Semipreparative synthesis, 13C- and 2D-NMR of Pulo'upone

J. Matikainen, S. Kaltia, Tapio Hase, Ilkka Kilpeläinen, Torbjörn Drakenberg, Arto Annila

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Abstract

A mmolar scale synthetic route to (±)-pulo'upone, in 9 steps, 3.8 % overall yield, and under non-epimerizing conditions, is reported. A complete assignment of the compound's 1H and 13C NMR shifts is presented.

(±)-Pulo'upone (1) is synthesized from 4-pentyl-1-ol (2) (9 steps, 3.8% overall). A complete 1H and 13C NMR signal assignment for (1) is presented.

Original languageEnglish
Pages (from-to)8007-8014
Number of pages8
JournalTetrahedron
Volume49
Issue number36
DOIs
Publication statusPublished - 1993
MoE publication typeA1 Journal article-refereed

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    Matikainen, J., Kaltia, S., Hase, T., Kilpeläinen, I., Drakenberg, T., & Annila, A. (1993). Semipreparative synthesis, 13C- and 2D-NMR of Pulo'upone. Tetrahedron, 49(36), 8007-8014. https://doi.org/10.1016/S0040-4020(01)88024-8