Selective chemical functionalization of carbon nanobuds

I.V. Anoshkin (Corresponding Author), A.G. Nasibulin (Corresponding Author), P.R. Mudimela, J. Raula, Vladimir Ermolov, E.I. Kauppinen

    Research output: Contribution to journalArticleScientificpeer-review

    6 Citations (Scopus)

    Abstract

    single-walled carbon nanotubes (CNTs). The successful covalent modification of CNBs by double carboxylic group in Bingel reaction was demonstrated. It was found that CNBs have higher chemical reactivity compared to CNTs in the reactions of cyclopropanation. Chemical structures of the modified CNBs and CNTs were confirmed by FTIR spectroscopy, TEM and EDX-spectroscopy. Using light sensitive molecule – 5,10,15,20-tetra(4-pyridyl)porphyrin, it was shown that the resistance of modified CNB network can be reversibly switched by low power UV illumination with the detection speed less than 0.3 s.
    Original languageEnglish
    Pages (from-to)4171-4174
    Number of pages3
    JournalCarbon
    Volume50
    Issue number11
    DOIs
    Publication statusPublished - 2012
    MoE publication typeA1 Journal article-refereed

    Fingerprint

    Carbon Nanotubes
    Carbon nanotubes
    Carbon
    Spectroscopy
    Chemical reactivity
    Porphyrins
    Single-walled carbon nanotubes (SWCN)
    Energy dispersive spectroscopy
    Lighting
    Transmission electron microscopy
    Molecules
    5,10,15,20-tetra(4-pyridyl)porphyrin

    Cite this

    Anoshkin, I. V., Nasibulin, A. G., Mudimela, P. R., Raula, J., Ermolov, V., & Kauppinen, E. I. (2012). Selective chemical functionalization of carbon nanobuds. Carbon, 50(11), 4171-4174. https://doi.org/10.1016/j.carbon.2012.04.066
    Anoshkin, I.V. ; Nasibulin, A.G. ; Mudimela, P.R. ; Raula, J. ; Ermolov, Vladimir ; Kauppinen, E.I. / Selective chemical functionalization of carbon nanobuds. In: Carbon. 2012 ; Vol. 50, No. 11. pp. 4171-4174.
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    title = "Selective chemical functionalization of carbon nanobuds",
    abstract = "single-walled carbon nanotubes (CNTs). The successful covalent modification of CNBs by double carboxylic group in Bingel reaction was demonstrated. It was found that CNBs have higher chemical reactivity compared to CNTs in the reactions of cyclopropanation. Chemical structures of the modified CNBs and CNTs were confirmed by FTIR spectroscopy, TEM and EDX-spectroscopy. Using light sensitive molecule – 5,10,15,20-tetra(4-pyridyl)porphyrin, it was shown that the resistance of modified CNB network can be reversibly switched by low power UV illumination with the detection speed less than 0.3 s.",
    author = "I.V. Anoshkin and A.G. Nasibulin and P.R. Mudimela and J. Raula and Vladimir Ermolov and E.I. Kauppinen",
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    doi = "10.1016/j.carbon.2012.04.066",
    language = "English",
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    Anoshkin, IV, Nasibulin, AG, Mudimela, PR, Raula, J, Ermolov, V & Kauppinen, EI 2012, 'Selective chemical functionalization of carbon nanobuds', Carbon, vol. 50, no. 11, pp. 4171-4174. https://doi.org/10.1016/j.carbon.2012.04.066

    Selective chemical functionalization of carbon nanobuds. / Anoshkin, I.V. (Corresponding Author); Nasibulin, A.G. (Corresponding Author); Mudimela, P.R.; Raula, J.; Ermolov, Vladimir; Kauppinen, E.I.

    In: Carbon, Vol. 50, No. 11, 2012, p. 4171-4174.

    Research output: Contribution to journalArticleScientificpeer-review

    TY - JOUR

    T1 - Selective chemical functionalization of carbon nanobuds

    AU - Anoshkin, I.V.

    AU - Nasibulin, A.G.

    AU - Mudimela, P.R.

    AU - Raula, J.

    AU - Ermolov, Vladimir

    AU - Kauppinen, E.I.

    PY - 2012

    Y1 - 2012

    N2 - single-walled carbon nanotubes (CNTs). The successful covalent modification of CNBs by double carboxylic group in Bingel reaction was demonstrated. It was found that CNBs have higher chemical reactivity compared to CNTs in the reactions of cyclopropanation. Chemical structures of the modified CNBs and CNTs were confirmed by FTIR spectroscopy, TEM and EDX-spectroscopy. Using light sensitive molecule – 5,10,15,20-tetra(4-pyridyl)porphyrin, it was shown that the resistance of modified CNB network can be reversibly switched by low power UV illumination with the detection speed less than 0.3 s.

    AB - single-walled carbon nanotubes (CNTs). The successful covalent modification of CNBs by double carboxylic group in Bingel reaction was demonstrated. It was found that CNBs have higher chemical reactivity compared to CNTs in the reactions of cyclopropanation. Chemical structures of the modified CNBs and CNTs were confirmed by FTIR spectroscopy, TEM and EDX-spectroscopy. Using light sensitive molecule – 5,10,15,20-tetra(4-pyridyl)porphyrin, it was shown that the resistance of modified CNB network can be reversibly switched by low power UV illumination with the detection speed less than 0.3 s.

    U2 - 10.1016/j.carbon.2012.04.066

    DO - 10.1016/j.carbon.2012.04.066

    M3 - Article

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    SP - 4171

    EP - 4174

    JO - Carbon

    JF - Carbon

    SN - 0008-6223

    IS - 11

    ER -

    Anoshkin IV, Nasibulin AG, Mudimela PR, Raula J, Ermolov V, Kauppinen EI. Selective chemical functionalization of carbon nanobuds. Carbon. 2012;50(11):4171-4174. https://doi.org/10.1016/j.carbon.2012.04.066