Ru3(CO)12/2,2'-bipyrine supported on inorganic carriers as 1-hexene hydroformylation catalysts

Leila Alvila (Corresponding Author), Juha Pursiainen, Jari Kiviaho, Pakkanen Tapani, Outi Krause

Research output: Contribution to journalArticleScientificpeer-review

29 Citations (Scopus)

Abstract

Ru3(CO)12 and 2,2′-bipyridine were supported on various inorganic carriers and used as hydroformylation catalysts. The stability of the catalyst was studied by determining ruthenium contents of hydroformylation products and also by special dissolution tests. Ruthenium was found to dissolve in hydroformylation products (aldehydes and alcohols). However, the nature of the catalyst proved to be mainly heterogeneous.
Original languageEnglish
Pages (from-to)335-342
Number of pages8
JournalJournal of Molecular Catalysis
Volume91
Issue number3
DOIs
Publication statusPublished - 1994
MoE publication typeA1 Journal article-refereed

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Hydroformylation
Ruthenium
Catalysts
Aldehydes
Dissolution
Alcohols

Cite this

Alvila, Leila ; Pursiainen, Juha ; Kiviaho, Jari ; Tapani, Pakkanen ; Krause, Outi. / Ru3(CO)12/2,2'-bipyrine supported on inorganic carriers as 1-hexene hydroformylation catalysts. In: Journal of Molecular Catalysis. 1994 ; Vol. 91, No. 3. pp. 335-342.
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abstract = "Ru3(CO)12 and 2,2′-bipyridine were supported on various inorganic carriers and used as hydroformylation catalysts. The stability of the catalyst was studied by determining ruthenium contents of hydroformylation products and also by special dissolution tests. Ruthenium was found to dissolve in hydroformylation products (aldehydes and alcohols). However, the nature of the catalyst proved to be mainly heterogeneous.",
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Ru3(CO)12/2,2'-bipyrine supported on inorganic carriers as 1-hexene hydroformylation catalysts. / Alvila, Leila (Corresponding Author); Pursiainen, Juha; Kiviaho, Jari; Tapani, Pakkanen; Krause, Outi.

In: Journal of Molecular Catalysis, Vol. 91, No. 3, 1994, p. 335-342.

Research output: Contribution to journalArticleScientificpeer-review

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T1 - Ru3(CO)12/2,2'-bipyrine supported on inorganic carriers as 1-hexene hydroformylation catalysts

AU - Alvila, Leila

AU - Pursiainen, Juha

AU - Kiviaho, Jari

AU - Tapani, Pakkanen

AU - Krause, Outi

PY - 1994

Y1 - 1994

N2 - Ru3(CO)12 and 2,2′-bipyridine were supported on various inorganic carriers and used as hydroformylation catalysts. The stability of the catalyst was studied by determining ruthenium contents of hydroformylation products and also by special dissolution tests. Ruthenium was found to dissolve in hydroformylation products (aldehydes and alcohols). However, the nature of the catalyst proved to be mainly heterogeneous.

AB - Ru3(CO)12 and 2,2′-bipyridine were supported on various inorganic carriers and used as hydroformylation catalysts. The stability of the catalyst was studied by determining ruthenium contents of hydroformylation products and also by special dissolution tests. Ruthenium was found to dissolve in hydroformylation products (aldehydes and alcohols). However, the nature of the catalyst proved to be mainly heterogeneous.

U2 - 10.1016/0304-5102(94)00044-1

DO - 10.1016/0304-5102(94)00044-1

M3 - Article

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SP - 335

EP - 342

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

SN - 0304-5102

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ER -