Simultaneous bench scale production of dissolving grade pulp and valuable hemicelluloses from softwood kraft pulp by ionic liquid extraction

Christiane Laine, Sari Asikainen, Riku Talja, Agnes Stépán, Herbert Sixta, Ali Harlin

    Research output: Contribution to journalArticleScientificpeer-review

    16 Citations (Scopus)

    Abstract

    Ionic liquid extraction of wood pulp has been highlighted as a highly potential new process for dissolving pulp production. Coproduction with a polymeric hemicellulose fraction was demonstrated in bench scale from softwood kraft pulp using extraction with the ionic liquid 1-ethyl-3-methylimidazolium acetate (EMIM OAc) and water. In total, the recovered pulp and hemicellulose fraction together yielded 95.5 wt.% of the pulp input. The extracted pulp had a remarkably high purity with an R18-value of 97.8%. The hemicellulose fraction consisted of galactoglucomannan, arabinoxylan and some cellulose and was precipitated from the ionic liquid-water mixture. After hydroxypropylation of the hemicellulose fraction, films were prepared and barrier and strength properties were compared to films from other polysaccharides. Reduced oxygen and water vapor permeation and good strength properties were demonstrated when compared to corresponding films from hydroxypropylated xylan from cold caustic extraction. The films have potential for applications in food packaging and edible films.
    Original languageEnglish
    Pages (from-to)402-408
    JournalCarbohydrate Polymers
    Volume136
    DOIs
    Publication statusPublished - 2016
    MoE publication typeA1 Journal article-refereed

    Keywords

    • hemicellulose
    • wood pulp
    • dissolving pulp
    • ionic liquid
    • modification
    • barrier film
    • strength properties

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