Separation of Metal Complexes by On-Line Coupled LC-GC

P. Lukkari, J. Hannuksela, Veikko Häkkinen (Corresponding Author), Maija-Liisa Mattinen, M. Virolainen, Riekkola Marja-Liisa

Research output: Contribution to journalArticleScientificpeer-review

2 Citations (Scopus)

Abstract

The on‐line coupled LC‐GC technique was applied to the analysis of several metal chelates of N,N‐diethyldithiocarbamic acid. A 10‐port valve interface was used to couple the LC and GC instruments. Conditions during sample transfer into the GC gave fully concurrent solvent evaporation. The chelates investigated were separated with a short apolar fused silica column. LC preseparation was made with cyano or amino phases using a hexane/dichloromethane mixture as eluent. On‐line LC‐GC combination seems to be very suitable for the separation of the metal chelates studied.

Original languageEnglish
Pages (from-to)170-172
JournalHRC Journal of High Resolution Chromatography
Volume13
Issue number3
DOIs
Publication statusPublished - 1990
MoE publication typeNot Eligible

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Coordination Complexes
Metal complexes
Metals
Methylene Chloride
Dichloromethane
Hexanes
Fused silica
Hexane
Evaporation
Acids

Cite this

Lukkari, P., Hannuksela, J., Häkkinen, V., Mattinen, M-L., Virolainen, M., & Marja-Liisa, R. (1990). Separation of Metal Complexes by On-Line Coupled LC-GC. HRC Journal of High Resolution Chromatography, 13(3), 170-172. https://doi.org/10.1002/jhrc.1240130306
Lukkari, P. ; Hannuksela, J. ; Häkkinen, Veikko ; Mattinen, Maija-Liisa ; Virolainen, M. ; Marja-Liisa, Riekkola. / Separation of Metal Complexes by On-Line Coupled LC-GC. In: HRC Journal of High Resolution Chromatography. 1990 ; Vol. 13, No. 3. pp. 170-172.
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Lukkari, P, Hannuksela, J, Häkkinen, V, Mattinen, M-L, Virolainen, M & Marja-Liisa, R 1990, 'Separation of Metal Complexes by On-Line Coupled LC-GC', HRC Journal of High Resolution Chromatography, vol. 13, no. 3, pp. 170-172. https://doi.org/10.1002/jhrc.1240130306

Separation of Metal Complexes by On-Line Coupled LC-GC. / Lukkari, P.; Hannuksela, J.; Häkkinen, Veikko (Corresponding Author); Mattinen, Maija-Liisa; Virolainen, M.; Marja-Liisa, Riekkola.

In: HRC Journal of High Resolution Chromatography, Vol. 13, No. 3, 1990, p. 170-172.

Research output: Contribution to journalArticleScientificpeer-review

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T1 - Separation of Metal Complexes by On-Line Coupled LC-GC

AU - Lukkari, P.

AU - Hannuksela, J.

AU - Häkkinen, Veikko

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AU - Virolainen, M.

AU - Marja-Liisa, Riekkola

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AB - The on‐line coupled LC‐GC technique was applied to the analysis of several metal chelates of N,N‐diethyldithiocarbamic acid. A 10‐port valve interface was used to couple the LC and GC instruments. Conditions during sample transfer into the GC gave fully concurrent solvent evaporation. The chelates investigated were separated with a short apolar fused silica column. LC preseparation was made with cyano or amino phases using a hexane/dichloromethane mixture as eluent. On‐line LC‐GC combination seems to be very suitable for the separation of the metal chelates studied.

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Lukkari P, Hannuksela J, Häkkinen V, Mattinen M-L, Virolainen M, Marja-Liisa R. Separation of Metal Complexes by On-Line Coupled LC-GC. HRC Journal of High Resolution Chromatography. 1990;13(3):170-172. https://doi.org/10.1002/jhrc.1240130306