M. M{\"a}kel{\"a} and J. Niinist{\"o} and Harri Lipsanen and Jouni Ahopelto and M. Ritala and M. Leskel{\"a}",
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    Arpiainen, S, Chen, Y, Mäkelä, M, Niinistö, J, Lipsanen, H, Ahopelto, J, Ritala, M & Leskelä, M 2014, Remote plasma ALD silver nanoparticles on graphene. in BALD2014 Abstract book. 12th International Baltic Conference on Atomic Layer Deposition, Baltic ALD 2014, Helsinki, Finland, 12/05/14.

    Remote plasma ALD silver nanoparticles on graphene. / Arpiainen, Sanna; Chen, Y.; Mäkelä, M.; Niinistö, J.; Lipsanen, Harri; Ahopelto, Jouni; Ritala, M.; Leskelä, M.

    BALD2014 Abstract book. 2014.

    Research output: Chapter in Book/Report/Conference proceedingConference abstract in proceedingsScientific

    TY - CHAP

    T1 - Remote plasma ALD silver nanoparticles on graphene

    AU - Arpiainen, Sanna

    AU - Chen, Y.

    AU - Mäkelä, M.

    AU - Niinistö, J.

    AU - Lipsanen, Harri

    AU - Ahopelto, Jouni

    AU - Ritala, M.

    AU - Leskelä, M.

    N1 - HUO: Poster presentation Project code: 73337

    PY - 2014

    Y1 - 2014

    N2 - We report on the growth of silver nanoparticles (AgNPs) on graphene and study the applicability of the material for Surface Enhanced Raman Spectroscopy (SERS). Graphene has been shown to enhance the SERS signal with AgNPs by a factor of 2 - 17 due to charge transfer effects. Direct deposition of NPs can provide more uniform spatial distribution than spin on deposition of chemically derived NPs, and ALD has more potential for tuning the NP size and density if compared to evaporation. In experiments, the relative enhancement in R6G SERS signal was similar on both SIO2 and graphene templates, despite the lower density of the AgNPs on graphene. Most importantly, graphene was found to quench the background fluorescence by an order of magnitude when compared to SiO2.

    AB - We report on the growth of silver nanoparticles (AgNPs) on graphene and study the applicability of the material for Surface Enhanced Raman Spectroscopy (SERS). Graphene has been shown to enhance the SERS signal with AgNPs by a factor of 2 - 17 due to charge transfer effects. Direct deposition of NPs can provide more uniform spatial distribution than spin on deposition of chemically derived NPs, and ALD has more potential for tuning the NP size and density if compared to evaporation. In experiments, the relative enhancement in R6G SERS signal was similar on both SIO2 and graphene templates, despite the lower density of the AgNPs on graphene. Most importantly, graphene was found to quench the background fluorescence by an order of magnitude when compared to SiO2.

    KW - graphene

    KW - remote plasma ALD

    KW - nanoparticle

    KW - SERS

    M3 - Conference abstract in proceedings

    BT - BALD2014 Abstract book

    ER -

    Arpiainen S, Chen Y, Mäkelä M, Niinistö J, Lipsanen H, Ahopelto J et al. Remote plasma ALD silver nanoparticles on graphene. In BALD2014 Abstract book. 2014