Ru3(CO)12/2,2'-bipyrine supported on inorganic carriers as 1-hexene hydroformylation catalysts

Leila Alvila; Juha Pursiainen; Jari Kiviaho; Tapani Pakkanen; Outi Krause

doi:10.1016/0304-5102(94)00044-1

Ru₃(CO)₁₂/2,2'-bipyrine supported on inorganic carriers as 1-hexene hydroformylation catalysts

Leila Alvila^*, Juha Pursiainen, Jari Kiviaho, Tapani Pakkanen, Outi Krause

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

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Abstract

Ru₃(CO)₁₂ and 2,2′-bipyridine were supported on various inorganic carriers and used as hydroformylation catalysts. The stability of the catalyst was studied by determining ruthenium contents of hydroformylation products and also by special dissolution tests. Ruthenium was found to dissolve in hydroformylation products (aldehydes and alcohols). However, the nature of the catalyst proved to be mainly heterogeneous.

Original language	English
Pages (from-to)	335-342
Journal	Journal of Molecular Catalysis
Volume	91
Issue number	3
DOIs	https://doi.org/10.1016/0304-5102(94)00044-1
Publication status	Published - 1994
MoE publication type	A1 Journal article-refereed

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10.1016/0304-5102(94)00044-1

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title = "Ru3(CO)12/2,2'-bipyrine supported on inorganic carriers as 1-hexene hydroformylation catalysts",

abstract = "Ru3(CO)12 and 2,2′-bipyridine were supported on various inorganic carriers and used as hydroformylation catalysts. The stability of the catalyst was studied by determining ruthenium contents of hydroformylation products and also by special dissolution tests. Ruthenium was found to dissolve in hydroformylation products (aldehydes and alcohols). However, the nature of the catalyst proved to be mainly heterogeneous.",

author = "Leila Alvila and Juha Pursiainen and Jari Kiviaho and Tapani Pakkanen and Outi Krause",

year = "1994",

doi = "10.1016/0304-5102(94)00044-1",

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journal = "Journal of Molecular Catalysis",

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T1 - Ru3(CO)12/2,2'-bipyrine supported on inorganic carriers as 1-hexene hydroformylation catalysts

AU - Alvila, Leila

AU - Pursiainen, Juha

AU - Kiviaho, Jari

AU - Pakkanen, Tapani

AU - Krause, Outi

PY - 1994

Y1 - 1994

N2 - Ru3(CO)12 and 2,2′-bipyridine were supported on various inorganic carriers and used as hydroformylation catalysts. The stability of the catalyst was studied by determining ruthenium contents of hydroformylation products and also by special dissolution tests. Ruthenium was found to dissolve in hydroformylation products (aldehydes and alcohols). However, the nature of the catalyst proved to be mainly heterogeneous.

AB - Ru3(CO)12 and 2,2′-bipyridine were supported on various inorganic carriers and used as hydroformylation catalysts. The stability of the catalyst was studied by determining ruthenium contents of hydroformylation products and also by special dissolution tests. Ruthenium was found to dissolve in hydroformylation products (aldehydes and alcohols). However, the nature of the catalyst proved to be mainly heterogeneous.

U2 - 10.1016/0304-5102(94)00044-1

DO - 10.1016/0304-5102(94)00044-1

M3 - Article

SN - 0304-5102

VL - 91

SP - 335

EP - 342

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

IS - 3

ER -

Ru3(CO)12/2,2'-bipyrine supported on inorganic carriers as 1-hexene hydroformylation catalysts

Abstract

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Ru₃(CO)₁₂/2,2'-bipyrine supported on inorganic carriers as 1-hexene hydroformylation catalysts