Safety Aspects of Polymer Films with Atomic Layer Deposited Thin Al2O3 Barrier Layers

Mika Vähä-Nissi, Marja Pitkänen, Erkki Salo, Jenni Sievänen, Matti Putkonen, Ali Harlin

Research output: Contribution to conferenceConference AbstractScientificpeer-review

Abstract

Atomic layer deposition (ALD) is an efficient tool for improving the barrier properties of polymer films and polymer-coated papers/paperboards. However, adequate barrier properties are only one of the requirements set for the packaging materials. The purpose here is to present the safety aspects related to polymer films with a thin ALD deposited oxide barrier layers, especially those with Al2O3. Several approaches for testing ALD material were utilized. Based on our analyses ALD grown uniform Al2O3 thin barrier layers do not fall under the European Commission's definition of nanomaterial and the related limitations in the Commission Regulation. Plastic food contact materials may also contain non-authorized substances provided that their migration to food do not exceed very low migration limit (0.01 mg/kg food) and they are not mutagenic, carcinogenic nor toxic for reproduction, or are in nanoform. However, functional barrier concept should not be used to separate food and nanomaterial. Meanwhile, U.S. Food and Drug Administration (FDA) has a more inclusive approach to identifying products of interest in context of nanotechnology including size and/or function. FDA does not categorically judge products containing nanomaterials to be inherently harmful. Al2O3 and organic compounds of interest, such as ethylene glycol and glycerol, are accepted in Europe as additives for plastics in contact with food. Likewise, in USA these are accepted as either as indirect additives used in food contact substances or generally regarded as safe. According to some producers AlOx coatings have also been approved in USA for indirect contact with food. In our experiments abrasive testing of polymer films, although detrimental in several cases to the film itself, did not increase the number of airborne particles. ALD Al2O3 deposited at 100 ºC onto silicon and commercial polymer films were also exposed to liquid food simulants while evaluating the change in surface and barrier properties. Finally, we also tested the films for migration, although overall migration from thin films has been previously regarded as extremely low. The Al2O3 coated films were affected by the simulant exposure, but the impact depended on the substrate material and the oxidizing precursor. This indicates different thin layer growth on different polymer films. As a conclusion, ALD grown Al2O3 thin layer requires an additional, for example, laminated or extrusion coated top layer to protect it from both mechanical and chemical stresses, to prevent migration to the food, and also to act as a sealant layer in food packaging.
Original languageEnglish
Publication statusPublished - 2013
Event13th International Conference on Atomic Layer Deposition, ALD 2013 - San Diego, California, San Diego, United States
Duration: 28 Jul 201331 Jul 2013
Conference number: 13

Conference

Conference13th International Conference on Atomic Layer Deposition, ALD 2013
Abbreviated titleALD 2013
CountryUnited States
CitySan Diego
Period28/07/1331/07/13

Fingerprint

films (materials)
polymers
nanomaterials
plastics
indirect contact
paperboard
abrasives
nanotechnology
food packaging
ethylene glycol
packaging materials
silicon
organic compounds
extrusion
coatings
oxides
glycerol
foods
testing
liquids

Keywords

  • ALD
  • aluminium oxide
  • atomic layer deposition
  • oxygen barrier
  • migration
  • nanotechnology
  • safety

Cite this

Vähä-Nissi, M., Pitkänen, M., Salo, E., Sievänen, J., Putkonen, M., & Harlin, A. (2013). Safety Aspects of Polymer Films with Atomic Layer Deposited Thin Al2O3 Barrier Layers. Abstract from 13th International Conference on Atomic Layer Deposition, ALD 2013, San Diego, United States.
Vähä-Nissi, Mika ; Pitkänen, Marja ; Salo, Erkki ; Sievänen, Jenni ; Putkonen, Matti ; Harlin, Ali. / Safety Aspects of Polymer Films with Atomic Layer Deposited Thin Al2O3 Barrier Layers. Abstract from 13th International Conference on Atomic Layer Deposition, ALD 2013, San Diego, United States.
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Vähä-Nissi, M, Pitkänen, M, Salo, E, Sievänen, J, Putkonen, M & Harlin, A 2013, 'Safety Aspects of Polymer Films with Atomic Layer Deposited Thin Al2O3 Barrier Layers' 13th International Conference on Atomic Layer Deposition, ALD 2013, San Diego, United States, 28/07/13 - 31/07/13, .

Safety Aspects of Polymer Films with Atomic Layer Deposited Thin Al2O3 Barrier Layers. / Vähä-Nissi, Mika; Pitkänen, Marja; Salo, Erkki; Sievänen, Jenni; Putkonen, Matti; Harlin, Ali.

