TY - JOUR
T1 - Revised structure of antidesmone, an unusual alkaloid from tropical Antidesma plants (Euphorbiaceae)
AU - Bringmann, G.
AU - Schlauer, J.
AU - Rischer, Heiko
AU - Wohlfarth, M.
AU - Mühlbacher, J.
AU - Buske, A.
AU - Porzel, A.
AU - Schmidt, J.
AU - Adam, G.
PY - 2000
Y1 - 2000
N2 - The structure of antidesmone, an alkaloid from Antidesma membranaceum Müll. Arg. and A. venosum E. Mey. (Euphorbiaceae), was revised to be (S)-4,8-dioxo-3-methoxy-2-methyl-5-n-octyl-1,4,5,6,7,8-hexahydroquinoline [(S)-2], not the isoquinoline derivative 1, as assumed previously. The revision was initiated by biosynthetic feeding experiments of one of our groups.
AB - The structure of antidesmone, an alkaloid from Antidesma membranaceum Müll. Arg. and A. venosum E. Mey. (Euphorbiaceae), was revised to be (S)-4,8-dioxo-3-methoxy-2-methyl-5-n-octyl-1,4,5,6,7,8-hexahydroquinoline [(S)-2], not the isoquinoline derivative 1, as assumed previously. The revision was initiated by biosynthetic feeding experiments of one of our groups.
U2 - 10.1016/S0040-4020(00)00289-1
DO - 10.1016/S0040-4020(00)00289-1
M3 - Article
SN - 0040-4020
VL - 56
SP - 3691
EP - 3695
JO - Tetrahedron
JF - Tetrahedron
IS - 23
ER -