Revised structure of antidesmone, an unusual alkaloid from tropical Antidesma plants (Euphorbiaceae)

G. Bringmann; J. Schlauer; Heiko Rischer; M. Wohlfarth; J. Mühlbacher; A. Buske; A. Porzel; J. Schmidt; G. Adam

doi:10.1016/S0040-4020(00)00289-1

Revised structure of antidesmone, an unusual alkaloid from tropical Antidesma plants (Euphorbiaceae)

G. Bringmann^*
, J. Schlauer
, Heiko Rischer
, M. Wohlfarth
, J. Mühlbacher
, A. Buske
, A. Porzel
, J. Schmidt
, G. Adam

^*Corresponding author for this work

Not published at VTT

Research output: Contribution to journal › Article › Scientific › peer-review

43 Citations (Scopus)

Abstract

The structure of antidesmone, an alkaloid from Antidesma membranaceum Müll. Arg. and A. venosum E. Mey. (Euphorbiaceae), was revised to be (S)-4,8-dioxo-3-methoxy-2-methyl-5-n-octyl-1,4,5,6,7,8-hexahydroquinoline [(S)-2], not the isoquinoline derivative 1, as assumed previously. The revision was initiated by biosynthetic feeding experiments of one of our groups.

Original language	English
Pages (from-to)	3691-3695
Number of pages	5
Journal	Tetrahedron
Volume	56
Issue number	23
DOIs	https://doi.org/10.1016/S0040-4020(00)00289-1
Publication status	Published - 2000
MoE publication type	Not Eligible

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abstract = "The structure of antidesmone, an alkaloid from Antidesma membranaceum M{\"u}ll. Arg. and A. venosum E. Mey. (Euphorbiaceae), was revised to be (S)-4,8-dioxo-3-methoxy-2-methyl-5-n-octyl-1,4,5,6,7,8-hexahydroquinoline [(S)-2], not the isoquinoline derivative 1, as assumed previously. The revision was initiated by biosynthetic feeding experiments of one of our groups.",

author = "G. Bringmann and J. Schlauer and Heiko Rischer and M. Wohlfarth and J. M{\"u}hlbacher and A. Buske and A. Porzel and J. Schmidt and G. Adam",

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doi = "10.1016/S0040-4020(00)00289-1",

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T1 - Revised structure of antidesmone, an unusual alkaloid from tropical Antidesma plants (Euphorbiaceae)

AU - Bringmann, G.

AU - Schlauer, J.

AU - Rischer, Heiko

AU - Wohlfarth, M.

AU - Mühlbacher, J.

AU - Buske, A.

AU - Porzel, A.

AU - Schmidt, J.

AU - Adam, G.

PY - 2000

Y1 - 2000

N2 - The structure of antidesmone, an alkaloid from Antidesma membranaceum Müll. Arg. and A. venosum E. Mey. (Euphorbiaceae), was revised to be (S)-4,8-dioxo-3-methoxy-2-methyl-5-n-octyl-1,4,5,6,7,8-hexahydroquinoline [(S)-2], not the isoquinoline derivative 1, as assumed previously. The revision was initiated by biosynthetic feeding experiments of one of our groups.

AB - The structure of antidesmone, an alkaloid from Antidesma membranaceum Müll. Arg. and A. venosum E. Mey. (Euphorbiaceae), was revised to be (S)-4,8-dioxo-3-methoxy-2-methyl-5-n-octyl-1,4,5,6,7,8-hexahydroquinoline [(S)-2], not the isoquinoline derivative 1, as assumed previously. The revision was initiated by biosynthetic feeding experiments of one of our groups.

U2 - 10.1016/S0040-4020(00)00289-1

DO - 10.1016/S0040-4020(00)00289-1

M3 - Article

SN - 0040-4020

VL - 56

SP - 3691

EP - 3695

JO - Tetrahedron

JF - Tetrahedron

IS - 23

ER -

Revised structure of antidesmone, an unusual alkaloid from tropical Antidesma plants (Euphorbiaceae)

Abstract

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