2013. Abstract from 13th International Conference on Atomic Layer Deposition, ALD 2013, San Diego, United States.

Research output: Contribution to conferenceConference AbstractScientificpeer-review

TY - CONF

T1 - Safety Aspects of Polymer Films with Atomic Layer Deposited Thin Al2O3 Barrier Layers

AU - Vähä-Nissi, Mika

AU - Pitkänen, Marja

AU - Salo, Erkki

AU - Sievänen, Jenni

AU - Putkonen, Matti

AU - Harlin, Ali

N1 - Project code: 70962

PY - 2013

Y1 - 2013

N2 - Atomic layer deposition (ALD) is an efficient tool for improving the barrier properties of polymer films and polymer-coated papers/paperboards. However, adequate barrier properties are only one of the requirements set for the packaging materials. The purpose here is to present the safety aspects related to polymer films with a thin ALD deposited oxide barrier layers, especially those with Al2O3. Several approaches for testing ALD material were utilized. Based on our analyses ALD grown uniform Al2O3 thin barrier layers do not fall under the European Commission's definition of nanomaterial and the related limitations in the Commission Regulation. Plastic food contact materials may also contain non-authorized substances provided that their migration to food do not exceed very low migration limit (0.01 mg/kg food) and they are not mutagenic, carcinogenic nor toxic for reproduction, or are in nanoform. However, functional barrier concept should not be used to separate food and nanomaterial. Meanwhile, U.S. Food and Drug Administration (FDA) has a more inclusive approach to identifying products of interest in context of nanotechnology including size and/or function. FDA does not categorically judge products containing nanomaterials to be inherently harmful. Al2O3 and organic compounds of interest, such as ethylene glycol and glycerol, are accepted in Europe as additives for plastics in contact with food. Likewise, in USA these are accepted as either as indirect additives used in food contact substances or generally regarded as safe. According to some producers AlOx coatings have also been approved in USA for indirect contact with food. In our experiments abrasive testing of polymer films, although detrimental in several cases to the film itself, did not increase the number of airborne particles. ALD Al2O3 deposited at 100 ºC onto silicon and commercial polymer films were also exposed to liquid food simulants while evaluating the change in surface and barrier properties. Finally, we also tested the films for migration, although overall migration from thin films has been previously regarded as extremely low. The Al2O3 coated films were affected by the simulant exposure, but the impact depended on the substrate material and the oxidizing precursor. This indicates different thin layer growth on different polymer films. As a conclusion, ALD grown Al2O3 thin layer requires an additional, for example, laminated or extrusion coated top layer to protect it from both mechanical and chemical stresses, to prevent migration to the food, and also to act as a sealant layer in food packaging.

AB - Atomic layer deposition (ALD) is an efficient tool for improving the barrier properties of polymer films and polymer-coated papers/paperboards. However, adequate barrier properties are only one of the requirements set for the packaging materials. The purpose here is to present the safety aspects related to polymer films with a thin ALD deposited oxide barrier layers, especially those with Al2O3. Several approaches for testing ALD material were utilized. Based on our analyses ALD grown uniform Al2O3 thin barrier layers do not fall under the European Commission's definition of nanomaterial and the related limitations in the Commission Regulation. Plastic food contact materials may also contain non-authorized substances provided that their migration to food do not exceed very low migration limit (0.01 mg/kg food) and they are not mutagenic, carcinogenic nor toxic for reproduction, or are in nanoform. However, functional barrier concept should not be used to separate food and nanomaterial. Meanwhile, U.S. Food and Drug Administration (FDA) has a more inclusive approach to identifying products of interest in context of nanotechnology including size and/or function. FDA does not categorically judge products containing nanomaterials to be inherently harmful. Al2O3 and organic compounds of interest, such as ethylene glycol and glycerol, are accepted in Europe as additives for plastics in contact with food. Likewise, in USA these are accepted as either as indirect additives used in food contact substances or generally regarded as safe. According to some producers AlOx coatings have also been approved in USA for indirect contact with food. In our experiments abrasive testing of polymer films, although detrimental in several cases to the film itself, did not increase the number of airborne particles. ALD Al2O3 deposited at 100 ºC onto silicon and commercial polymer films were also exposed to liquid food simulants while evaluating the change in surface and barrier properties. Finally, we also tested the films for migration, although overall migration from thin films has been previously regarded as extremely low. The Al2O3 coated films were affected by the simulant exposure, but the impact depended on the substrate material and the oxidizing precursor. This indicates different thin layer growth on different polymer films. As a conclusion, ALD grown Al2O3 thin layer requires an additional, for example, laminated or extrusion coated top layer to protect it from both mechanical and chemical stresses, to prevent migration to the food, and also to act as a sealant layer in food packaging.

KW - ALD

KW - aluminium oxide

KW - atomic layer deposition

KW - oxygen barrier

KW - migration

KW - nanotechnology

KW - safety

M3 - Conference Abstract

ER -

Vähä-Nissi M, Pitkänen M, Salo E, Sievänen J, Putkonen M, Harlin A. Safety Aspects of Polymer Films with Atomic Layer Deposited Thin Al2O3 Barrier Layers. 2013. Abstract from 13th International Conference on Atomic Layer Deposition, ALD 2013, San Diego, United States.