Selective chemical functionalization of carbon nanobuds

I.V. Anoshkin (Corresponding Author), A.G. Nasibulin (Corresponding Author), P.R. Mudimela, J. Raula, Vladimir Ermolov, E.I. Kauppinen

Research output: Contribution to journalArticleScientificpeer-review

6 Citations (Scopus)

Abstract

single-walled carbon nanotubes (CNTs). The successful covalent modification of CNBs by double carboxylic group in Bingel reaction was demonstrated. It was found that CNBs have higher chemical reactivity compared to CNTs in the reactions of cyclopropanation. Chemical structures of the modified CNBs and CNTs were confirmed by FTIR spectroscopy, TEM and EDX-spectroscopy. Using light sensitive molecule – 5,10,15,20-tetra(4-pyridyl)porphyrin, it was shown that the resistance of modified CNB network can be reversibly switched by low power UV illumination with the detection speed less than 0.3 s.
Original languageEnglish
Pages (from-to)4171-4174
Number of pages3
JournalCarbon
Volume50
Issue number11
DOIs
Publication statusPublished - 2012
MoE publication typeA1 Journal article-refereed

Fingerprint

Carbon Nanotubes
Carbon nanotubes
Carbon
Spectroscopy
Chemical reactivity
Porphyrins
Single-walled carbon nanotubes (SWCN)
Energy dispersive spectroscopy
Lighting
Transmission electron microscopy
Molecules
5,10,15,20-tetra(4-pyridyl)porphyrin

Cite this

Anoshkin, I. V., Nasibulin, A. G., Mudimela, P. R., Raula, J., Ermolov, V., & Kauppinen, E. I. (2012). Selective chemical functionalization of carbon nanobuds. Carbon, 50(11), 4171-4174. https://doi.org/10.1016/j.carbon.2012.04.066
Anoshkin, I.V. ; Nasibulin, A.G. ; Mudimela, P.R. ; Raula, J. ; Ermolov, Vladimir ; Kauppinen, E.I. / Selective chemical functionalization of carbon nanobuds. In: Carbon. 2012 ; Vol. 50, No. 11. pp. 4171-4174.
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abstract = "single-walled carbon nanotubes (CNTs). The successful covalent modification of CNBs by double carboxylic group in Bingel reaction was demonstrated. It was found that CNBs have higher chemical reactivity compared to CNTs in the reactions of cyclopropanation. Chemical structures of the modified CNBs and CNTs were confirmed by FTIR spectroscopy, TEM and EDX-spectroscopy. Using light sensitive molecule – 5,10,15,20-tetra(4-pyridyl)porphyrin, it was shown that the resistance of modified CNB network can be reversibly switched by low power UV illumination with the detection speed less than 0.3 s.",
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Anoshkin, IV, Nasibulin, AG, Mudimela, PR, Raula, J, Ermolov, V & Kauppinen, EI 2012, 'Selective chemical functionalization of carbon nanobuds', Carbon, vol. 50, no. 11, pp. 4171-4174. https://doi.org/10.1016/j.carbon.2012.04.066

Selective chemical functionalization of carbon nanobuds. / Anoshkin, I.V. (Corresponding Author); Nasibulin, A.G. (Corresponding Author); Mudimela, P.R.; Raula, J.; Ermolov, Vladimir; Kauppinen, E.I.

In: Carbon, Vol. 50, No. 11, 2012, p. 4171-4174.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Selective chemical functionalization of carbon nanobuds

AU - Anoshkin, I.V.

AU - Nasibulin, A.G.

AU - Mudimela, P.R.

AU - Raula, J.

AU - Ermolov, Vladimir

AU - Kauppinen, E.I.

PY - 2012

Y1 - 2012

N2 - single-walled carbon nanotubes (CNTs). The successful covalent modification of CNBs by double carboxylic group in Bingel reaction was demonstrated. It was found that CNBs have higher chemical reactivity compared to CNTs in the reactions of cyclopropanation. Chemical structures of the modified CNBs and CNTs were confirmed by FTIR spectroscopy, TEM and EDX-spectroscopy. Using light sensitive molecule – 5,10,15,20-tetra(4-pyridyl)porphyrin, it was shown that the resistance of modified CNB network can be reversibly switched by low power UV illumination with the detection speed less than 0.3 s.

AB - single-walled carbon nanotubes (CNTs). The successful covalent modification of CNBs by double carboxylic group in Bingel reaction was demonstrated. It was found that CNBs have higher chemical reactivity compared to CNTs in the reactions of cyclopropanation. Chemical structures of the modified CNBs and CNTs were confirmed by FTIR spectroscopy, TEM and EDX-spectroscopy. Using light sensitive molecule – 5,10,15,20-tetra(4-pyridyl)porphyrin, it was shown that the resistance of modified CNB network can be reversibly switched by low power UV illumination with the detection speed less than 0.3 s.

U2 - 10.1016/j.carbon.2012.04.066

DO - 10.1016/j.carbon.2012.04.066

M3 - Article

VL - 50

SP - 4171

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JO - Carbon

JF - Carbon

SN - 0008-6223

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Anoshkin IV, Nasibulin AG, Mudimela PR, Raula J, Ermolov V, Kauppinen EI. Selective chemical functionalization of carbon nanobuds. Carbon. 2012;50(11):4171-4174. https://doi.org/10.1016/j.carbon.2012.04.066